Evaluation of the spontaneous combustion characteristics of coal of different metamorphic degrees based on a temperature-programmed oil bath experimental system

Research on the micro- and macrocharacteristics of different metamorphic degrees of coal helps improve the control and protection techniques used during spontaneous combustion. Nine coals with different properties were thoroughly investigated in this study. Fourier transform infrared spectroscopy and a self-designed temperature-programmed oil bath experimental system were adopted to analyze the molecular structure and macrocharacteristic parameters of the spontaneous combustion of coal. Additionally, the influence of particle size on spontaneous combustion was considered. Various functional groups were employed as microcharacteristic parameters to capture the principal active groups in oxidation. The gas production rate, oxygen consumption rate, gas concentration, heat energy release rate, and characteristic temperatures were evaluated as macrocharacteristic parameters to investigate the changes in coal during oxidation. The results establish that the microcharacteristics of coal molecules determine the degree of spontaneous combustion based on intrinsic properties and that changes in the macrocharacteristics of the spontaneous combustion of coal reflect the microstructural changes. The contents of the hydroxyl groups, carbonyl groups, alkyl ether and aryl ether in the coal molecules gradually decrease with the metamorphic increase. Oxygen-containing functional groups have higher reactivities and easily react with oxygen, causing the macroparameters, such as the oxygen consumption rate, the gas generation rate and the heat energy release rate, to consistently decrease with the increase of the metamorphic degree. Small-particle-size coal molecules have more active aliphatic hydrocarbons, oxygen-containing functional groups and a larger specific surface area, increasing the chances of adsorbing the oxygen of active groups and promoting the reaction between coal and oxygen. The experimental results indicate that coal samples with higher metamorphic degrees or larger sizes exhibit lower tendencies toward spontaneous combustion. Evaluation of the spontaneous combustion of coal based on a temperature-programmed oil bath experimental system is of great practical importance for preventing the spontaneous combustion of coal during storage, processing and utilization and can serve as a convenient reference for production safety in mining applications.     

基于健康度分析的电网单元设备集可靠性评估研究

电网作为一类关键基础设施,能否安全稳定运行直接关系到社会的安全稳定以及经济发展。对电网进行可靠性评估,找到薄弱环节并给予增强稳固来提高电网整体抗扰性,降低电网风险,具有重要现实意义。在构建电网网络结构中节点单元的可靠性评估模型时,以设备可靠性模型为基础,将电网设备的健康度分析、老化度分析引入可靠性评估模型,一定程度上减少了可靠性评估模型中人为主观因素的影响;同时,将动态健康度预测和静态健康度总结进行综合,减少了各自评估的缺点,为可靠性评估提供了更为准确的变量信息,能够更为准确的区分不同设备的安全性程度。通过评估模型的构建和Q市电网算例的应用,表明该模型可以有效、快捷的衡量电网设备信息,为电网一线工作人员提供了较为方便的评估手段。     

水中总硬度测量不确定度的评定

采用EDTA滴定法测定水质总硬度的测量不确定度评定。充分考虑测量重复性、标准溶液的配制、滴定等过程对测量的影响,计算水中总硬度的测量相对合成标准不确定度为1·81×10-3。     

Level of coordinated development in economy and environment

ＬｅｖｅｌｏｆｃｏｏｒｄｉｎａｔｅｄｄｅｖｅｌｏｐｍｅｎｔｉｎｅｃｏｎｏｍｙａｎｄｅｎｖｉｒｏｎｍｅｎｔＺｈａｎｇＱｉｄｅ，ＷａｎｇＹｕｘｉｕ，ＲｅｎＪｉｎｓｏｎｇＬｉａｏｎｉｎｇＩｎｓｔｉｔｕｔｅｏｆＥｎｖｉｒｏｎｍｅｎｔＰｒｏｔｅｃｔｉｏｎＳｃｉ...     

基于物元可拓模型的尾矿库溃坝风险评价研究

为准确的评价尾矿库溃坝风险等级,建立了物元可拓评价模型:首先确定风险评价指标体系与评价标准,通过隶属函数对评价标准进行隶属化,解决其因特征值超出节域范围导致关联函数失效问题与因量纲不一致而造成的不可公度性问题;然后确定其经典域、节域与待评物元,为评价尾矿库溃坝风险等级提供前提条件;再通过计算简单关联函数值与初等关联函数值,确定各评价指标的权重与各等级的可拓关联度;最后依据最大关联原则,确定风险等级,并计算等级变量特征值以更准确的评价其等级。工程实例应用表明,该方法应用于尾矿库溃坝风险评价准确、符合实际情况。     

沿海城市经济与环境协调关系的时空演变分析

运用耦合协调模型和空间相关性模型研究了2006—2016年53个沿海城市的经济发展与生态环境协调关系的时空演变趋势、重心迁移、空间相关性。结果表明:我国沿海城市经济发展与生态环境的协调发展状况总体呈向好态势,但总体协调度不高,仍处于协调发展的初级阶段;协调度发展存在严重的空间不均衡性,且呈逐步扩大态势,高值区域主要分布在省会城市和计划单列市,而其他大部分城市仍处于失调状态;2006—2016年协调度重心均位于浙江省金华市,并逐步向西南方向迁移;全局Moran’s I指数和局部Moran散点图显示协调度在空间上呈现明显的正相关,空间集聚性较强。     

流沙湾海域水质的综合评价与分析

以流沙湾2008年4个航次水质监测数据资料为依据,选择具有代表性的9种监测指标,分别采用模糊综合评价法和模糊贴近度法进行海水水质评价比较与分析,得出流沙湾海域水质评价等级。研究结果表明,流沙湾海域冬夏季节的水环境质量差于春秋两季,其中夏季水质最差。将整年水质监测指标平均值进行综合评价,结果表明,流沙湾各站位均符合二类水质标准。以模糊贴近度法作为主要评价方法、以模糊综合评价法作为辅助评价方法进行综合评价,更有利于流沙湾海域水质的整体分析。研究结果可作为流沙湾海域水产养殖规划和整治的参考依据,为将来合理开发利用流沙湾海域提供科学依据。     

Influence of vacuum degree on the effect of gas explosion suppression by vacuum chamber

In order to study the influence of vacuum degree on gas explosion suppression by vacuum chamber, this study used the 0.2 mm thick polytetrafluoroethylene film as the diaphragm of vacuum chamber to carry out a series of experiments of gas explosion suppression by vacuum chamber with the vacuum degree from −0.01 MPa to −0.08 MPa. The experimental results show that: under the condition of any vacuum degree, vacuum chamber can effectively suppress the explosion flame and overpressure; as vacuum degree changes, the effect of gas explosion suppression using vacuum chamber is slightly different. Vacuum chamber has obvious influence on propagation characteristics of the explosion flame. After explosion flame passes by vacuum chamber, the flame signal weakens, the flame thickness becomes thicker, and the flame speed slows down. With the increase of the vacuum degree of vacuum chamber, the flame speed can be prevented from rising early by vacuum chamber. The higher the vacuum degree is, the more obviously the vacuum chamber attenuates the explosion overpressure, the smaller the average overpressure is, and the better effect of the gas explosion suppression is. Vacuum chamber can effectively weaken the explosion impulse under each vacuum degree. From the beginning of −0.01 MPa, the vacuum chamber can gradually weaken explosion impulse as the vacuum degree increases, and the effect of gas explosion suppression gradually becomes better. When the vacuum degree is greater than −0.04 MPa, the increase of vacuum degree can make the explosion overpressure decrease but have little influence on the explosion impulse. Therefore, the vacuum chamber has the preferable suppression effect with equal to or greater than −0.04 MPa vacuum degree.     

两性聚丙烯酰胺的制备研究

本文研究了丙烯酰胺（ＡＭ）－丙烯酸（ＡＡ）共聚物的水溶液，经Ｍａｎｎｉｃｈ反应制备两性聚丙烯酰胺的反应条件，讨论了影响胺化度的因素。实验结果表明：分子量为３００万、阴离子度为２０％、浓度为２．５％的共聚物，在原料配比为（ＡＭ－ＡＡ）：ＨＣＨＯ：ＮＨ（ＣＨ３）２＝１：１．１：１．５、反应温度为５０±１℃、反应２ｈ的条件下，制得的两性聚丙烯酰胺的胺化度为４２．５％，是最佳的合成条件。用氯化胺和盐酸季胺     

污水在水体中的稀释扩散及稀释度的计算

结合长江白龙港水域水力模型试验对污水排海工程中污水稀释扩散的机理进行了描述，并对污水的两种稀释度（浓度释稀度和体积稀释度）进行了分析比较，得出了在污染物本底值存在时两种稀释度之间的关系。