全文获取类型
收费全文 | 441篇 |
免费 | 43篇 |
国内免费 | 188篇 |
专业分类
安全科学 | 82篇 |
废物处理 | 16篇 |
环保管理 | 33篇 |
综合类 | 345篇 |
基础理论 | 70篇 |
污染及防治 | 60篇 |
评价与监测 | 35篇 |
社会与环境 | 13篇 |
灾害及防治 | 18篇 |
出版年
2024年 | 3篇 |
2023年 | 9篇 |
2022年 | 21篇 |
2021年 | 20篇 |
2020年 | 24篇 |
2019年 | 18篇 |
2018年 | 20篇 |
2017年 | 20篇 |
2016年 | 26篇 |
2015年 | 27篇 |
2014年 | 32篇 |
2013年 | 42篇 |
2012年 | 43篇 |
2011年 | 59篇 |
2010年 | 36篇 |
2009年 | 22篇 |
2008年 | 31篇 |
2007年 | 42篇 |
2006年 | 23篇 |
2005年 | 24篇 |
2004年 | 15篇 |
2003年 | 16篇 |
2002年 | 12篇 |
2001年 | 11篇 |
2000年 | 8篇 |
1999年 | 9篇 |
1998年 | 15篇 |
1997年 | 9篇 |
1996年 | 6篇 |
1995年 | 7篇 |
1994年 | 5篇 |
1993年 | 5篇 |
1992年 | 2篇 |
1991年 | 2篇 |
1990年 | 3篇 |
1988年 | 1篇 |
1985年 | 1篇 |
1982年 | 1篇 |
1978年 | 1篇 |
1975年 | 1篇 |
排序方式: 共有672条查询结果,搜索用时 31 毫秒
31.
建立DPX快速吸附萃取、程序升温(PTV)大体积进样与气相色谱/质谱(GC/MS)联用,SIM模式同时测定水中19种多溴联苯(PBBs)单体的方法。该方法在PBBs质量浓度1~50μg/L范围内线性良好,19种PBBs单体检出限为0.147~0.230μg/L,相对标准偏差为6.61%~10.5%,加标回收率为61.5%~82.6%。 相似文献
32.
在常温条件下,采用生物滴滤塔处理模拟甲硫醚废气,考察了气体空床停留时间(EBRT)、容积负荷、喷淋密度及营养液pH对生物滴滤塔性能的影响。实验结果表明:当EBRT为90 s、进气甲硫醚质量浓度为150 mg/m~3、喷淋密度为0.65 m~3/(m~2·h),营养液pH为6.8时,甲硫醚去除率为90%;容积负荷高于15 g/(m~3·h)时,对生物滴滤塔的性能产生抑制作用;EBRT为90 s及60 s时,最佳喷淋密度分别为0.56~0.65 m~3/(m~2·h)及0.65~0.75 m~3/(m~2·h);降解甲硫醚的微生物对pH的变化较敏感,最适营养液pH为6~7。 相似文献
33.
成都市餐厨垃圾产量分析预测及监管体系建设研究 总被引:1,自引:0,他引:1
整理汇总了成都市中心城区及郊县餐厨垃圾产生和收运现状,对其产量作出预测;在此基础上提出适合成都市自身情况的餐厨垃圾监管体系构建设想。 相似文献
34.
We evaluated the exposure to pesticides from the consumption of passion fruits and subsequent human health risks by combining several methods: (i) experimental field studies including the determination of pesticide residues in/on passion fruits, (ii) dynamic plant uptake modelling, and (iii) human health risk assessment concepts. Eight commonly used pesticides were applied onto passion fruits cultivated in Colombia. Pesticide concentrations were measured periodically (between application and harvest) in whole fruits and fruit pulp. Measured concentrations were compared with predicted residues calculated with a dynamic and crop-specific pesticide uptake model, namely dynamiCROP. The model accounts for the time between pesticide application and harvest, the time between harvest and consumption, the amount of spray deposition on plant surfaces, uptake processes, dilution due to crop growth, degradation in plant components, and reduction due to food processing (peeling). Measured and modelled residues correspond well (r2 = 0.88-0.99), with all predictions falling within the 90% confidence interval of the measured values. A mean error of 43% over all studied pesticides was observed between model estimates and measurements. The fraction of pesticide applied during cultivation that is eventually ingested by humans is on average 10−4-10−6, depending on the time period between application and ingestion and the processing step considered. Model calculations and intake fractions via fruit consumption based on experimental data corresponded well for all pesticides with a deviation of less than a factor of 2. Pesticide residues in fruits measured at recommended harvest dates were all below European Maximum Residue Limits (MRLs) and therefore do not indicate any violation of international regulatory thresholds. 相似文献
35.
Hedberg Y Herting G Wallinder IO 《Environmental pollution (Barking, Essex : 1987)》2011,159(5):1144-1150
Membrane filtration is commonly performed for solid-liquid separation of aqueous solutions prior to trace metal analysis and when assessing “dissolved” metal fractions. Potential artifacts induced by filtration such as contamination and/or adsorption of metals within the membrane have been investigated for different membrane materials, metals, applied pressures and pre-cleaning steps. Measurements have been conducted on aqueous solutions including well-defined metal standards, ultrapure water, and on runoff water from corroded samples.Filtration using both non-cleaned and pre-cleaned filters revealed contamination and adsorption effects, in particular pronounced for zinc, evident for copper but non-significant for nickel. The results clearly show these artifacts to be non-systematic both for non-cleaned and pre-cleaned membranes. The applied pressure was of minor importance.Measurements of the labile fraction by means of stripping voltammetry clearly elucidate that membrane filtration followed by total metal analysis cannot accurately assess the labile or the dissolved metal fraction. 相似文献
36.
为评估由我国大气中α HCH所导致的人体健康风险,利用CanMETOP 模拟的2005年日均α HCH大气浓度,基于吸入因子和致癌风险进行研究。结果表明年吸入因子呈东部>西部,北部>南部的特征,东中和东北部地区的吸入因子分别主要由人口密度和α HCH大气浓度贡献,东中和东南部地区的个体健康损失小于东北地区,东中和东南部地区年内逐月吸入因子分配较为均匀,而东北地区主要集中的夏季,东北地区个体致癌风险系数明显高于中部和南部。推测由其它污染物所形成的暴露风险具有类似的时空分布。加之夏季东北地区集中降水所形成的湿沉降以及气温升高等因素,使摄食暴露和皮肤接触暴露增大,东北地区人群的复合暴露风险将显著大于其它地区 相似文献
37.
为研究水下公路隧道纵向疏散通道加压送风系统的关键设计参数,结合纵向疏散通道的特点,借鉴一般建筑加压送风系统的设计要求,提出了纵向疏散通道内加压送风量的计算方法,并通过数值模拟方法对纵向疏散通道加压送风系统进行了研究。结果表明,利用风速法计算得到的送风量比压差法计算得到的结果大20倍左右,并且压差法计算送风量时受疏散口缝隙宽度影响较大,工程适用性差。通过数值模拟可知,疏散通道内的送风风速达到1.5m/s时即能够满足人员安全疏散要求,这与风速法计算的结果一致。研究结果可供采用纵向疏散模式的隧道疏散通道加压送风系统设计参考。 相似文献
38.
现行的泥石流总量计算方法普遍存在计算参数较难获取或难以精确获取的问题,加上汶川地震灾区沟谷内分布大量的由崩塌、滑坡体等形成的固体松散物质;所以多数泥石流总量计算公式在汶川震区存在局限性.参考适用于以崩塌、滑坡体为主要物源的泥石流总量计算公式;分析研究区范围内地形地貌发育状态与降雨因素及其地质条件之间的影响关系;将地貌指数(Strahler积分)应用于泥石流总量计算,尝试解决缺乏降雨数据情况下泥石流总量计算问题.根据“8.13”四川清平群发性泥石流数据初步回归分析得到适合于汶川震区的泥石流总量计算模型. 相似文献
39.
G. Bronzetti A. Galli P. Boccardo R. Vellosi R. Del Carratore E. Sabbioni 《毒物与环境化学》2013,95(1-2):103-111
The genotoxicity of chromium chloride was investigated in cells of D7 strain of Saccharomyces cerevisiae harvested either from logarithmic or stationary growth phase. A weak induction of mifotic gene conversion and point reverse mutation was obtained when the incubations were performed using phosphate buffer. No genetic effect was observed when the incubations were performed using Tris‐HCl buffer. The experiments with 51Cr radiotracer demonstrated that Cr3+ ion enters the yeast cells and binds to DNA even if the incubation mixture was performed with Tris HCl buffer. This behaviour could be due to the highest concentration of CrCl3 that cause some damages to cytoplasmatic membrane. 相似文献
40.
Steffi Mayer Philipp Klaritsch Scott Petersen Elisa Done Inga Sandaite Holger Till Filip Claus Jan A. Deprest 《黑龙江环境通报》2011,31(11):1086-1096