Nonylphenols in freshwaters of the hydrologic system of an Italian district: association with human activities and evaluation of human exposure

A sampling campaign for the determination of concentrations of nonylphenol isomers (NPs) in freshwaters and sediments of the hydrologic system of the Rieti district (central Italy) was conducted from 2002 to 2003. Eighteen sampling points, selected on the basis of the different human activities in the vicinity, were monitored; six series of water samples (from June 2002 to February 2003) and one of sediment samples (summer 2002) were analyzed by GC/MS.

There was a direct relationship between concentrations of NPs and the presence of urban or industrial activities near the sampling point. However, concentrations of NPs in water were in the range of <0.1–1.4 μg l⁻¹, and their presence limited to short distances from the sources of contamination. Accumulation factors in sediment samples ranged from 10² to 5 × 10³.     

Preface

A new method for generating reactive species to destroy toxic organic chemicals has been developed. This method reacts yellow phosphorus with O₂, in moist air to produce species such as O,O₃, PO, and PO₂, which are capable of reacting with various types of organics. Toxic organic com-pounds are converted to small molecular wight organic acids, aldehydes, and/or alcohols, while yel-low phosphonis is oxidital into phosphoric acid, which may be recovered as a valuable byproduct.This technique has ben demonstrated to be effective for destroying many types of toxic organiccompounds. including PAH, aromatic chlorides, amines, alcohols, and acids, nitro-aromatics,heterocyclic hydrocarbons, PCB, aliphatic chlorides and sulfides, dyes, and pesticides.     

基于FUZZY-AHP的危化品管道运输 安全等级综合评判模型与应用

为有效控制与降低危化品管道运输风险,以国家安全生产法和危化品输送管道安全管理规定为基础依据,与我国危化品管道运输现状相结合,建立以危化品管道运输安全等级为目标层的评价指标体系后,基于层次分析法(AHP)理论与模糊数学综合评价法(FUZZY),构建其综合评价模型。通过实例验证表明,该模型对危化品管道运输安全等级的确立科学且有效,所得结论对于提升危化品管道运输安全等级有较好的理论和实践指导作用。     

危险化学品环境风险评估报告编制中若干问题的研究

为加强重点危险化学品环境管理工作,国家要求实行重点危险化学品环境风险评估制度。在风评制度尚未全面开展的情况下,通过先行对一家重点环境管理危险化学品使用企业开展风险评估,从而对风评报告编制过程中存在的问题与困难进行总结,并提出建议与对策,可为其他编制机构开展环境风险评估工作提供指导作用。     

环境激素对鱼的影响

环境激素是存在于环境之中,以某种方式干扰正常内分泌功能的天然或合成的化合物。鱼在水生生态系统之中分布广泛,是在食物链中具有重要位置的物种,在毒理学和生态风险评价中具有重要的实验价值。文中对鱼暴露于一些常见环境激素时,受激素调节的生殖和发育过程所受到的影响及相应机理进行了探讨。同时介绍了鱼应用于水环境中激素的筛选与监测评价的方法。      

环境激素对水蚤的影响

存在于环境中的环境激素是以某种方式干扰正常内分泌功能的天然或合成的化合物。地水蚤在水生生态系统及生态风险评价中的重要位置与作用,探讨水蚤暴露于一些常见环境激素时,其受激素调节的生殖和蜕皮过程所受到的影响及相应机理很有必要。     

Industrial accidents in spray dryer plants for dairy products in Europe

Despite the fact that the information about past accidents is an integral part of accident prevention, the information about industrial accidents is not commonly available in food and agricultural sectors. Spray dryer plants for dairy products are not an exception. The aim of this paper is the creation of the representative database for industrial spray drying accidents in order to identify their major causes. The paper is divided into 8 chapters. The first two chapters deal with the general information about technology of spray drying of dairy products. The third chapter provides the outputs from the authors' database containing records of 25 accidents in milk drying facilities in Europe. These accidents took place between 1999 and 2019 in six European countries. Based on the accident database, the most common causes of accidents were identified. Processes that can cause a fire, an explosion, or damage to environment are described in the fourth, fifth and sixth chapter. The seventh chapter deals with process, technical and organizational measures; these were discussed using literature research and the results of the accident database. The eighth chapter is the conclusion with a focus on further improvement of process safety through newly developed protective tools.     

危化品道路运输事故应急救援中心选址模型研究

为快速提高危化品道路运输事故应急救援能力,降低事故后果,文章基于目前应急救援中心选址模型的不足,提出了一种新的双目标决策救援中心选址模型。通过综合考虑应急响应时间及应急处理能力对救援能力的影响,建立了救援中心点的最大网络覆盖模型;并采用较优的邻域搜索算法求解救援中心点的合理位置。最后以某地危化品运输路网为例,利用所建模型对事故应急救援中心的合理布局计算求解。结果表明:考虑应急响应时间及应急处理能力限制的应急救援中心选址模型,能够有效提高救援中心的综合应急能力,为有关部门合理规划危化品道路运输事故应急救援中心布局提供理论参考和决策依据。     

Proactive limit values for responsible management of chemicals

Limit values (LVs) are legal concentration limits for constituents, residues and contaminants in consumer products or for emissions from production processes into environmental compartments. They are a traditional regulatory aid to manage chemicals in human environments. To make them proactive, LVs should become enforced by means of a transparent and informed decision process whose starting point is the Basic Rule of Environmental Hygiene, BREH:Avoid useless exposure as far as possible, minimize useful exposure in a reasonable manner, and prevent that exposure which is dangerous. The BREH calls upon minimizing exposure not only according toon site risk potentials and acceptance, but also tooff site avoidability and acceptability.     

Accumulation, distribution and transformation of DDT and PCBs by Phragmites australis and Oryza sativa L.: II. Enzyme study

Two wetland plant species, Phragmites australis and Oryza sativa, were grown in a glasshouse under hydroponics conditions. Enzyme extracts from different parts of the plants were used to determine the transformation rate of o,p′-DDT, p,p′-DDT and PCBs. The organic pollutants were directly spiked into the enzyme extracts, and samples were collected every 30 min and analyzed with a GC-ECD. Root extracts of P. australis readily degraded and transformed DDT and some PCB congeners with a low degree of chlorination. In contrast, crude extracts of O. sativa showed no appreciable degradation or transformation of DDT or PCBs. Inhibition studies indicated that the degradation and transformation of both DDT and PCBs by P. australis enzymes were partly mediated by peroxidase and the plant P-450 system. PCBs with a high degree of chlorination were highly resistant to transformation or degradation by plant enzymes. Both wetland plant species accumulated substantial quantities of the persistent organic chemicals but had different degradation capacities. The enzyme systems in P. australis were much more effective that those in rice in the degradation and transformation of the organic pollutants.