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1.
Background, Aim and Scope Air quality is an field of major concern in large cities. This problem has led administrations to introduce plans and regulations
to reduce pollutant emissions. The analysis of variations in the concentration of pollutants is useful when evaluating the
effectiveness of these plans. However, such an analysis cannot be undertaken using standard statistical techniques, due to
the fact that concentrations of atmospheric pollutants often exhibit a lack of normality and are autocorrelated. On the other
hand, if long-term trends of any pollutant’s emissions are to be detected, meteorological effects must be removed from the
time series analysed, due to their strong masking effects.
Materials and Methods The application of statistical methods to analyse temporal variations is illustrated using monthly carbon monoxide (CO) concentrations
observed at an urban site. The sampling site is located at a street intersection in central Valencia (Spain) with a high traffic
density. Valencia is the third largest city in Spain. It is a typical Mediterranean city in terms of its urban structure and
climatology. The sampling site started operation in January 1994 and monitored CO ground level concentrations until February
2002. Its geographic coordinates are W0°22′52″ N39°28′05″ and its altitude is 11 m. Two nonparametric trend tests are applied.
One of these is robust against serial correlation with regards to the false rejection rate, when observations have a strong
persistence or when the sample size per month is small. A nonparametric analysis of the homogeneity of trends between seasons
is also discussed. A multiple linear regression model is used with the transformed data, including the effect of meteorological
variables. The method of generalized least squares is applied to estimate the model parameters to take into account the serial
dependence of the residuals of this model. This study also assesses temporal changes using the Kolmogorov-Zurbenko (KZ) filter.
The KZ filter has been shown to be an effective way to remove the influence of meteorological conditions on O3 and PM to examine underlying trends.
Results The nonparametric tests indicate a decreasing, significant trend in the sampled site. The application of the linear model
yields a significant decrease every twelve months of 15.8% for the average monthly CO concentration. The 95% confidence interval
for the trend ranges from 13.9% to 17.7%. The seasonal cycle also provides significant results. There are no differences in
trends throughout the months. The percentage of CO variance explained by the linear model is 90.3%. The KZ filter separates
out long, short-term and seasonal variations in the CO series. The estimated, significant, long-term trend every year results
in 10.3% with this method. The 95% confidence interval ranges from 8.8% to 11.9%. This approach explains 89.9% of the CO temporal
variations.
Discussion The differences between the linear model and KZ filter trend estimations are due to the fact that the KZ filter performs the
analysis on the smoothed data rather than the original data. In the KZ filter trend estimation, the effect of meteorological
conditions has been removed. The CO short-term componentis attributable to weather and short-term fluctuations in emissions.
There is a significant seasonal cycle. This component is a result of changes in the traffic, the yearly meteorological cycle
and the interactions between these two factors. There are peaks during the autumn and winter months, which have more traffic
density in the sampled site. There is a minimum during the month of August, reflecting the very low level of vehicle emissions
which is a direct consequence of the holiday period.
Conclusions The significant, decreasing trend implies to a certain extent that the urban environment in the area is improving. This trend
results from changes in overall emissions, pollutant transport, climate, policy and economics. It is also due to the effect
of introducing reformulated gasoline. The additives enable vehicles to burn fuel with a higher air/fuel ratio, thereby lowering
the emission of CO. The KZ filter has been the most effective method to separate the CO series components and to obtain an
estimate of the long-term trend due to changes in emissions, removing the effect of meteorological conditions.
Recommendations and Perspectives Air quality managers and policy-makers must understand the link between climate and pollutants to select optimal pollutant
reduction strategies and avoid exceeding emission directives. This paper analyses eight years of ambient CO data at a site
with a high traffic density, and provides results that are useful for decision-making. The assessment of long-term changes
in air pollutants to evaluate reduction strategies has to be done while taking into account meteorological variability 相似文献
2.
乌鲁木齐空气微生物含量的测定 总被引:2,自引:0,他引:2
用自然平皿沉降法对乌鲁木齐市13个室内外空气测点作了微生物含量的测定,结果表明平均室外空气的细菌、真菌、总菌含量及F/T%分别为28583 8、780 5、29364 3CFU·m-3及2 7,证实了该市空气处于中度微生物污染状态。少量测点显示其空气已受到严重污染,空气质量不佳。室内空气微生物污染也重。空气微生物污染以细菌为主。分析了室外空气微生物含量的时空分布特点差异,探讨了其成因,并与其他城市作了比较。文章指出增强环境忧患意识,采用切实而有效措施,减少环境污染的必要性。 相似文献
3.
4.
供水管线震害量化参数--渗漏面积的估算方法 总被引:2,自引:2,他引:2
为了分析管线破坏状态对震后供水管网功能的影响,首先需要对管线的震害状态进行量化。建议用管线渗漏面积标定管线的破坏状态。在管线震害分析和理论计算的基础上,提出了震后管线渗漏面积的计算方法,为进一步进行供水管网抗震分析和设计提供了研究基础。 相似文献
5.
矿井水是宝贵的地下水资源 总被引:1,自引:0,他引:1
本文针对煤矿矿井水是废水的错误认识,深入浅出地讨论了矿井水的水质特征,鲜明地提出矿井水是宝贵的地下水资源的观点,以及矿井水资源化的法规保证。 相似文献
6.
This article does not focus on adaptation or mitigation policy directly but on an allied opportunity that exists for the Pacific
Islands via the auspices of the Climate Convention, because the existing very costly energy systems used in the Pacific Island
region are fossil-fuel dependent. It is argued here that efforts can be made towards the development of energy systems that
are ecologically sustainable because Pacific Island nations are eligible to receive assistance to introduce renewable energy
technology and pursue energy conservation via implementation mechanisms of the Climate Convention and, in particular, through
transfer of technology and via joint implementation.
It is contended that assistance in the form of finance, technology, and human resource development from developed countries
and international organizations would provide sustainable benefits in improving the local Pacific Island environments. It
is also emphasized that mitigation of greenhouse gas emissions is not the responsibility of the Pacific Islands as they contribute
very little on a per capita global scale and a tiny proportion of total global greenhouse gas emissions. 相似文献
7.
从综合治理,合理利用采出污水的长远利益出发,针对东部油田高含水阶段的新特点,提出地面高效处理,地下控水稳油相结合的治理策略,探讨了相关的技术和方法,并讨论了采出污水回注利用中应加强研究的几个问题。 相似文献
8.
浙产白术市售种子质量的鉴定 总被引:1,自引:0,他引:1
根据试验,浙江产白术种子的净度可分为3个等级:一级净度为95%以上,二级净度90%~95%,三级净度90%以下.其发芽率为45%~59%,与种子批次的千粒重密切相关.种子在室外阳光下晒干.含水量可控制在8%~10%,而在室内阴干则与环境的相对湿度密切相关.其千位重的差异与该种子批次内大.中、小粒种子的比例有关,一般种子千粒重为25.60~37.50g. 相似文献
9.
10.
Christopher R. Ellis Jerry Champlin Heinz G. Stefan 《Journal of the American Water Resources Association》1997,33(6):1363-1374
ABSTRACT: Evidence is presented that snowmelt runoff from an urban watershed can produce density current intrusions (underflows) in a lake. Several episodes of density current intrusions are documented. Water temperatures and salinities measured near the bottom of a 10 m deep Minneapolis lake during the late winter warming periods in 1989, 1990, 1991, and 1995 show significant rapid changes which are correlated with observed higher air temperatures and snowmelt runoff. The snowmelt runoff entering this particular lake (Ryan Lake) has increased electrical conductivity, salinity, and density. The source of the salinity is the salt spread on urban streets in the winter. Heating of littoral waters in spring may also contribute to the occurrence of the sinking flows, but is clearly not the only cause. 相似文献