抛石环境中铝合金阳极性能评价及其对海底隧道钢壳保护效果评估

目的 解决埋覆介质中牺牲阳极电化学性能评价的不确定性,实现非匀质介质中牺牲阳极电容量测试结果的评价和对比.方法 模拟沉管隧道埋覆的环境介质,对铝合金牺牲阳极的电容量和溶解形貌进行评测.为区别于现有的海水等匀质介质中阳极的检测方法,建立非匀质介质中铝阳极电化学性能评价方法.另外,在上述埋覆介质中,测定阳极和阴极的极化曲线,修正仿真计算的边界条件,有利于模拟这种高电阻率介质环境下阴极保护电位分布.结果 测试箱所测电阻率与商用便携式电导率仪测定精度相当.A1阳极在低电阻率的海水中(25～40?·cm)性能稳定,电容量稳定在2500 A·h/kg,溶解性能良好;在40?·cm海淡水+回填石的混合介质中,电容量测试值数据波动大,重现性差.B1阳极在海水(25～40?·cm)中的电容量和A1阳极相当,未见到差异,在40?·cm海淡水+回填石混合介质中,电容量数值分散性小,电化学活性高.结论 混合介质中的评价试验体现了海淡水、混合介质电阻率和回填石对阳极溶解产物阻滞的综合效应,提高了抛石环境中铝阳极寿命评估的准确性,尤其适用于沉管隧道钢壳用铝合金阳极电化学性能评价和牺牲阳极保护效果评估.     

Temporal and spatial distribution of Cs in Eastern Mediterranean Sea. Horizontal and vertical dispersion in two regions

Caesium-137 activity concentration in the water columns of the Gulf of Patras (Central Greece) and the North-Eastern Aegean Sea (easterward to Lemnos Island) was investigated in selected sampling stations during the period September 2004–June 2006. The methodology followed was based on the sorption of caesium (Cs) on cotton wound cartridge filters impregnated by Cu₂[Fe(CN)₆] via in-situ pumping. In terms of the horizontal and vertical records, the activity concentrations of ¹³⁷Cs in the Gulf of Patras ranged between 1.2 and 6.7 Bq m⁻³, depending on the sampling period and the prevailing physicochemical regime at the sampling station. The general pattern of the decreased activity concentrations of ¹³⁷Cs with increasing depth was reversed in the Gulf of Patras during the cold period attributed to the prevailing advective processes of the area. The activity concentrations of ¹³⁷Cs in the North-Eastern Aegean Sea ranged from 2.6 to 12.8 Bq m⁻³, whereas significant stratified curves were observed during the warm period and also, in one station during the cold period. In terms of temporal variation, the discharges in the Gulf of Patras resulted in enhanced levels of ¹³⁷Cs, whereas in the North Aegean Sea the incoming water masses form the Black Sea had an apparent influence throughout the year by increasing the ¹³⁷Cs levels, hence presenting a weak seasonal variation. Comparing the two studied areas, one could say that the North Aegean Sea, as an open sea environment, presented higher concentrations due to the influence of the Black Sea water masses. The estimated inventories of ¹³⁷Cs in the Gulf of Patras ranged 0.25 ± 0.03–0.79 ± 0.03 kBq m⁻², whereas in the North-Eastern Aegean Sea they ranged 0.33 ± 0.02–0.92 ± 0.03 kBq m⁻².     

固结时间对软粘土动剪切模量的影响

随着固结时间的增加,试样逐渐变硬的硬化效应使软粘土的动剪切模量增大;同时,随着固结时间的增加,试样高度和直径明显减小的尺寸效应,也使软粘土的动剪切模量受到显著的影响。通过软粘土自振柱试验,分析了固结时间对软粘土的最大动剪切模量、动剪切模量比和试样尺寸的影响;根据自振柱试验的基本原理,分析了试样尺寸的变化对软粘土动剪切模量的影响;结合试验得到的固结时间和试样尺寸的关系,分析了固结时间通过试样尺寸对软粘土动剪切模量的影响。     

某装药弹振动特性的安全分析

为分析某装药弹的振动特性,并为该弹提供必要的力学数据,建立某装药弹模态方程。采用ANSYS软件对该弹振动特性进行了数值模拟,利用Block Lanczos法求解,得到前10阶振动固有频率和振型。分析结果表明:低阶频率主要以摆动和转动为主,高阶频率主要以弯曲扭动为主,低阶频率对该弹的影响比较小,高阶频率对该弹的影响比较大,尤其是7～10阶频率,该弹的主振频率为1053.8 Hz,为该弹的优化设计提供科学依据,在加工、储存、运输和使用条件下应低于该频率;为验证该方法可信度,采用某小型装药弹进行了实验验证,实验结果和仿真结果偏差小于1%;同时证明该有限元数值分析的方法是经济可靠的。     

气相色谱法测定工业废水中联苯与菲

文章研究了一种新的测定废水中联苯及菲含量的方法,该方法采用气相色谱薄涂柱,对联苯与菲进行了有效的分离与测定。该方法具有固定液用量少,柱温低,分离效果好,分析速度快等特点,利用该对废水样进行了测定,取得了满意的结果。     

改性沸石对2,4-二氯苯酚的去除作用

采用溴化十六烷基三甲铵(HDTMAB)制备改性沸石,在与天然沸石对比的基础上,研究了改性沸石在动态条件下去除2,4-DCP的效果。并对影响去除率的主要因素,包括沸石粒径、进水浓度,进水流速,沸石用量,进水pH值等进行研究。结果表明,细粒改性沸石在pH2.5左右时处理低浓度2,4-DCP溶液时,能取得较好的去除效果,流速较低时去除率最高可达80%以上。     

HP6890色谱柱用于环境空气中微量恶臭硫化物的检测

利用HP6890型气相色谱仪进行环境空气中微量恶臭硫化物分析,实验结果表明:分离效果、峰形都很好,实验采用4种柱箱初始温度及升温程序,分别由初始温度70℃升温至90℃、120℃、130℃及由初始温度150℃,最后升温至190℃,相应分析一个样品的时间依次为:130.515min、63.419min、56.359min及11.116min,样品分析时间大大缩短,可提高分析效率。     

苏南地区新近沉积土的动剪切模量比与阻尼比--试验研究

苏南地区的场地土主要为漫滩相、湖沼相或冲湖相新近沉积软弱土，结构松散，沉积零乱，成分复杂，饱水可液化粉细砂层及粉土层较为发育，在地震或动力荷载的作用下有可能发生软土震陷或砂土液化。通过对苏南地区淤泥质粉质粘土、粘土、粉质粘土、粉质粘土与粉细砂互层土、粉土、粉砂、细砂和中粗砂等8类新近沉积土155个原状土样历时4年的试验研究，给出了该地区上述8类新近沉积土的动剪切模量比G／Gmax和阻尼比D随剪应变幅值γ变化的平均拟合曲线及其参数的推荐值。为便于一般工程应用，给出了这8类新近沉积土的G/Gmax-γ，和D—γ关系曲线的推荐值及其标准差。     

泥石流的运动机理和减阻

野外调查研究发现,存在着两种具有不同动力学特征和机理的泥石流,粘滞性泥石流和两相泥石流,粘滞性泥石流由卵石、沙和粘土构成,难以区分固相和液相,为典型的非牛顿体,具有间歇性流动,“铺床现象”,高达60％的减阻和显著超高等流动特点,粘滞性泥石流的阻力远小于流变参数所代表的阻力,传统的利用本构方程研究阻力的方法不能解决问题,研究表明,其30％的减阻是由于铺床作用,另外20％－30％,是由于流动混合物充气所致,两相泥石流主要由粗颗粒物质构成,两相之间有明显的相对流动,显示较大的阻力和发生“石街”现象。粘滞性泥石流沟谷的中值坡度为0．16,两相泥石流阻力大,因而河谷的平均坡度较大（0．19－0．27）。     

Ecological Variation in the Morphological Structure of the Crown in Siberian Stone Pine at the Timberline

The structure of the crown and branching; the growth, development, and ontogeny of branches; and organogenesis and growth of female shoots in the model Siberian stone pine trees were studied in four types of habitats at the timberline in the central Altai Mountains (1700–2170 m a.s.l.). The results provided evidence that the ecological forms of trees appear due to changes in the pattern of branching as well as to the decreased rate of vegetative (primarily apical) growth. The diameter of the shoot pith is one of the most variable characters reflecting the deterioration of environmental conditions at higher elevations.