Polyphenylene sulfide based anion exchange fiber: Synthesis, characterization and adsorption of Cr(VI)

A fibrous strong base anion exchanger (QAPPS) was prepared for the first time via chloromethylation and quaternary amination reaction of polyphenylene sulfide fiber (PPS), and its physical-chemical structure and adsorption behavior for Cr(VI) were characterized by FT-IR, Energy Dispersive Spectrometry, TG-DTG, elemental analysis and batch adsorptive technique, respectively. The novel fibrous adsorbent could effectively adsorb Cr(VI) over the pH range 1-12, the maximum adsorption capacity was 166.39 mg/g at pH 3.5, and the adsorption behavior could be described well by Langmuir isotherm equation model. The adsorption kinetics was studied using pseudo first-order and pseudo second-order models, and the t_1/2 and equilibrium adsorption time were 5 and 20 min respectively when initial Cr(VI) concentration was 100 mg/L. The saturated fibers could be regenerated rapidly by a mixed solution of 0.5 mol/L NaOH and 0.5 mol/L NaCl, and the adsorption capacity was well maintained after six adsorption-desorption cycles.     

新概念消防车的发展

分析了新概念消防车的发展现状,介绍了新概念消防车目前主要开发的品种、灭火原理、特点及结构等,可应用于扑灭石油化工企业火灾、大跨度建筑物火灾、地下工程火灾、飞机火灾等多方面。     

粤闽交界中强地震前水化学异常特征分析

研究了粤闽交界90年以来ML≥4.5地震前水化学前兆资料,结果表明:(1)水化学前兆异常形态复杂多样,以短期和短临变化为主;(2)同一台站震前所观测的异常变化具有多测项同步异常的特征;(3)震前异常持续时间、异常形态与震中距有关。同时研究表明,统计水化学异常出现的集中程度无法判定未来震中位置。     

大断面巷道中空预应力注浆锚杆的支护效果研究

针对金川矿区大断面巷道在强构造应力作用下围岩变形严重的情况,提出了中空预应力注浆锚杆的支护工艺。通过数值计算得出以下结论:相比传统的普通砂浆锚杆支护工艺,采用中空预应力注浆锚杆支护工艺能够主动加固围岩,提高支护刚度;巷道两帮的变形减小了约14.56%,最大、最小主应力分别降低了4.4%和7.2%,粘结层破坏范围也随之减小。通过对支护后巷道变形监测发现:两帮最终变形量减小了约36.6%;通过抗拔实验,中空预应力注浆锚杆的抗拔力达到140kN,远大于普通砂浆锚杆的40kN抗拔力,中空预应力注浆锚杆有更好的支护效果。     

地表夯击载荷作用下埋地管道力学分析

为研究地基强夯作业中夯击载荷对埋地管道力学性能的影响,基于有限元原理建立了夯锤-管道-围土耦合三维模型,分析了夯击过程中管道截面变形及所受冲击力变化规律,研究了管道壁厚、夯击速度、夯锤体积对管道应力、应变及变形的影响规律。结果表明:夯击载荷下的管道所受冲击力为脉冲型,且随时间推移逐渐降低为0,最大冲击力随管道壁厚、夯击速度、夯锤体积增大而增大;管道最大等效应力、高应力范围及最大等效塑性应变随壁厚增加而减小,但随夯击速度或夯锤体积增大而增大;随着夯击速度、夯锤体积增大,管道截面变形率（椭圆度或凹陷率）逐渐增大,但其随壁厚增加而减小。     

Acid aerosols in the Pittsburgh Metropolitan area

This article presents data on ambient concentrations of selected acidic aerosols at four existing monitoring sites in the Pittsburgh PA metropolitan area. The data were collected by staff of the Allegheny County Health Department, Division of Air Quality during the summer and fall of 1993. The sampling protocol was focused on obtaining 24 h-average ammonia, ammonium, acidic sulfates, and particle strong acids data on a 2 to 3 day cycle. The data were obtained using Harvard University School of Public Health's “Short-HEADS” annular denuder sampling train. The Pittsburgh area is of interest because it is downwind of a major regional source of sulfur and nitrogen emissions from coal-burning power plants: the Ohio River Valley. The data presented here indicate that ground-level concentrations of acidic aerosols in Pittsburgh are highly correlated spatially and that many pollutants are higher on days when ground-level wind direction vectors indicate that wind is coming from the southwest rather than from the Pittsburgh source area itself. The monitoring site that is most upwind of the Pittsburgh source area – South Fayette – has particle strong acid levels about twice those of sites closer in to the Pittsburgh central business district.     

北川县城汶川地震震害特征及其成因探讨

根据笔者在汶川大地震极震区北川县城现场考察的第一手资料,分析了2008年5月12日汶川8.0级大地震后北川县城的震害特征,论述了北川县城地震后建筑物、生命线工程的破坏以及次生地质灾害;并对造成各类震害的原因进行了初步的探讨。最后,在总结震害特征及其成因的基础上,提出了当前应加强研究的相关课题,旨在为今后的工程抗震设防和研究提供参考。     

Pt-Cu/TiO2{001}纳米片用于CO2加氢制甲醇反应的研究

以高暴露{001}晶面的TiO₂纳米片为载体,利用共还原法负载0.5%的Pt和一定量的Cu得到Pt-Cu/TiO₂{001}催化剂,并在P=3.0 MPa,T=200~300℃,V（N₂）：V（H₂）：V（CO₂）=8：69：23,空速（WHSV）=3600 mL·g^-1·h^-1反应条件下评价了催化剂催化CO₂加氢制甲醇的反应性能.XRD、XPS、EPR和CO₂-TPD等的表征表明,与催化剂Cu/TiO₂相比,引入Pt后,催化剂由于金属Pt的电子促进作用使负载的金属与载体之间的相互作用更强,进而有利于稳定Cu颗粒尺寸且载体形成了更多缺陷（如氧空位、Ti³⁺）.因此,Pt-Cu/TiO₂{001}催化剂的金属与载体界面上的活性位点更多,从而表现出更好的CO₂活化能力和甲醇生成性能.     

农田排水对地表水环境影响的调查

中国是农业大国,以保障食品供应安全为前提的农耕生产,还未将生态环境保护纳入生产过程进行管理。为进一步了解农耕生产对地表水环境的影响,支撑未来生态环境管理需求,选取具有代表性的独立水田和旱田作为实验区块,在备耕期追加底肥,泡田时段和农作物生长期施加农药、化肥、除草剂、杀虫剂等各个农事环节前后时段,跟踪监测实验区块内积水、外排水、周边受纳水体在实验区块排水前后的水质变化情况,共设置27个监测点位,收集4 184个实验数据。实验显示:农田排水会污染地表水环境,污染具有冲击性,且与农药和化肥的施用时间、种类和数量密切相关,并随农田农药和化肥肥效衰减而逐渐降低直至消失。     

福建地磁总强观测资料综合处理与讨论

运用AUTOCAD软件对福建省龙岩、永安、邵武、漳州、同安、泉州六个台站的1982年1月1日至2002年12月31日总强观测资料,进行处理分析.所得结果不仅表明六个台站的磁场变化特征较为明显,同步变化具有很强的吻合性,而且客观地反映了各台站小范围背景场磁场干扰、仪器工作状态不佳、少量数据质量差、数据连续性差等问题.本文还对数据的使用、台湾强震群与福建磁场变化特征提出了分析意见.这些在很大程度上可以为数字化观测数据的分析使用提供借鉴,为进一步提高和完善观测质量提供参考依据.