长江上游典型农业源溪流溶存氧化亚氮(N2O)浓度特征及影响因素

随着农业非点源氮（N）污染的加剧,农田周边溪流成为重要的活性N汇和潜在的氧化亚氮（N₂O）排放源.为查明长江上游农业源溪流中溶存N₂O浓度的全年动态变化特征,于2014年12月~2015年10月开展紫色土丘陵区典型农田源头溪流N₂O浓度的连续采样观测,采用水-气顶空平衡-气相色谱法测定顶空气体中N₂O浓度,根据相关参数计算出本研究水体中的溶存N₂O浓度,并同步测定溪流水体物理化学指标,分析水中溶存N₂O浓度的主要影响因素.结果表明,长江上游紫色土丘陵区的典型农业源溪流的硝态氮（NO₃^--N）是最主要的活性N赋存形态（年均1.45 mg·L^-1）,溪流水体溶存N₂O质量浓度（以N计）全年平均为0.57 μg·L^-1（范围0.26~1.28 μg·L^-1）,冬、春、夏和秋季的均值分别为0.63、0.45、0.53和0.64 μg·L^-1,但季节间无显著差异.溪流水体溶存N₂O浓度全年都处于过度饱和状态（饱和度年平均为203.9%,范围109.7%~546.5%）,可见,农业源溪流全年均为潜在的N₂O释放源.溪流溶存N₂O浓度的变化主要由水体NO₃^--N浓度决定,N₂O的主要产生机制为反硝化作用;溪流季节平均N₂O饱和度在夏、秋季显著高于冬、春季,水中溶存N₂O饱和度的变化主要受水温和NO₃^--N浓度的共同影响.研究还发现农业源溪流中溶存N₂O浓度在4~10月（湿润季节）间波动明显,较强降雨可促使其水中NO₃^--N浓度在雨后短期内升高,进而促进水体反硝化作用,导致雨后溪流中溶存N₂O浓度的增加.     

The habitat saturation hypothesis and sociality in an allodapine bee: cooperative nesting is not “making the best of a bad situation”

Several factors thought to be important for the evolution of cooperative breeding in vertebrates have received little attention in facultatively social insects. One of these, the “habitat saturation hypothesis” of Selander (1964), predicts that colony sizes will be greater in breeding units where dispersal opportunities are limited, suggesting that group living is a secondary option to independent reproduction. The Australian allodapine bee Exoneura bicolor exhibits a number of traits that occur in cooperatively breeding bird species, including long life-span, repeated opportunities for reproduction, and vulnerability to brood predation and parasitism. We experimentally examined the effect of a potentially limiting environmental factor, nesting substrate availability, as an agent influencing sociality in E. bicolor. We manipulated nesting substrate availability in two separate locations during a time when foundress dispersal is common. No significant difference was found between colony sizes in cases where dispersal options were abundant and cases where dispersal options were limited. An increase in opportunities for dispersal did not lead to higher rates of independent nesting, suggesting that cooperative nesting is a preferred strategy regardless of distance-related costs of dispersal. Reproductivity per female and brood survival were examined as factors selecting for group living. Low survival of brood in single-female nests has the potential to select for cooperative nesting in this bee. Received: 29 September 1995/Accepted after revision: 24 June 1996     

潜流湿地处理生活污水时的强化策略

研究在潜流湿地处理生活污水时通过预处理强化、介质优化和工艺改进克服现有技术缺陷的可行性.改进方法包括化学强化预处理、预曝气、添加氮吸附介质、添加磷吸附介质、湿地高浸润线、中浸润线、低浸润线和动态浸润线运行.结果表明,化学强化预处理不仅可以除磷,而且削减湿地污染负荷可使后续湿地面积减小63%,但是不能有效脱氮.预曝气仅使氨氮去除率提高了1%.添加氮吸附介质的有效时间短,运行前3个月对NH₄⁺-N去除率为84%,5个月后下降到64%.添加磷吸附介质的有效时间较长,可维持数年.因此,脱氮过程只有通过基质微生物实现.稳态浸润线下对COD、NH₄⁺-N、TN、TP的去除率,高浸润线湿地为50%、21%、32%、-26%;中浸润线湿地为53%、48%、48%、-14%;低浸润线湿地为74%、96%、35%、22%.提出动态浸润线及序批式潜流人工湿地工艺(CBSW),其对COD、NH₄⁺-N、TN、TP去除率为67%、62%、53%、33%.CBSW实现了单级湿地内好氧/缺氧环境的交替出现,提高了脱氮能力,除污综合表现最佳.     

天空蓝色饱和程度与城市空气质量等级的相关性

以大气散射理论为基础,结合颜色学、大气环境监测及城市空气质量日报等相关原理,从理论分析与实证研究2个方面证实了天空蓝色饱和程度与城市空气质量等级之间存在着显著的负相关性,即:天空蓝色饱和程度越低,空气污染等级越高,空气质量状况越差;天空蓝色饱和程度越高,空气污染等级较低,空气质量状况越好;通过相关及回归分析与检验,制得“城市空气质量等级目测色卡”,适用于晴朗天气肉眼观察天空颜色,进而目测估计空气质量等级状况,以采取必要防护措施。     

Geochemical Characteristics of the Acid Mine Drainage in the Water System in the Vicinity of the Dogye Coal Mine in Korea

This study investigated geochemical characteristics of the acid mine drainage (AMD) discharged from the abandoned mine adits in the vicinity of the Dogye coal mine in Korea. Acid mine drainage discharged from Jeoncha pit adit of the Dogye coal mine, which is the main source of the AMD in the study area, had a pH value of 3.0 and concentrations of 2148mg SO₄ ^2– L^–1, 229mg Fe L^–1, 71mg A1 L^–1 and 11mg Mn L^–1. The reduction of some metal concentrations downstream from the discharge point could be explained on the basis of dilution and precipitation. The order of removal of metal ions downstream from the discharge point was Fe>A1, Cu>Zn, Mn. Acidity could be used as a good determining factor offering comprehensive and quantitative values for the polluting extent of acid mine drainage. The acidities existing in all acidic water samples in the Gunahan district originated primarily from mineral acidity, especially in the upper Nahan Creek from dissolved Fe and Al and in the middle and down Nahan Creek from dissolved Al. From the application of the WATEQ4F program, it was determined that predominant species of dissolved Fe in all water samples was Fe²⁺, and those of dissolved Al were AlSO₄ ⁺ and Al³⁺ except for IW2 sample which was associated with white precipitates. The species of dissolved Al in IW2 sample include also AlOH²⁺ and Al(OH)₂ ⁺. The saturation indices of goethite and haematite were positive in the water samples associated with ochrous precipitates (usually called Yellow Boy), therefore these solids might be precipitated. For the IW2 sample, the saturation indices of amorphous Al(OH)₃ and gibbsite were positive, so theoretically these solids might also be precipitated. By XRD analysis, it was found that goethite occurs in ochrous precipitates, and gibbsite in white precipitates.     

CDM Forestry and the Ultimate Objective of the Climate Convention

In its Article 2, the U.N. Framework Convention on Climate Change policymakers gave themselves a long-term dynamic mandate under uncertainty. Taking the example of forestry activities in developing countries, the present article discusses whether land-based climate change mitigation measures in the context of compensation mechanisms for human-induced greenhouse gas emissions are covered under the UNFCCC's ultimate objective. Both the problem of climate change and human intervention act over long, yet finite timeframes. The article argues for taking a dynamic 100-year timeframe as reference for present-day activities. It concludes that increasing biotic carbon storage is legitimate for measures that contribute to biodiversity conservation, as long as it does not serve as a pretext for neglecting technological change. Among all forestry options, the list of priorities should be avoiding deforestation and devegetation, sustainable forest management, and afforestation. The problem of saturation can be encountered by the combination of forestry with the increased use of wood products and bioenergy. Concluding, the article gathers criteria for forest climate activities in the post-2012 regime. JEL Classification: Q23, Q54; Q57; Q58     

光纤光栅(FBG)传感器在尾矿库在线监测中的应用

光纤光栅(FGB)传感器已经广泛应用于水利工程监测中,在尾矿库在线监测系统中的应用也在逐步增多。为提高某尾矿库在线监测系统的抗干扰和运行稳定性,某尾矿库在线监测系统工程采用以光纤光栅传感器作为主要采集设备。应用结果表明:光纤光栅传感设备的突出优点是运行稳定性好、抗干扰能力强,测量精度满足使用要求;明显不足是安装条件要求高,前期投入较高。     

Integrating soil carbon cycling with that of nitrogen and phosphorus in the watershed model SWAT: Theory and model testing

In this paper we describe and test a sub-model that integrates the cycling of carbon (C), nitrogen (N) and phosphorus (P) in the Soil Water Assessment Tool (SWAT) watershed model. The core of the sub-model is a multi-layer, one-pool soil organic carbon (S_C) algorithm, in which the decomposition rate of S_C and input rate to S_C (through decomposition and humification of residues) depend on the current size of S_C. The organic N and P fluxes are coupled to that of C and depend on the available mineral N and P, and the C:N and N:P ratios of the decomposing pools. Tillage explicitly affects the soil organic matter turnover rate through tool-specific coefficients. Unlike most models, the turnover of soil organic matter does not follow first order kinetics. Each soil layer has a specific maximum capacity to accumulate C or C saturation (S_x) that depends on texture and controls the turnover rate. It is shown in an analytical solution that S_x is a parameter with major influence in the model C dynamics. Testing with a 65-yr data set from the dryland wheat growing region in Oregon shows that the model adequately simulates the S_C dynamics in the topsoil (top 0.3 m) for three different treatments. Three key model parameters, the optimal decomposition and humification rates and a factor controlling the effect of soil moisture and temperature on the decomposition rate, showed low uncertainty as determined by generalized likelihood uncertainty estimation. Nonetheless, the parameter set that provided accurate simulations in the topsoil tended to overestimate S_C in the subsoil, suggesting that a mechanism that expresses at depth might not be represented in the current sub-model structure. The explicit integration of C, N, and P fluxes allows for a more cohesive simulation of nutrient cycling in the SWAT model. The sub-model has to be tested in forestland and rangeland in addition to agricultural land, and in diverse soils with extreme properties such high or low pH, an organic horizon, or volcanic soils.     

Application of Light Reflection Visualization for Measuring Organic-Liquid Saturation for Two-Phase Systems in Two-Dimensional Flow Cells

Abstract A simple, noninvasive imaging technique was used to obtain in situ measurements of organic-liquid saturation in a two-phase system under dynamic conditions. Efficacy of the light reflection visualization (LRV) imaging method was tested through comparison of measured and known volumes of organic liquid for experiments conducted with a two-dimensional flow cell. Two sets of experiments were conducted, with source-zone configurations representing two archetypical residual-and-pool architectures. LRV measurements were collected during the injection of organic liquid and during a dissolution phase induced by water flushing. There was a strong correlation between measured and known organic-liquid volumes, with the LRV-measured values generally somewhat lower than the known volumes. Errors were greater for the system wherein organic liquid was present in multiple zones comprised of porous media of different permeabilities, and for conditions of multiphase flow. This method proved effective at determinin...     

填埋场内温度场下渗滤液饱和带内硫酸盐还原行为表征

填埋场内渗滤液饱和带是物质交换和生化反应的活跃区域,也是含硫恶臭的主要发生源.本研究探究了填埋场内温度场下渗滤液饱和带内硫酸盐还原行为特征,结果表明,在25～55℃逐步升温的温度场下,渗滤液饱和带内的硫酸盐还原行为逐步增强且差异显著.渗滤液饱和带纵向SO42-和DOC迁移转化规律各异但趋势相同.硫酸盐还原行为主要发生在固液交界区和固相区,且固液交界区的电子供、受体呈特定化学计量关系.电子供体是引起硫酸盐还原行为差异的主要原因.本研究揭示的温度场下渗滤液饱和带内硫酸盐还原行为可为填埋场精准除臭提供重要依据.