The psychological contract and the transition from full to part‐time police work

The cognitive‐perceptual conceptualisation of the psychological contract has dominated research in this field. In this paper, it is argued that locating the psychological contract at the level of the individual‐organisational relationship can offer rich insights into psychological contract dynamics. Using qualitative interview data from a research study exploring how managers and part‐timers deal with the transition from full to part‐time police work in the UK, it is argued that a multi‐perspective conceptualisation of the sources of the psychological contract is critical for understanding processes that lead to non‐mutuality of understandings. Specifically, it is argued that the institutional and organisational context, embedded in the actions of third parties and in management practices, can undermine the extent to which the manager and the employee can reach agreement about mutual obligations. The theoretical and policy implications of this position are developed. Copyright © 2006 John Wiley & Sons, Ltd.     

Fetoscopic myelomeningocoele closure: Is the scientific evidence enough to challenge the gold standard for prenatal surgery?

Since the completion of the Management of Myelomeningocoele Study, maternal-fetal surgery for spina bifida has become a valid option for expecting parents. More recently, multiple groups are exploring a minimally invasive approach and recent outcomes have addressed many of the initial concerns with this approach. Based on a previously published framework, we attempt to delineate the developmental stage of the surgical techniques. Furthermore, we discuss the barriers of performing randomized controlled trials comparing two surgical interventions and suggest that data collection through registries is an alternative method to gather high-grade evidence.     

Methane emission in a rice field of Thailand

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Genetic structure of the scleractinian coral<Emphasis Type="Italic"> Platygyra sinensis</Emphasis> in Hong Kong

Genetic structure was studied in Platygyra sinensis from six sites in Hong Kong by allozyme electrophoresis using an isoelectric focusing gel (IEF). Seven variable loci were detected using six enzyme systems. The number of alleles per locus ranged from 3.3 to 3.6 in the six samples, and heterozygosity from 0.429 to 0.540. Genotype frequencies were generally close to Hardy–Weinberg expectations. The values of unique multilocus genotype to the number of individuals for each sample (N_G/N) and observed genotypic diversity to expected genotypic diversity (G_O/G_E) were high, indicating a high level of sexual reproduction. Variation in allele frequencies among sites was low (F_ST=0.017), as was Nei's unbiased genetic distance (D), suggesting genetic similarity among sites.Communicated by T. Ikeda, Hakodate     

What have we known so far about microplastics in drinking water treatment? A timely review

• 23 available research articles on MPs in drinking water treatment are reviewed. • The effects of treatment conditions and MP properties on MP removal are discussed. • DWTPs with more steps generally are more effective in removing MPs. • Smaller MPs (e.g.,<10 μm) are more challenging in drinking water treatment. Microplastics (MPs) have been widely detected in drinking water sources and tap water, raising the concern of the effectiveness of drinking water treatment plants (DWTPs) in protecting the public from exposure to MPs through drinking water. We collected and analyzed the available research articles up to August 2021 on MPs in drinking water treatment (DWT), including laboratory- and full-scale studies. This article summarizes the major MP compositions (materials, sizes, shapes, and concentrations) in drinking water sources, and critically reviews the removal efficiency and impacts of MPs in various drinking water treatment processes. The discussed drinking water treatment processes include coagulation-flocculation (CF), membrane filtration, sand filtration, and granular activated carbon (GAC) filtration. Current DWT processes that are purposed for particle removal are generally effective in reducing MPs in water. Various influential factors to MP removal are discussed, such as coagulant type and dose, MP material, shape and size, and water quality. It is anticipated that better MP removal can be achieved by optimizing the treatment conditions. Moreover, the article framed the major challenges and future research directions on MPs and nanoplastics (NPs) in DWT.     

Interlaboratory evaluation of endotoxin analyses in agricultural dusts--comparison of LAL assay and mass spectrometry

Endotoxin exposure is associated with wheeze and asthma morbidity, while early life exposure may reduce risk of allergy and asthma. Unfortunately, it is difficult to compare endotoxin results from different laboratories and environments. We undertook this study to determine if lipopolysaccharide (LPS) extraction efficiency could account for differences among laboratories. We generated and collected aerosols from chicken and swine barns, and corn processing. We randomly allocated side-by-side filter samples to five laboratories for Limulus assay of endotoxin. Lyophilized aliquots of filter extracts were analyzed for 3-hydroxy fatty acids (3-OHFAs) as a marker of LPS using gas chromatography-mass spectrometry. There were significant differences in endotoxin assay and GC-MS (LPS) results between laboratories for all dust types (p < 0.01). Patterns of differences between labs varied by dust type. Relationships between assay and GC/MS results also depended on dust type. The percentages of individual 3-OHFA chain lengths varied across labs (p < 0.0001) suggesting that each lab recovered a different fraction of the LPS available. The presence of large amounts of particle associated LPS and absence of a freezing thawing cycle were associated with lower correlations between LPS and bioactivity, consistent with an absence of Limulus response to cell-bound endotoxin. These data suggest that extraction methods affect endotoxin measurements. The LAL methods may be most suitable when comparing exposures within similar environments; GC-MS offers additional information helpful in optimizing sample treatment and extraction. GC-MS may be of use when comparing across heterogeneous environments and should be considered for inclusion in future studies of human health outcomes.     

Effects of meteorological conditions on PM10 concentrations - A study in Macau

Review on the annual PM₁₀ concentrations over a 10-year period shows that Macau is subjected to severe fine particulate pollution. Investigations of its variation in monthly and daily time scales with the local meteorological records reveal further details. It is found that a distinct feature of the Asian monsoon climates, the changes of wind direction, mainly controls the general trend of PM₁₀ concentration in a year. The monsoon driven winter north-easterly winds bring upon Macau dry and particle enriched air masses leading to a higher concentration in that period while the summer south-westerly winds transport humid and cleaner air to the region leading to a lower PM₁₀ value. This distinct seasonal feature is further enhanced by the lower rainfall volume and frequency as well as mixing height in winter and their higher counterparts in summer. It is also found that the development of tropical cyclones near Macau could also impose episode like PM₁₀ concentration spikes due to the pre-typhoon induced stagnant air motion followed by the swing of wind direction to the northerly.     

Materials,fuels, upgrading,economy, and life cycle assessment of the pyrolysis of algal and lignocellulosic biomass: a review

Climate change issues are calling for advanced methods to produce materials and fuels in a carbon–neutral and circular way. For instance, biomass pyrolysis has been intensely investigated during the last years. Here we review the pyrolysis of algal and lignocellulosic biomass with focus on pyrolysis products and mechanisms, oil upgrading, combining pyrolysis and anaerobic digestion, economy, and life cycle assessment. Products include oil, gas, and biochar. Upgrading techniques comprise hot vapor filtration, solvent addition, emulsification, esterification and transesterification, hydrotreatment, steam reforming, and the use of supercritical fluids. We examined the economic viability in terms of profitability, internal rate of return, return on investment, carbon removal service, product pricing, and net present value. We also reviewed 20 recent studies of life cycle assessment. We found that the pyrolysis method highly influenced product yield, ranging from 9.07 to 40.59% for oil, from 10.1 to 41.25% for biochar, and from 11.93 to 28.16% for syngas. Feedstock type, pyrolytic temperature, heating rate, and reaction retention time were the main factors controlling the distribution of pyrolysis products. Pyrolysis mechanisms include bond breaking, cracking, polymerization and re-polymerization, and fragmentation. Biochar from residual forestry could sequester 2.74 tons of carbon dioxide equivalent per ton biochar when applied to the soil and has thus the potential to remove 0.2–2.75 gigatons of atmospheric carbon dioxide annually. The generation of biochar and bio-oil from the pyrolysis process is estimated to be economically feasible.

     

Consequences of shell-species preferences for female reproductive success in the hermit crab Pagurus bernhardus

Littoral hermit crabs, Pagurus bernhardus, show a strong preference for Littorina obtusata shells rather than those of Gibbula species. The fitness consequences, in terms of fecundity, for this shell preference is examined for female crabs. Females in the preferred species produced eggs earlier in the season, produced more eggs in the first brood, and produced a second brood more often than did females in the less preferred species. The smaller brood for Gibbula spp. was not a consequence of egg loss from the pleopods due to an unfavourable shape of shell, but rather reflected lower egg production. It is not clear, however, if this differential reproduction is due to direct costs of carrying an unfavourable shell, i.e. the shell impedes reproduction, or whether crabs compete aggressively for favoured shells so that only crabs of low quality inhabit lowquality shells.