A mini-review on rare earth metal-doped TiO<Subscript>2</Subscript> for photocatalytic remediation of wastewater

Titanium dioxide (TiO₂) has been considered a useful material for the treatment of wastewater due to its non-toxic character, chemical stability and excellent electrical and optical properties which contribute in its wide range of applications, particularly in environmental remediation technology. However, the wide band gap of TiO₂ photocatalyst (anatase phase, 3.20 eV) limits its photocatalytic activity to the ultraviolet region of light. Besides that, the electron-hole pair recombination has been found to reduce the efficiency of the photocatalyst. To overcome these problems, tailoring of TiO₂ surface with rare earth metals to improve its surface, optical and photocatalytic properties has been investigated by many researchers. The surface modifications with rare earth metals proved to enhance the efficiency of TiO₂ photocatalyts by way of reducing the band gap by shifting the working wavelength to the visible region and inhibiting the anatase-to-rutile phase transformations. This review paper summarises the attempts on modification of TiO₂ using rare earth metals describing their effect on the photocatalytic activities of the modified TiO₂ photocatalyst.     

Examining driver behavior using data gathered from red light photo enforcement cameras

INTRODUCTION: To develop an effective driver assistance system that can prevent red light violations, it is important to have a thorough understanding of contributing factors and circumstances surrounding such violations. METHODS: Red light violation behavior was examined using about 47,000 violation records that were captured by photo enforcement cameras from 11 signalized intersections in the city of Sacramento, California, over a four-year period. This examination identified factors with strong correlation to red light running behavior. RESULTS: Key findings based on Sacramento's red light violation records include: (a) younger drivers showed a higher tendency of running the red light and were more likely to commit such a violation at speeds above the posted speed limit; (b) off-peak time period between 8 p.m. to 5 a.m. had lower violation counts, but red light violators in this time frame had a higher propensity of racing through intersections at high speeds; (c) also during the time period between 8 p.m. to 5 a.m., violators showed a higher probability of entering intersections two or more seconds after the onset of red light; and (d) violators were less likely to cross high traffic-volume intersections with speeds greater than the posted speed limit. DISCUSSION: Sacramento's data suggest that some red light violators might have committed such an offense unintentionally. The top three violation speeds were all below 20 mph and more than 94% of red light runners crossed intersections within 2 seconds after the onset of the red light. IMPACT ON INDUSTRY: In the next several years, studies will be executed to assess whether a red light violation warning system can reduce "unintentional red light running" such as drivers who made incorrect judgment regarding the adequate time to clear the intersection and inattentive motorists who fail to observe the presence and status of the red light.     

International Standardisation of a Method for Detection of Human Pathogenic Viruses in Molluscan Shellfish

The viruses primarily associated with shellfish-borne illness are norovirus, causing gastroenteritis and hepatitis A virus (HAV). Recent years have seen a proliferation of publications on methods for detection of these viruses in shellfish using polymerase chain reaction (PCR). However, currently no standard harmonised procedures have been published. Standardisation is necessary before virus methods can be considered for adoption within a regulatory framework. A European standardisation working group is developing a two-part (quantitative and qualitative) standard method for virus detection in foodstuffs, including shellfish, which has the potential to be incorporated into EU legislation as a reference method. This article describes the development of the standard method and outlines the key methodology principles adopted, the controls and other quality assurance measures supporting the method and future necessary developments in the area.