固体废物相关概念的基本特点

固体废物法对废物的一些概念进行了定义,在固体废物环境管理当中,对这些概念缺乏深入认识,导致在实际管理中对固体废物和危险废物的调查、认定、统计、管理、预测、设施建设等一系列与废物相关的行动出现偏差甚至不准确。对固体废物、危险废物以及废物利用、处置、贮存、排放等概念包含的内容进行了研究,提出了一些新的认识观点。     

Screening 31 endocrine-disrupting pesticides in water and surface sediment samples from Beijing Guanting reservoir

For screening 31 potential or suspected endocrine-disrupting pesticides in water and surface sediments, a multiresidue analysis method based on gas chromatography with electron capture detection (GC/ECD) was developed. Solid phase extraction (SPE) technology with Oasis^® HLB cartridge was also applied in sample extraction. The relevant mean recoveries were 70–103% and 71–103% for water and sediment, respectively. Relative standard deviations (RSD) are 2.0–7.0%, 4.0–8.0% for water and sediment, respectively. Thirty one pesticides (-HCH, β-HCH, γ-HCH, δ-HCH, hexachlorobenzene (HCB), aldrin, heptachlor, endosulfan I & II, p,p′-DDD, o,p′-DDT, p,p′-DDT, p,p′-DDE, endrin aldehyde, endosulfan sulphate, methoxychlor, hepachlor epoxide, -chlordane, γ-chlordane, dieldrin, endrin, dicofol, acetochlor, alachlor, metolachlor, chlorpyriphos, nitrofen, trifluralin, cypermethrin, fenvalerate, deltamethrin) in water and surface sediment samples from Beijing Guanting reservoir were analyzed. Concentrations of pesticides ranged from 7.59 to 36.0 ng g⁻¹ on a dry wt. basis for sediment samples, from 279.3 to 2740 ng l⁻¹ for pore waters and from 48.8 to 890 ng l⁻¹ for water samples, respectively, with a mean concentration of 10.7 ng g⁻¹ in sediment, 735 ng l⁻¹ in pore water and 295 ng l⁻¹ in water, respectively. The data obtained provides information on the levels and sources of endocrine-disrupting pesticides in Guanting reservoir. These results underscore the need to improved environmental protection measures in order to reduce the exposure of the population and aquatic biota to these endocrine-disrupting compounds.     

HNO_3─KI─MIBK萃取／原子吸收光谱法测定固体废物浸提液中的微量银

采用选择性较好的ＨＮＯ３—ＫＩ—ＭＩＢＫ萃取体系对铋渣和尾矿渣浸出液中的痕量银进行预分离富集后，用火焰原子吸收法（ＡＡＳ）进行测定。此法不仅变异系数小（约为３．１％），而且检出限比直接火焰ＡＡＳ法降低两个数量级，达０．５ｎｇ／ｍｌ．另外，还就作品细度对银测定结果的影响原因做了初步探讨。     

Environmental monitoring of complex hydrocarbon mixtures in water and soil samples after solid phase microextraction using PVC/MWCNTs nanocomposite fiber

A novel nanocomposite based on incorporation of multiwalled carbon nanotubes (MWCNTs) in polyvinyl chloride (PVC) was prepared. Proposed nanocomposite was coated on stainless steel wire by deep coating. Composition of nanocomposite was optimized based on results of morphological studies using scanning electron microscopy. The best composition (83% MWCNTs:17% PVC) was applied as a solid phase microextraction fiber. Complex mixture of aromatic (BTEX) and aliphatic hydrocarbons (C₅–C₃₄) were selected as model analytes, and performance of proposed fiber in extraction of the studied compounds from water and soil samples was evaluated. Analytical merits of the method for water samples (LODs = 0.10–1.10 ng L⁻¹, r² = 0.9940–0.9994) and for soil samples (LODs = 0.10–0.77 ng kg⁻¹, r² = 0.9946–0.9994) showed excellent characteristics of it in ultra trace determination of petroleum type environmental pollutants. Finally, the method was used for determination of target analytes in river water, industrial effluent and soil samples.     

Biodegradation of α and β Endosulfan in Soil as Influenced by Application of Different Organic Materials

Abstract

A laboratory pot experiment was conducted to study the effect of amending soil with four different sources of organic matter on the degradation rate of α and β endosulfan isomers. Poultry by-product meal, poultry manure, dairy manure, and municipal solid waste compost were cured, dried, ground (<1 mm) and thoroughly mixed with a calcareous soil at a rate of 2% and placed in plastic pots. Endosulfan was added at the rate of 20 mg kg^?1. The moisture level was kept near field capacity and the pots were kept at room temperature. Soil sub-samples, 100 g each, were collected from every pot at days 1, 8, 15, 22, 29, 43, and 57 for the measurement of endosulfan isomers. Endosulfan residues were extracted from the soil samples with acetone. The supernatant was filtered through anhydrous sodium sulphate, 5 mL aliquot was diluted to 25 mL with hexane, mixed well, and then two sub-samples from the filtrates were analyzed for α and β endosulfan isomers by gas chromatography. The results indicated that the half-life (T _½) of α-endosulfan in the poultry by-product meal treatment was 15 days compared to about 22 days in the other treatments. The T _½ of β-endosulfan was 22 days in the poultry by-product meal treatment and followed a bi-phasic pattern, 57 days in the municipal solid waste compost treatment and the extrapolated T _½ was about 115 days for the other three treatments.     

High-energy milling to decontaminate soils polluted by polychlorobiphenyls and atrazine

Mechanical energy has been used so far for running chemical reactions and for preparing new materials in absence of solvents. Very recently, the technology has been applied to solve environmental problems. In this paper, we describe the application of high-energy milling (HEM) for the remediation of soils contaminated by chlorinated organic compounds such as polychlorobiphenyls (PCBs) and agrochemicals like atrazine. NaBH₄ and LiAlH₄ have been successfully used for the total dehydrohalogenation of both classes of compounds, leaving a residue lower than 2 ppmw of the starting compound in the treated soil. LiAlH₄ was found to be more active than NaBH₄.     

Electrocatalytic oxidation of gaseous toluene in an all-solid cell using a foam Ti/Sb-SnO2/β-PbO2 anode

Mineralization of benzene, toluene, and xylene (BTX) with high efficiency at room temperature is still a challenge for the purification of indoor air. In this work, a foam Ti/Sb-SnO₂/β-PbO₂ anode catalyst was prepared for electrocatalytically oxidizing gaseous toluene in an all-solid cell at ambient temperature. The complex Ti/Sb-SnO₂/β-PbO₂ anode, which was prepared by sequentially deposing Sb-SnO₂ and β-PbO₂ on a foam Ti substrate, shows high electrocatalytic oxidation efficiency of toluene (80%) at 7 hr of reaction and high CO₂ selectivity (94.9%) under an optimized condition, i.e., a cell voltage of 2.0 V, relative humidity of 60% and a flow rate of 100 mL/min. The better catalytic performance can be ascribed to the high production rate of ⋅OH radicals from discharging adsorbed water and the inhibition of oxygen evolution on the surface of foam Ti/Sb-SnO₂/β-PbO₂ anode when compared with the foam Ti/Sb-SnO₂ anode. Our results demonstrate that prepared complex electrodes can be potentially used for electrocatalytic removal of gaseous toluene at room temperature with a good performance.     

Auditing non-hazardous wastes from golf course operations: moving from a waste to a sustainability framework

This paper provides non-hazardous solid waste audit procedures and bench mark audit data for golf courses (GCs). The paper also demonstrates the narrow scope of solid waste audit data, and the need to move towards a broader auditing scope such as that contained in sustainability auditing frameworks. A case study of Clear Lake Golf Course, located in southwestern Manitoba, Canada was completed. Annual waste generation rates at the GC were estimated to be 46.2 tonnes/year with 83% of this material compostable. Grass clipping material generated from the putting greens accounted for 79% of the waste stream. The GC achieved a solid waste diversion rate of 81% (waste generated not destined for landfill per total waste material generated). A future, realistic target of 97% diversion was also identified. The 7 day audit period was found to be unsuitable for estimating grass clipping generation rates. Implementation of a broader sustainability framework for future audits will harmonize many existing management functions such as solid waste auditing, waste characterizations, pollution prevention, green procurement, customer satisfaction, and the efficiency of the operations.     

Multi-criteria evaluation technique for SFI site identification of NORMS and oil industry waste disposal – Possibilities in Kuwait

Waste generation and accumulating quantities of oil field waste are a matter of environmental concern. This study proposes the Slurry Fracture Injection (SFI) technique as an alternative waste disposal method. The slurried solids injection waste disposal method is environmentally secure and permanent, leaving no future liabilities that must be risk-evaluated or priced. An entire waste stream comprising ground solids and waste water can be injected into deep and hydraulically secure target strata with no contamination of potable water-bearing formations or formations outside the target zone that may contain resources (gas and oil). The slurry injection method can be used to clean and reclaim landfills, oil pits and granular waste dumps. This article proposes a two-tier screening method for evaluating the feasibility of this technique and the identification of suitable target zones. A stringent environmental and process control monitoring program should complement the planning and operational period to ensure environmental protection, waste containment, and regulatory HSE compliance.     

Development of a database of landfills and dump sites in Asian countries

This article briefly summarizes the limited landfill/dump information available for developing Asian countries, and introduces a database that aims to close the information gap through collecting and sharing data. Developing nations usually try to adapt the systems and technologies of developed countries. However, this approach may not be appropriate because of differences in socioeconomic, cultural, and political backgrounds. Many waste management projects fail after operations are transferred to local authorities owing to a lack of funds to cover the high operational expenses. Some successful projects have been adapted to local conditions, although the information on these successes is not often available for others. Nevertheless, only a few developing countries even have a national inventory of their dumps/landfills, and decision-makers have little awareness of the dumps and their impacts. The database introduced here will gather landfill/dump information from each country and organize it in a comparable format, and it will then be published on the Internet.