Experimental Zn(II) retention in a sandy loam soil by very small columns

The use of column experiments, usually performed to better approximate field conditions, may provide information that is not available from batch experiments. In such experiments heavy metals are often adsorbed until saturation followed by desorption experiments. When the affinity of the metal to soil is high, the retention factor (R) could be greater than thousands and the duration of experiments can become impractically long. In order to use reasonable laboratory time, the flow rate should be increased or the column size decreased. The increase in flow rate produces undesirable kinetic and dispersion effects, so we used very small soil columns (pore volume = 0.31–0.70 ml) and relatively high flow rates (0.03–0.12 ml min⁻¹) in studies of Zn(II) adsorption and retention in soils. Conservative tracer flow column experiments under saturation conditions were carried out to determine flow parameters for different flow rates. Column pore volume (V_p), Peclet numbers (Pe) and longitudinal dispersion coefficients (D_L) were determined from breakthrough curves. The effect of type of electrolyte and ionic strength on the Zn(II) retention onto soil was determined. The influence of flow rate and bed height on the retention coefficient and on the mass transfer zone was also studied. The effect of different influent Zn(II) concentrations on the R values obtained was analyzed. Freundlich parameters from column experiments were compared with batch ones. The leaching efficiency of different electrolytes, salts of weak organic acids and EDTA was also studied.     

Defining Acceptable Levels for Ecological Indicators: An Approach for Considering Social Values

Ecological indicators can facilitate an adaptive management approach, but only if acceptable levels for those indicators have been defined so that the data collected can be interpreted. Because acceptable levels are an expression of the desired state of the ecosystem, the process of establishing acceptable levels should incorporate not just ecological understanding but also societal values. The goal of this research was to explore an approach for defining acceptable levels of ecological indicators that explicitly considers social perspectives and values. We used a set of eight indicators that were related to issues of concern in the Lake Champlain Basin. Our approach was based on normative theory. Using a stakeholder survey, we measured respondent normative evaluations of varying levels of our indicators. Aggregated social norm curves were used to determine the level at which indicator values shifted from acceptable to unacceptable conditions. For seven of the eight indicators, clear preferences were interpretable from these norm curves. For example, closures of public beaches because of bacterial contamination and days of intense algae bloom went from acceptable to unacceptable at 7–10 days in a summer season. Survey respondents also indicated that the number of fish caught from Lake Champlain that could be safely consumed each month was unacceptably low and the number of streams draining into the lake that were impaired by storm water was unacceptably high. If indicators that translate ecological conditions into social consequences are carefully selected, we believe the normative approach has considerable merit for defining acceptable levels of valued ecological system components.     

环境库兹涅茨曲线的虚幻性及其对可持续发展的现实影响

生态环境质量真的能够随着经济发展而改善吗？“先污染、后治理”真的是普遍的发展规律吗？既有的理论一般认为．随着经济的发展．生态环境的质量在经过一个时期的恶化之后，将在一定的发展阶段出现好转．其变化过程呈“倒U曲线”状态．这就是环境Kuznets曲线。作者认为这是一个貌似真实的虚幻．生态环境随着经济发展而好转只可能是局部的、而不可能是整体性的．经济发展与生态维护的双赢目标也同样是难以企及的，经济发展与生态维护只能是基于各种利益关系的权衡。文章还对中国长期推行的几种宏观经济政策的生态环境影响进行了分析，并提出了经济利益与生态利益相权衡的现实主张。     

Methodology for Developing Flood Rule Curves Conditioned on El Niño‐Southern Oscillation Classification1

Lee, Se‐Yeun, Alan F. Hamlet, Carolyn J. Fitzgerald, and Stephen J. Burges, 2011. Methodology for Developing Flood Rule Curves Conditioned on El Niño‐Southern Oscillation Classification. Journal of the American Water Resources Association (JAWRA) 47(1):81‐92. DOI: 10.1111/j.1752‐1688.2010.00490.x Abstract: Regional climate varies on interannual and decadal time scales that in turn affect annual streamflows, flood risks, and reservoir storage deficits in mid‐summer. However, these variable elements of the climate system are generally not included in water resources operating policies that attempt to preserve a balance between flood risk and other water resources system objectives. A methodology for incorporating El Niño‐Southern Oscillation (ENSO) information in designing flood control curves is investigated. An optimization‐simulation procedure is used to develop a set of ENSO‐conditioned flood control rule curves that relate streamflow forecasts to flood control evacuation requirements. ENSO‐conditioned simulated flood risk and storage deficits under current operating policy are used to calibrate a unique objective function for each ENSO classification. Using a case study for the Columbia River Basin, we demonstrate that ENSO‐conditioned flood control curves constructed using the optimization‐simulation procedure consistently reduce storage deficits at a number of interrelated projects without increasing flood risk. For the Columbia Basin, the overall improvements in reservoir operations are relatively modest, and (in isolation) might not motivate a restructuring of flood control operations. However, the technique is widely applicable to a wide range of water resources systems and/or different climate indices.     

Improved Bankfull Channel Geometry Prediction Using Two‐Year Return‐Period Discharge1

He, Laien and Gregory V. Wilkerson, 2011. Improved Bankfull Channel Geometry Prediction Using Two‐Year Return‐Period Discharge. Journal of the American Water Resources Association (JAWRA) 47(6):1298–1316. DOI: 10.1111/j.1752‐1688.2011.00567.x Abstract:  Bankfull discharge (Q_bf) and bankfull channel geometry (i.e., width, W_bf; mean depth, D_bf; and cross‐section area, A_bf) are important design parameters in stream restoration, habitat creation, mined land reclamation, and related projects. The selection of values for these parameters is facilitated by regional curves (regression models in which Q_bf, W_bf, D_bf, and A_bf are predicted as a function of drainage area, A_da). This paper explores the potential for the two‐year return‐period discharge (Q₂) to improve predictions of W_bf, D_bf, and A_bf. Improved predictions are expected because Q₂ estimates integrate the effects of basin drainage area, climate, and geology. For conducting this study, 29 datasets (each representing one hydrologic region) spanning 14 states in the United States were analyzed. We assessed the utility of using Q₂ by comparing statistical measures of regression model performance (e.g., coefficient of determination and Akaike’s information criterion). Compared to using A_da, Q₂ is shown to be a “clearly superior” predictor of W_bf, D_bf, and A_bf, respectively, for 21, 13, and 25% of the datasets. By contrast, A_da yielded a clearly superior model for predicting W_bf, D_bf, and A_bf, respectively, for 0, 0, and 14% of the datasets. Our conclusion is that it alongside with developing conventional regional curves using A_da it is prudent to develop regional curves that use Q₂ as an independent variable because in some cases the resulting model will be superior.     

Chemical looping combustion for power generation—Concept study for a 10 MWth demonstration plant

A semi-commercial 10 MW_th chemical looping combustion (CLC) plant for power production is proposed as a next scale demonstration plant after successful operation of a 120 kW CLC pilot rig. The design criteria for the CLC boiler are derived from the experience obtained from the CLC pilot rig at Vienna University of Technology. The IPSEpro simulation environment is chosen for implementation of the process flow sheet of the CLC power plant. A single pressure steam cycle is suggested for this small scale demonstration plant. Heat exchangers and a five-stage steam turbine are arranged. Basic design parameters of the power plant are derived from detailed mass and energy investigations and discussed. It turns out that the net electric efficiency of such a small scale plant can be expected to be in the range of 32.5–35.8%. However, a demonstration of CLC at such a scale is necessary in order to gain confidence in more sophisticated CLC power generation concepts at larger scale.     

Impact of perceptual countermeasures on driving behavior at curves using driving simulator

Objective: The probability of crash occurrence on horizontal curves is 1.5 to 4 times higher than that on tangent sections. A majority of these crashes are associated with human errors. Therefore, human behavior in curves needs to be corrected.

Methodology: In this study, 2 different road marking treatments, optical circles and herringbone patterns, were used to influence driver behavior while entering a curve on a 2-lane rural road section. A driving simulator was used to perform the experiment. The simulated road sections are replicas of 2 real road sections in Flanders.

Results: Both treatments were found to reduce speed before entering the curve. However, speed reduction was more gradual when optical circles were used. A herringbone pattern had more influence on lateral position than optical circles by forcing drivers to maintain a safe distance from opposing traffic in the adjacent lane.

Conclusion: The study concluded that among other low-cost speed reduction methods, optical circles are effective tools to reduce speed and increase drivers’ attention. Moreover, a herringbone pattern can be used to reduce crashes on curves, mainly for head-on crashes where the main problem is inappropriate lateral position.     

Use of environmental DNA in assessment of fish functional and phylogenetic diversity

Assessing the impact of global changes and protection effectiveness is a key step in monitoring marine fishes. Most traditional census methods are demanding or destructive. Nondisturbing and nonlethal approaches based on video and environmental DNA are alternatives to underwater visual census or fishing. However, their ability to detect multiple biodiversity factors beyond traditional taxonomic diversity is still unknown. For bony fishes and elasmobranchs, we compared the performance of eDNA metabarcoding and long-term remote video to assess species’ phylogenetic and functional diversity. We used 10 eDNA samples from 30 L of water each and 25 hr of underwater videos over 4 days on Malpelo Island (pacific coast of Colombia), a remote marine protected area. Metabarcoding of eDNA detected 66% more molecular operational taxonomic units (MOTUs) than species on video. We found 66 and 43 functional entities with a single eDNA marker and videos, respectively, and higher functional richness for eDNA than videos. Despite gaps in genetic reference databases, eDNA also detected a higher fish phylogenetic diversity than videos; accumulation curves showed how 1 eDNA transect detected as much phylogenetic diversity as 25 hr of video. Environmental DNA metabarcoding can be used to affordably, efficiently, and accurately census biodiversity factors in marine systems. Although taxonomic assignments are still limited by species coverage in genetic reference databases, use of MOTUs highlights the potential of eDNA metabarcoding once reference databases have expanded.     

Performance and kinetics of iron-based oxygen carriers reduced by carbon monoxide for chemical looping combustion

Chemical looping combustion is a promising technology for energy conversion due to its low-carbon, high-efficiency, and environmental-friendly feature. A vital issue for CLC process is the development of oxygen carrier, since it must have sufficient reactivity. The mechanism and kinetics of CO reduction on iron-based oxygen carriers namely pure Fe₂O₃ and Fe₂O₃ supported by alumina (Fe₂O₃/Al₂O₃) were investigated using thermo-gravimetric analysis. Fe₂O₃/Al₂O₃ showed better reactivity over bare Fe₂O₃ toward CO reduction. This was well supported by the observed higher rate constant for Fe₂O₃/Al₂O₃ over pure Fe₂O₃ with respective activation energy of 41.1±2.0 and 33.3±0.8 kJ·mol⁻¹. The proposed models were compared via statistical approach comprising Akaike information criterion with correction coupled with F-test. The phase-boundary reaction and diffusion control models approximated to 95% confidence level along with scanning electron microscopy results; revealed the promising reduction reactions of pure Fe₂O₃ and Fe₂O₃/Al₂O₃. The boosting recital of iron-based oxygen carrier support toward efficient chemical looping combustion could be explained accurately through the present study.     

垃圾衍生燃料两段式化学链气化特性

提出了一种两段式化学链反应方式,并以Fe₂O₃为载氧体对生活垃圾衍生燃料（Refuse-Derived Fuel RDF）的化学链气化开展试验研究,分析了反应温度、载氧体含量、CaO的添加对载氧体气化性能的影响.结果表明,载氧体可以显著提高产气率,气化过程中产气率、碳转化率等均随着温度的升高而增大;随着载氧体含量的增加,CO、H₂的含量先增大后减小,在850 ℃、Fe₂O₃/C=0.15（物质的量比）时,含量最高.CaO的加入更进一步促进了焦油的裂解,提升产气率的同时,也起到了吸收CO₂的作用,改善了合成气的品质.通过X射线衍射（XRD）对反应后载氧体的组分进行了分析,结果发现,随着温度的提高,载氧体的释氧能力逐渐增强,850 ℃时,载氧体反应后被还原为FeO.