白果壳遗态Fe/C复合材料对水中磷的吸附特征

为研究PBGC-Fe/C-G（白果壳遗态Fe/C复合材料）对水中磷的吸附特征,以PBGC-Fe/C-G为吸附剂,对吸附剂投加量、溶液体系pH、初始磷质量浓度、温度和吸附剂粒径为影响因素进行静态吸附试验分析,并结合SEM、EDS、XRD和FT-IR等手段对吸附前、后材料进行表征,以揭示PBGC-Fe/C-G的吸附除磷机制.结果表明:①当初始磷质量浓度 < 10 mg/L、吸附剂投加量为0.2 g/（50 mL）、溶液为酸性（pH=3）、反应温度为45℃、吸附剂粒径 < 0.149 mm时,吸附效果最佳,吸附量达1.62 mg/g.②准二级动力学模型和Freundlich吸附等温模型能较好地模拟PBGC-Fe/C-G对磷的吸附过程.③热力学结果显示,ΔG < 0、ΔS>0和ΔH>0,说明PBGC-Fe/C-G对磷的吸附过程是自发、熵增的吸热过程.研究显示,PBGC-Fe/C-G吸附除磷主要通过配位作用、静电引力、等电荷离子交换和物理作用4种协同完成,其中Fe活性位与磷酸根离子的配位反应为主要的反应过程.      

国家重点文物旅游资源的开发利用--以河南省为例

河南是我国重点保护文物（以下简称重点文物）大省，众多的古建筑、古遗址、古墓葬是河南旅游的主要吸引物。文章从分析了河南重点文物的开发现状，发现其文物旅游的优势和劣势，并结合均衡开发、循序渐进、三个效益并行、尊重历史剖面四个原则，提出了文物开发的五个策略：理顺管理体制、实现开发主体多元化、发挥自身优势突出特色旅游、加强基础设施建设和人才培养、加大营销力度、把科技引入文物开发。     

黑白显像管玻壳铅尘中铅的提取方法

研究了黑白显像玻壳生产中产生的含铅粉尘的水溶性,酸溶性,浸出毒性和铅的存在形态,提出了用盐酸循环浸铅,冷析ＰｂＣｌ２的提铅方法,考察了浸取剂及浓度,浸取温度,浸取时间对铅浸出率的影响,为充分利用铅资源及实现铅尘无害化提供了依据。     

等边双圆锥台壳体端部约束胀形的实验研究

针对等边双圆锥台壳体在自由胀形过程中 ,赤道环焊缝处产生失稳起皱现象 ,提出了壳体的内约束胀形工艺 ,实验证明 ,壳体端部加约束后成形过程中没有起皱现象发生     

简析近年噪声环境影响评价中出现的错误预测模式

分析了环评中噪声源置于厂房内预测厂区内外噪声的错误模式,指出这些模式只能计算出不反映实际声场分布的同心族圆的等声级线,对环评工作毫无意义.其根本错误在于将壳体组合结构的整体隔声能力当作其各部位的实际隔声能力,而且忽略客观实际环境、甚至无视厂房存在所致.     

Investigation of acetaminophen adsorption with a biosorbent as a purification method of aqueous solution

ABSTRACT

Pharmaceutical compounds are considered emerging environmental pollutants that have a potential harmful impact on environment and human health. In this study, the spiky green horse-chestnut shell was used for the biosorption and removal of acetaminophen from aqueous solution. It was analysed how the parameters, like contact time, pH, mass of biosorbent and temperature, influence the effectiveness of acetaminophen removal from aqueous solutions. The equilibrium was quickly achieved after 10?min (～60%). The amount of acetaminophen adsorption slightly increased with the increase of the mass of biosorbent, and for example for an aqueous solution containing 10?mg/L of acetaminophen adsorption was increased from 62% to 81%. The promising results obtained at pH ranged between 2 and 9, which shows that the adsorption of acetaminophen did not depend on the pH and it may be a consequence of the predominant microporous sorbent and its surface charge. The result is better correlated to a pseudo-second-order kinetic model of type 2 (r ²?=?0.9992) than pseudo-first-order. A sorption mechanism of acetaminophen on biosorbent was also proposed. The sorption of acetaminophen over biosorbent is mainly preceded by hydrophilic interactions between hydroxyl and carbonyl groups in pharmaceutical molecules and hydroxyl and carboxyl groups on the surface of biosorbent.     

Double-Arranged Mound-Mounted Shelterbelts: Influence of Porosity on Wind Reduction between the Shelters

Using a two-dimensional LDA-System, measurements in an atmospheric boundary layer wind tunnel have been made in the intermediate field of double-arranged, mound-mounted shelterbelts. The porosity of the shelterbelts ranged from 0% to 52%. For each porosity, seven different distances of the two windbreaks between 5 and 25 times the windbreak height were investigated. The efficiency of the windbreak systems is assessed by means of protection parameters considering the change of horizontal momentum on bodies immersed in the flow, of pedestrian comfort conditions and of momentum exchange in vertical direction. Furthermore recirculation zones and the change of kinetic energy are shown. The measurement results are given in the form of contour plots indicating flow quantities and protection volumes between the two windbreaks. The shelter efficiency of the investigated windbreak systems is compared to that of adequate single line windbreaks. It is shown that for certain windbreak configurations the wind-protected area in the intermediate field of consecutively arranged windbreaks becomes larger in comparison to a single windbreak.     

nZVI@mesoSiO2的可控合成及应用性能研究

采用改进的两步法在原位基础上合成了以纳米零价铁(nano Zero Valent Iron,nZVI)为核芯的核壳型介孔二氧化硅(nZVI@mesoSiO_2).同时,通过简单地调控铁源用量得到具有单一nZVI核芯和不同壳层厚度的核壳型纳米复合材料.结果发现,铁源用量的增加会导致核芯尺寸减小、壳层厚度增加及颗粒比表面积下降.当铁源用量为2.78 g时,得到的nZVI@mesoSiO_2不仅具有较高的比表面积和单一且均匀的孔径分布,而且对2,4,6-三氯苯酚(2,4,6-Trichlorophenol, 2,4,6-TCP)的去除表现出很高的性能.影响因素实验表明,材料的最佳投加量为1.0 g·L~(-1),体系适宜初始pH为5.0,污染物初始浓度升高会导致去除效果下降,并且反应体系内乙二胺四乙酸(EDTA)的存在可以提高2,4,6-TCP的去除率.材料的重复利用实验结果表明,经过多次循环反应后会导致材料nZVI核芯的失活和孔道的堵塞.本研究不仅为制备可控壳层厚度的核壳型介孔材料提供了理论指导,而且为进一步改性合成对2,4,6-TP具有高选择性的复合材料提供了依据.     

炭化核桃壳对废水中Cr（Ⅵ）的吸附

制备了炭化核桃壳,采用SEM,EDX,FTIR等方法对炭化核桃壳进行了表征,研究了炭化核桃壳对废水中Cr（Ⅵ）的吸附效果。表征结果显示,炭化后的核桃壳为片状结构,且形成了大量的微孔,微孔数量的增加使得核桃壳的比表面积明显增大。实验结果表明,炭化核桃壳吸附处理含Cr（Ⅵ）废水的最佳工艺条件为：初始废水pH 2.0、炭化核桃壳加入量16 g/L、吸附温度25 ℃、转速150 r/min、吸附时间180 min,在此最佳工艺条件下吸附处理Cr（Ⅵ）质量浓度为20 mg/L废水,Cr（Ⅵ）去除率高达98.7%,最大吸附量为8.731 mg/g。Langmuir吸附等温模型可更好地描述炭化核桃壳对Cr（Ⅵ）的吸附过程,吸附属于单分子层吸附。拟二级动力学方程能更好地描述炭化核桃壳对Cr（Ⅵ）的吸附行为,此吸附过程以化学吸附为主控步骤。     

核桃壳滤料用于处理含油、含浊废水的试验研究

考察了在不同粒径、不同滤速和混凝剂不同投加量的情况下。核桃壳滤料对洗井废水中油和浊度的去除效果。经试验比较，最后确定粒径范围为0．45～0．9mm，最佳滤速为10m／h，混凝剂投加量为10mg／L。