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1.
Gemma Molins María Dolores Álvarez Núria Garrido Jorge Macanás Fernando Carrillo 《Journal of Polymers and the Environment》2018,26(3):873-884
The aim of this study is to analyse the environmental impacts (EIs) of the process of preparation of new biocomposite materials obtained from polylactide (PLA) and chicken feathers (CFs). Two CFs stabilization methods and different percentages of CFs have been studied. The EIs of these new composites were compared to the impact of virgin PLA. Cradle-to-gate life cycle inventories were assessed for 0–35% v/v of CFs in a CFs/PLA biocomposite. Two CFs stabilization processes, autoclave and surfactant, were tested and compared with the aim to prioritize one of them from the environmental point of view. A composite plate of 184?×?184?×?2.2 mm3 was defined as the functional unit. Autoclave stabilization process exhibited lower environmental impact compared with surfactant stabilization process mainly due to both the lower requirements of electricity and water and the reduced pollution loads of the generated wastewater. Thus, the autoclave process was selected as the standard method when comparing the EIs of the proposed CFs/PLA biocomposites. In this sense, the addition of CFs to PLA matrix proportionally reduces all the EIs compared to pure PLA due to the replacement of PLA with CFs. This behaviour can be explained because the PLA production accounts for the 99% of the impact of the biocomposite. Consequently, CFs conveniently stabilized might be an alternative raw material to prepare CFs/PLA biocomposites with less environmental impact compared to pure PLA. 相似文献
2.
Windblown dust is known to impede visibility, deteriorate air quality and modify the radiation budget. Arid and semiarid areas with unpaved and unvegetated land cover are particularly prone to windblown dust, which is often attributed to high particulate matter (PM) pollution in such areas. Yet, windblown dust is poorly represented in existing regulatory air quality models. In a study by the authors on modeling episodic high PM events along the US/Mexico border using the state-of-the-art CMAQ/MM5/SMOKE air quality modeling system [Choi, Y.-J., Hyde, P., Fernando, H.J.S., 2006. Modeling of episodic particulate matter events using a 3D air quality model with fine grid: applications to a pair of cities in the US/Mexico border. Atmospheric Environment 40, 5181–5201], some of the observed PM10 NAAQS exceedances were inferred as due to windblown dust, but the modeling system was incapable of dealing with time-dependent episodic dust entrainment during high wind periods. In this paper, a time-dependent entrainment parameterization for windblown dust is implemented in the CMAQ/MM5/SMOKE modeling system with the hope of improving PM predictions. An approach for realizing windblown dust emission flux for each grid cell over the study domain on an hourly basis, which accounts for the influence of factors such as soil moisture content, atmospheric stability and wind speed, is presented in detail. Comparison of model predictions with observational data taken at a pair of US/Mexico border towns shows a clear improvement of model performance upon implementation of the dust emission flux parameterization. 相似文献
3.
Aragón-Durand F 《Disasters》2007,31(4):477-494
Chronic flooding in the Chalco valley, state of Mexico, Mexico, is the outcome of past and present socio‐environmental changes which have taken place in Mexico City's south‐eastern peri‐urban interface. This flooding is the result of a complex interaction between urbanisation in an ex‐lacustrine area, permanent ecological deterioration and ground subsidence, poor sanitation and inadequate policy responses. Far from solving the flooding problem, short‐term policy responses have created increasingly unsafe conditions for current residents. A socio‐historical analysis of disasters reveals the importance of taking into consideration particular social actors and institutions in hazard generation and flood vulnerability over time. This paper analyses three aspects of this flooding: first, the importance of approaching floods from a socio‐historical perspective; second, the relation between urbanisation, former policies and flood risk generation; and third, current policy responses to and the failure in the risk management of La Compañía Canal. 相似文献
4.
Oxidation of trichloroethene over metal oxide catalysts: kinetic studies and correlation with adsorption properties 总被引:3,自引:0,他引:3
The performance of bulk chromium oxide is compared with that of a Mn commercial catalyst for the deep oxidation of trichloroethene (1000-2500ppmv, 55h(-1) space velocity) in air, in dry and wet (20000ppm of H(2)O) conditions, in terms of activity, selectivity and stability. Chromium oxide was found to be more active (on a catalyst weight basis), however its activity decreases continuously with time on stream. The presence of water increases its stability, the Mn catalyst showing the opposite behaviour. The effect of water on the Cr catalyst can be explained according to the Deacon equilibrium, as the presence of water tends to decrease the Cl(2) concentration, assumed to be responsible of the catalyst deactivation. Regarding to the selectivity, the Mn catalyst yields C(2)Cl(4), CCl(4) and CHCl(3) as organochlorinated by-products, whereas chromium oxide produces only trace amounts of CCl(4). Simple power-law kinetics expressions (first-order for Mn and zero-order for Cr) provide fairly good fits for the evolution of the conversion with the temperature. Furthermore, the kinetic behaviour of chromium oxide can be represented with a Langmuir-Hinshelwood model taking into account the chlorine inhibitory effect. 相似文献
5.
6.
Paulino Martinez-Fernandez Fernando deLlano-Paz Anxo Calvo-Silvosa Isabel Soares 《Environment, Development and Sustainability》2018,20(1):199-212
In this work, we apply the Modern Portfolio Theory and the Capital Assets Pricing Model financial tools to a portfolio of CO2-emitting generation technologies under diverse scenarios. We will calculate the efficient—in the sense of having the minimum risk for a given level of emissions—portfolios frontier. The Capital Market Line (CML) is the place where all the possible combinations of a specific efficient portfolio and a pollution-free portfolio—made up with nuclear and renewable generation technologies—lie. In Finance, that specific efficient portfolio is called the market portfolio but we will see that in our case it lacks an evident meaning. Therefore, we will explain which should be the reference portfolio for power generation planning analysis. Anyway, the fact is that those combinations are less pollutant than the portfolios in the efficient frontier. Thus, a policy-maker can analyse which is their effect on emissions reduction. We will start analysing the efficient pollutant generation portfolios. Then, we will introduce the CML-analogous lines (CML-A) to allow the possibility of reducing emissions by combining an efficient portfolio with a non-pollutant portfolio—this non-pollutant portfolio is free of both emissions and risk. Results support the necessity of considering the carbon capture and storage technology to achieve a less risky generation mix, with less emissions and allowing a higher diversification due to the presence of cleaner fossil fuel technologies. All of that leads to better levels of energy security. 相似文献
7.
Marcello D’Amico Inês Catry Ricardo C. Martins Fernando Ascensão Rafael Barrientos Francisco Moreira 《Ambio》2018,47(6):650-656
Power-line grids are increasingly expanding worldwide, as well as their negative impacts on avifauna, namely the direct mortality through collision and electrocution, the reduction of breeding performance, and the barrier effect. On the other hand, some bird species can apparently benefit from the presence of power lines, for example perching for hunting purposes or nesting on electricity towers. In this perspective essay, we reviewed the scientific literature on both costs and benefits for avifauna coexisting with power lines. Overall, we detected a generalized lack of studies focusing on these costs or benefits at a population level. We suggest that a switch in research approach to a larger spatio-temporal scale would greatly improve our knowledge about the actual effects of power lines on bird populations. This research approach would facilitate suitable landscape planning encompassing both mitigation of costs and promotion of benefits for bird populations coexisting with power lines. For example, the strategic route planning of electricity infrastructures would limit collision risk or barrier effects for threatened bird populations. Concurrently, this strategic route planning would promote the range expansion of threatened populations of other bird species, by providing nesting structures in treeless but potentially suitable landscapes. We suggest establishing a collaborative dialogue among the scientific community, governments, and electricity companies, with the aim to produce a win–win scenario in which both biodiversity conservation and infrastructure development are integrated in a common strategy. 相似文献
8.
Fernando Rojano Pierre-Emmanuel Bournet Melynda Hassouna Paul Robin Murat Kacira Christopher Y. Choi 《Environmental monitoring and assessment》2018,190(12):724
Air inside poultry houses must be removed on a regular basis to prevent excess of heat, particles and noxious gases that can imperil animals. To cope with this issue, natural ventilation could be an effective method when assisted by accurate predictions. This study investigates air discharges caused by natural ventilation of a poultry house by means of a three-dimensional computational fluid dynamics (CFD) model. It solves the governing equations of momentum, heat and mass transport, radiative transfers and animal-generated heat. Wind directions of 0°, 36° and 56° (0° corresponds to a wind blowing perpendicular to the ridgeline) were investigated; the CFD model predictions achieved a RMSE of 1.2 °C and 0.6 g[H2O] kg?1 [dry air] for internal temperature and absolute humidity, respectively, when air blew with an angle of 36°. Air renewal rates (ARR) were 39.5 (±?1.9), 34.9 (±?2.2) and 33.6 (±?1.7) volumes of the building per hour, when air blew at 0°, 36° and 56°, respectively. Such ARR predictions served to know how the gases contained in air would likely spread downstream from the building in order to define regions of potentially high gas concentration that could endanger neighbouring habitable facilities. 相似文献
9.
Marko Kete Egon Pavlica Fernando Fresno Gvido Bratina Urška Lavrenčič Štangar 《Environmental science and pollution research international》2014,21(19):11238-11249
Photocatalytic properties of titanium (IV) oxide (TiO2) in anatase form can be used for various purposes, including photocatalytic purification of water. For such an application, suspended or fixed photocatalytic reactors are used. Those with fixed phase seem to be preferred due to some advantages, one of which is the avoidance of photocatalyst filtration. To avoid leaching and exfoliation of the fixed phase, an immobilization procedure leading to a good adhesion of a catalyst to a substrate is crucial. Within this work, we present physical and photocatalytic characterization results of five commercially available TiO2 photocatalysts (P25, P90, PC500, KRONOClean 7000, VPC-10) and one pigment (Hombitan LO-CR-S-M), which were successfully immobilized on glass slides by a “sol suspension” procedure. Different mechanical tests and characterization methods were used to evaluate the stability and morphology of the layers. Evaluation of photocatalytic activity was done by tests under UVA and UV–vis irradiation, using a method based on the detection of the fluorescent oxidation product of terephthalic acid (TPA), i.e., hydroxyterephthalic acid (HTPA). Aeroxide® P90 incorporated into the silica-titania binder was the most photocatalytically active layer and, unlike the others, showed significant increase of photocatalytic activity through the entire range of tested UVA irradiation intensities (2.3 mW/cm2–6.1 mW/cm2). The high mechanical stability of some photocatalytic layers allows using them in water photocatalytic purification reactions. 相似文献
10.
Distribution of PCDD/Fs and dioxin-like PCBs in sediment and plants from a contaminated salt marsh (Tejo estuary,Portugal) 总被引:1,自引:0,他引:1
Margarida Nunes Anaïs Vernisseau Philippe Marchand Bruno Le Bizec Fernando Ramos Miguel A. Pardal 《Environmental science and pollution research international》2014,21(4):2540-2549
Concentrations and profiles of 2,3,7,8-substituted polychlorinated dibenzo-p-dioxins, polychlorinated dibenzofurans (PCDD/Fs) and dioxin-like polychlorinated biphenyls (dl-PCBs) were investigated in sediment and plants collected from a salt marsh in the Tejo estuary, Portugal. The highest PCDD/F and dl-PCB concentrations were detected in uncolonized sediments, averaging 325.25?±?57.55 pg g?1 dry weight (dw) and 8,146.33?±?2,142.14 pg g?1 dw, respectively. The plants Sarcocornia perennis and Halimione portulacoides growing in PCDD/F and dl-PCB contaminated sediments accumulated contaminants in roots, stems, and leaves. It was observed that PCDD/F and dl-PCB concentrations in roots were significantly lower in comparison with stems and leaves. In general, concentration of ΣPCDD/Fs and Σdl-PCBs in H. portulacoides tissues were found to be twofold higher than those in S. perennis, indicating a difference in the accumulation capability of both species. Furthermore, congener profiles changed between sediments and plant tissues, reflecting a selective accumulation of low chlorinated PCDD/Fs and non-ortho dl-PCBs in plants. 相似文献