Thermal research on the uncontrolled behavior of styrene bulk polymerization

Thermal runaway can occur during the styrene bulk polymerization process because of easily formed local hotspots resulting from the high viscosity of reactants and the difficulty of heat dissipation. To obtain the thermal hazard characteristics, the polymerization behavior of styrene was investigated using differential scanning calorimetry (DSC) at a scanning rate of β = 2 °C/min. Experimental results showed that the exothermic peaks obtained for heat initiation were different from those obtained when initiator was added. The exothermic peak changed from one to two after the initiator was added. The exothermic onset temperature (T₀) was also reduced. Phi-tech II was utilized to study the bulk polymerization of styrene in an adiabatic environment. The adiabatic temperature rise (ΔT_ad), starting temperature of uncontrolled polymerization (T_star), maximum temperature (T_end), and heat of polymerization (ΔH) under different conditions were acquired. When the dose of the additive was increased, the starting temperature of uncontrolled polymerization (T_star) decreased and the adiabatic temperature rise (ΔT_ad) increased gradually. Severity grading was performed based on the severity evaluation criteria of runaway reaction. The results can help designers decide whether it is necessary to take certain measures to reduce risk.     

炼油污水处理过程中关键控制因素分析

文章从灰色关联方法选择及分析原理入手，用某炼油厂2002全年的污水处理监测数据进行了灰色关联分析，通过运算分析得出了大量污水处理的关联数据。找出了影响出水水质指标的关键因素，对指导炼油污水进行分级控制做了有益的尝试。     

库水作用下公路土质岸坡稳定性影响因素综合评判

以三峡库区公路土质岸坡为研究对象,通过对库水作用的影响效应分析,建立了岸坡稳定性评价的参数指标评价体系以及相应的分级标准.在此基础上,应用影响因素综合评判方法,对实例岸坡进行了稳定性分级评价,评价结果与实际情况基本相符.     

分指数分级评分叠加法在水质评价中的应用

提出了一种新的具有明确物理意义、且计算简单的“分指数分级评分叠加法”,讨论了该方法评价的表示方法,并给出了应用实例。     

基于指标气体关联分析的煤自燃分级预警研究

为准确预警煤炭自然发火,基于程序升温试验,获得指标气体与温度间的关系,并将起始温度V0和特征温度点V1、V2、V3时刻的碳氧化物比率作为预警界限,设定4级预警机制,采用灰色关联分析法关联性分析采空区和上隅角CO气体体积分数和碳氧化物比率,按照关联等级的高低细化4级预警机制,同时选取典型案例,详细展示该预警机制下的预警流...     

安康水库分级超蓄的洪水资源化方法及其风险

汛限水位动态控制是水库洪水资源化的一种重要策略,其核心是在合理权衡风险和效益这一对矛盾的基础上确定可行的水库超汛限水位调度方案。为实现相对较大效益的同时降低水库防洪风险,考虑利用流域降雨预报信息,采用预泄能力约束法,以不同的降雨预报量级为依据,提出分级超蓄的洪水资源化方法,并结合安康水库实例,求得其基于 24 h 小雨和无雨预报的分级超蓄上限分别为326 m和 328 m。通过风险分析得知：在不考虑降雨预报信息的情况下,水库超蓄上限不宜超过 327.5 m;而依据 24 h 降雨预报信息的水库超蓄风险小到可以忽略。最后,应用该超蓄方案对实际洪水进行调度,实现了在减少弃水量069亿m3的同时,增加发电收入约361万元人民币.     

基于风险等值线的职业安全评价分级方法

依据危害因素引发工伤、职业危害事件的后果严重度和可能性来开展职业安全评价,在严重度和可能性的定量评价基础上,引入等值风险线的概念,建立风险评价分级方法,并在单一危害因素的职业安全评价基础上建立了作业场所、工厂、企业的职业安全(风险)评价分级方法.通过应用实例分析,验证了该方法的可操作性.     

The Swedish System for Quality Assessment of Agricultural Soils

Soil quality assessment is based on the concept of soilfunctions. The performances of three soil functions, cropproduction, biological decomposition and matter exchange withthe atmosphere and groundwater, are used as quality criteria.Soil properties that can be used as indicators for the degreeof functional performance were identified. Each soil propertyselected was graded into five classes – from best (class 1) toworst (class 5). Grading was based biological on boundaryconditions as well as on statistical distribution. The systemoutlined can be used to interpret the quality state ofagricultural soils, provides for a relative comparison betweensoils, and may be helpful in an environmental monitoringprogram to assess trends in data.     

基于层次分析法的事故隐患模糊综合评价研究

根据某市重特大事故隐患评估的实际情况,结合其不同特点将其分为7大类,4种等级。以泄漏类事故隐患为例,建立了泄漏类事故隐患评估指标体系,对事故隐患的影响因素进行量化,利用层次分析法确定评价指标的权重,采用模糊综合评价方法对其进行评估,计算出隐患等级。评估结果与实际评估结果相一致。该方法已在实际工作中得到了验证,对重大事故隐患的评估有一定的参考作用。     

城镇煤气管道漏损分析与风险评价

在管道漏损的各种因素分析与分类的基础上,建立管道漏损综合评价模型,结合事故树法和专家评分法,实现对管道运行状况的评价。事故树模型采用最小割集的方法描述事故树相应的结构函数,从而评价事故树各底层事件的结构重要度。根据专家评分法,对危害因素指标和后果进行评分,实现管道工作状态的风险评价。该分析和评价方法,为实现基于风险评价的风险控制与管理提供理论依据。