独头巷道受限贴附射流有效射程的 理论研究与数值计算

为了探讨独头巷道受限贴附射流通风有效射程,利用巷道断面面积与风筒出流射流直径,定义了独头巷道射流的受限程度,采用理论分 析与数值计算方法,推导了受限射流无因次距离与沿程断面位置、断面流量和断面平均流速之间的关系式,建立了独头巷道受限贴附射流流动 特性模型。利用该模型,开展了8个不同工况下受限贴附射流的数值计算。结果表明,在受限的情况下,射流区无因次最大截面积出现在无因次 距离为0.200 0处,而无因次最大截面流量位于无因次距离为0.187 5处。理论推导和计算结果表明,所得模型和计算方法能更为准确预测受限 贴附射流的有效射程。     

海平面上升对珠江口水位影响的分析

珠江三角洲水位变化存在着大量不确定性、不精确性,这些特性既具有模糊特征,也具有灰色特征。在分析珠江三角洲灯笼山站年平均水位的变化特征和闸坡站海平面变化趋势的基础上,利用灰关联法分析代表站灯笼山站年平均水位与流量、海平面、潮差等8个因素的关系,年平均水位与影响因素之间的灰关联度均大于0.7,说明各因子对年平均水位均产生显著影响,其中海平面变化与年平均水位的灰关联度为0.736,说明海平面变化是年平均水位的重要影响因素。选取灰关联度较大的（马＋三）流量、闸坡站海平面、灯笼山站的年最高水位、年最低水位、年平均低潮、年平均潮差这6个指标进行主成分分析。结果表明：第一主成分为径流潮汐作用,第二主成分的代表因素为海平面上升,第三主成分的代表因素为年最高水位;其中海平面上升为代表的第二主成分对年平均水位的贡献率为20.1%。因此,海平面上升对灯笼山站年平均水位的影响虽然弱于径流潮汐作用,但其影响也是显著的。     

集约化蔬菜地土壤磷素累积特征及流失风险

以南京市郊集约化蔬菜长期种植基地为对象,采集蔬菜种植年限分别为3~5、15~20、25~30 a的土壤,测定土壤全磷(TP)、速效磷(Olsen-P)、水溶性磷(CaCl2-P)、生物有效磷(NaOH-P)的含量,并对0—20 cm土层磷素吸附特性进行分析,通过研究土壤磷吸附饱和度(DPS)、最大缓冲容量(MBC)来对土壤磷素流失风险进行评估。结果表明,在0—20 cm土层,除NaOH-P外,其余各形态磷(TP、Olsen-P、CaCl2-P)都随种植年限延长呈增加趋势。不同种植年限土壤TP、Olsen-P、CaCl2-P、NaOH-P主要积累在0—20 cm土层,且随着土层深度的增加土壤磷的累积量逐渐降低。DPS随种植年限延长而升高,种植年限25~30 a的菜地0—5 cm土层DPS超过土壤磷素流失环境敏感指标临界值(25%),其MBC也最低,表明随着蔬菜种植年限的延长土壤磷素流失风险加剧,且流失风险主要体现在0—5 cm土层。     

Properties of Starch/PVA Blend Films Containing Citric Acid as Additive

Starch/polyvinyl alcohol (PVA) blend films were prepared successfully by using starch, polyvinyl alcohol (PVA), glycerol (GL) sorbitol (SO) and citric acid (CA) for the mixing process. The influence of mixing time, additional materials and drying temperature of films on the properties of the films was investigated. With increase in mixing time, the tensile strength (TS), elongation (%E), degree of swelling (DS) and solubility (S) of the film were equilibrated. The equilibrium for TS, %E, DS and S value was 20.12 MPa, 36.98%, 2.4 and 0.19, respectively. The mixing time of equilibrium was 50 min. TS, %E, DS and S of starch/PVA blend film were examined adding glycerol (GL), sorbitol (SO) and citric acid (CA) as additives. At all measurement results, except for DS, the film adding CA was better than GL or SO because hydrogen bonding at the presence of CA with hydroxyl group and carboxyl group increased the inter/intramolecular interaction between starch, PVA and additives. Citric acid improves the properties of starch/PVA blend film compared to glycerol and sobitol. When the film was dried at low temperature, the properties of the films were clearly improved because the hydrogen bonding was activated at low temperature.     

区域PREE系统协调发展的定量描述

本文阐述了区域人口、资源、环境、经济(PREE系统)协调发展的含义,建立了定量描述PREE系统发展的协调度公式,并将其应用于盘锦市,描述了该市的发展状况,对该市今后的发展提出了建议。     

安徽省资源、环境、经济系统协调发展评价

以系统科学思想为基础，根据1990-2005年间安徽省的资源、环境与经济发展的实际情况，构建了一套分层次的协调发展评价指标体系，并运用主成分方法、坎蒂雷赋权法将相应层次的指标进行综合，根据协调发展的含义建立数学模型，从协调度、协调发展度、协调发展趋势指数的角度定量分析了安徽省资源、环境、经济系统协调发展的状况。该研究思路可作为其它地区在进行同类分析时提供参考。     

LNG储罐火灾和爆炸事故树分析

对引起液化天然气储罐发生火灾、爆炸的因素进行系统分析,建立以LNG储罐火灾、爆炸为顶事件的事故树,并进行事故树分析,得到影响顶事件的各阶最小割集。利用二次计算的方法,更加精确地计算底事件的结构重要度系数,确定了影响储罐事故的主要因素,为提高LNG储罐的安全性和运行可靠性,提出相应的改进措施。     

Effect of Degree of Substitution of Octenyl Succinate Starch on the Emulsification Activity on Different Oil Phases

Octenyl succinic starch (OSA starch) was synthesized from an aqueous medium and pyridine medium using previously established literature methods. Such a substitution would conceivably impart some hydrophobicity to the already hydrophilic starch chain. Thus, an amphiphilic character could be introduced wherein while the water solubility of the final product would be retained or enhanced, interactions with hydrophobic phases could be enhanced. These products find a variety of applications. The emulsifying activity of OSA starch was tested against different oil phases. It was found that the activity was dependent on the oil phase chosen. The activity was largely independent of the concentration of the substrates when the modification was conducted in an aqueous medium. Products from an organic medium did show an increase in activity with concentration. This difference in activity was attributed to the molecular weight of the final product, which seemed to be lower for the products from an organic medium as suggested by viscometry. The granular state of starch could also have a great effect on the properties of modified starch.     

Degradation of Cellulosic Materials Under the Alkaline Conditions of a Cementitious Repository for Low- and Intermediate-Level Radioactive Waste. II. Degradation Kinetics

The degradation of cellulosic materials, differing mainly in the degree of polymerization and the number of reducing end groups, was studied under the alkaline conditions similar to those existing in a cementitious repository for low- and intermediate-level radioactive waste (pH 13.3, T = 25°C). The kinetics of alkaline degradation (peeling-off reaction) were studied and the data analyzed by the model of Haas et al. [13]. The observed kinetic parameters for the propagation reaction and overall stopping reaction were compared with literature data. Although measured under different experimental conditions, literature data and data from this study show a consistent picture. Differences in the extent of degradation observed for the different cellulosic materials could be satisfactorily explained by differences in reducing end group content and, consequently, by differences in the degrees of polymerization. Besides the number of reducing end groups, the degree of amorphousness also plays an important role. The main degradation products formed under the experimental conditions used are - and -(gluco)isosaccharinic acid. This is in agreement with many other studies on alkaline degradation of cellulose. The two isomers are formed in roughly equal amounts.     

矿井(煤矿)通风系统安全度

分析了矿井（煤矿）通风系统的安全性,提出了评价矿井通风系统安全性的指标,确定了矿井通风系统安全性等级。