石化生产装置微量泄漏检测方法及应用

以石化装置为例介绍了生产装置微量泄漏的含义、适用的检测仪器种类以及泄漏检测的具体做法。通过实际检测数据的分析。说明了微量泄漏检测对设备管理、工艺改造的促进作用。     

Inhibiting effects by Fe2O3 on combustion and explosion characteristics of ABS resin

The global increase in the use of, and reliance on, plastics has prompted the demand for acrylonitrile-butadiene-styrene (ABS) resin in various fields. With this increased requirement, numerous failures have occurred in the ABS process. Those incidents, resulting from electrostatic discharge, powder accumulation, heat accumulation, construction sparks, and plant fires, have caused dust fire and explosions.In this study, the ABS resin was gleaned from the site and tested for its explosion parameters, including minimum ignition temperature of dust cloud (MIT_C), minimum ignition energy (MIE), and minimum explosion concentration (MEC). To improve loss prevention in the manufacturing process, ferric oxide (Fe₂O₃) as an inert additive was added in the ABS powder. According to the MIE test, Fe₂O₃ has an apparent inhibiting effect on dust explosion for the ABS dust. With the proportion of Fe₂O₃ increased from 25 to 50 mass% in ABS, the MIE increased from 67 to 540 mJ. The explosion tests via 20-L apparatus indicated that Fe₂O₃ mixed with ABS could not increase the MEC significantly. However, the explosion pressure dropped by increasing in the ratio of Fe₂O₃ in ABS. This inerting strategy of ABS was deemed to substantially lessen the probability and severity of fire and explosion.     

Experimental study on the inhibition of methane/air explosion by modified attapulgite powder

In order to explore the influence of attapulgite powder on the methane explosion, a small-size semi-closed visual explosion experiment platform was built, and experiments were carried out. The effect of spraying powder on the whole process of methane explosion was studied when methane concentration was 7%, 8%, 9.5%, 11% and 12%, respectively. When the methane concentration was 11%, the maximum explosion overpressure dropped by modified spraying attapulgite powder was as high as 33.26%, and at the same time, the reduction rate of flame propagation velocity reached the maximum value of 36.65%. Furthermore, when the methane concentration was 9.5%, the experimental results when the powder spraying amount of modified attapulgite was 120 mg, 160 mg, 200 mg, 240 mg and 280 mg showed that when the powder spraying was 240 mg, the maximum explosive overpressure decreased by 33.14%, and the reduction rate of the peak flame propagation velocity reached the maximum value of 33.73%. Through the video images recorded by the high-speed camera, the flame structure, shape, color, etc. Were analyzed. The characterization analysis illustrated that the modified attapulgite powder has a small particle size, relatively large porosity and specific surface area. Also, it has a high weight loss rate. Combined with the results of characterization analysis, the explosion suppression mechanism of modified attapulgite powder was discussed. It was found that the modified attapulgite powder could effectively absorb the active free radicals generated in the explosion, and the modified new chemical components have a better thermal decomposition and endothermic effect and a better suppression of methane explosions.     

多源数据支持下城市火灾风险评估及规划响应

为探析城市火灾风险的空间格局特征,提出科学的火灾防控体系,以合肥市为研究对象,基于火灾风险兴趣点(POI)数据、NPP/VIIRS夜间灯光影像数据、消防站与道路信息等多源数据,运用SAVEE模型和迭代方程评估城市火灾风险,并引入区位-配置(L-A)模型,从不同目标情境优化消防站点布局。研究表明:火灾高风险区主要集中于合肥市二环以内的建成区,尤其是老城区、合肥西站片区、政务区、科学城和东部新中心等区域;现有48座消防站对研究区内的POI覆盖效果较好,覆盖率为86.76%,而对NPP/VIIRS覆盖效果一般,覆盖率仅为55.94%,覆盖率在合肥市东北部、西北部和南部部分地区仍有不足;基于最大化覆盖模型,规划新增44座消防站,明显提升5 min响应时间的覆盖率,可进一步夯实城市消防安全。     

Quantified risk assessment on life and property loss from road collision vehicle fires with hydrogen-fueled tank

Hydrogen fuel cell vehicles pose hazards different from conventional vehicles. This paper performs a risk assessment on road collision vehicle fires with hydrogen-fueled tank of 70 MPa. The high voltage battery fire caused by road collision can lead to onboard hydrogen release or explosion. Events progressions are analyzed and typical hydrogen consequences are evaluated quantitatively, including hydrogen jet fires and tank catastrophic rupture. Perimeters around the accident scene are proposed for the safety of general public and first responders, respectively. Risks of fatalities, injuries, and damages are all quantified in financial terms to make it possible to combine and compare.     

煤田火区塌陷区渗透系数分布研究

通过分析煤田火区地表下沉量和破碎岩块孔隙率的关系,对地表下沉量进行测量,分析计算得到火区破碎岩块孔隙率的分布方程。在实验室中测量不同孔隙率破碎岩块的渗透系数,拟合建立渗透系数和孔隙率的关系方程,利用求得的关系方程和通过地表下沉量测量法得到的孔隙率分布方程,求得煤田火区塌陷区破碎岩块的渗透系数分布方程。     

地下煤火回风裂隙火风压分布实验研究

利用煤田露头火区模拟实验装置,通过对煤火燃烧过程中出风裂隙内气体温度的监测,发现裂隙内气体的温度沿裂缝逐渐降低并成指数衰减分布。通过分析得到火区裂隙温度的分布方程并计算得到了裂隙内火风压分布方程,得出煤田火区火风压的影响因素主要有自燃煤层温度、自燃深度和裂隙倾角。     

基于PCA-FPP-BP神经网络的高层建筑火灾安全评价

为解决高层建筑构造复杂、人员密度大、火灾触发因素繁多而造成高层建筑火灾安全评价困难的问题,本文提出基于PCA-FPP-BP神经网络的高层建筑火灾安全评价模型。首先运用主成分分析(PCA)对构建的高层建筑火灾安全评价指标降维处理,筛选主要信息;接着基于三角模糊数构建模糊评判矩阵,利用模糊优先规划(FPP)求解指标的权重值,减少主观的影响;最后考虑到指标间关系错综复杂彼此交叉和反馈的特性,选择BP神经网络对高层建筑火灾安全进行评价。通过工程案例证明该评价模型的实用性以及可靠性。     

A numerical study on the feasibility and efficiency of point smoke extraction strategies in large cross-section shield tunnel fires using CFD modeling

The strategy of smoke control is of high importance for the design process of tunnels, especially for long and large cross-section tunnels. The South Hongmei Rd. Tunnel (SHT) located in Shanghai, China, is a 3.39 km long shield TBM (tunnel boring machine) tunnel with an external diameter of 14.5 m. The point smoke extraction system was proposed initially as the main ventilation strategy during a tunnel fire. To investigate the fire characteristics in the tunnel and develop appropriate smoke control strategies, a series of numerical 3D Computation Fluid Dynamics (CFD) simulations were conducted. Three fire scenarios, namely 5 MW, 20 MW and 50 MW, were modeled to evaluate the point extraction system. The gas temperatures, the stratification of the smoke, air temperature, minimum visibility etc., during the smoke spreading of a fire were analyzed. Based on the results of the simulation, the smoke extraction strategies according to fire scale and fire location were proposed for fire extinguishing. It was found that the three-point extraction opening strategy can control the smoke better than two-point extraction opening strategy under various fire scales, especially under serious fire scenario. From the results, damper openings ranged at closer intervals were found more efficient in two-point extraction system. Besides, placing the damper openings in the longitudinal direction can improve the efficiency of smoke extraction. It also results in reduction of the quantity of prefabricated members of duct slab and the process of assembly will be simplified during the construction.     

日本“3·11”大地震对石化行业的启示

简要分析了日本“3·11”大地震后发生的2起炼油厂火灾事故,对日本在地震中的一些经验教训进行了总结,根据本次及近几年地震对石化企业的破坏情况,分析了地震中石化装置的薄弱环节,并提出对石化行业的启示。