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1.
Aysen Müezzinoğlu Tolga Elbir Abdurrahman Bayram 《Environmental Engineering and Policy》1998,1(2):109-116
In this study, an inventory of air pollutant emission estimates from major air polluting sources in Turkey for period between 1985 and 2005 with 5-year intervals were estimated. Inventory covers anthropogenic sources of five major air pollutants of particulate matter, sulfur dioxide, carbon monoxide, nitrogen oxides and non-methane volatile organic compounds. Their break-down with respect to main activity sectors were shown and their distribution by the largest industrial source categories were worked out as annual estimates. This inventory and its analysis point to serious environmental implications of air pollutants and a need to develop a policy plan for reducing these emissions. 相似文献
2.
Soil and atmospheric concentrations, dry deposition and soil-air gas exchange of organochlorine pesticides (OCPs) were investigated at an industrial site in Aliaga, Izmir, Turkey. Current-use pesticides, endosulfan and chlorpyrifos, had the highest atmospheric levels in summer and winter. Summertime total (gas + particle) OCP concentrations in air were higher, probably due to increased volatilization at higher temperatures and seasonal local/regional applications of current-use pesticides. Particle deposition fluxes were generally higher in summer than in winter. Overall average dry particle deposition velocity for all the OCPs was 4.9 ± 4.1 cm s−1 (average ± SD). ΣDDXs (sum of p,p′-DDT, p,p′-DDD, and p,p′-DDE) were the most abundant OCPs in Aliaga soils (n = 48), probably due to their heavy historical use and persistence. Calculated fugacity ratios and average net gas fluxes across the soil-air interface indicated volatilization for α-CHL, γ-CHL, heptachlorepoxide, cis-nonachlor, trans-nonachlor, and p,p′-DDT in summer, and for α-CHL, γ-CHL, trans-nonachlor, endosulfan sulfate, and p,p′-DDT in winter. For the remaining OCPs, soil acted as a sink during both seasons. Comparison of the determined fluxes showed that dry particle, gas-phase, and wet deposition are significant OCP input mechanisms to the soil in the study area. 相似文献
3.
Potentiometric studies of mixed complexes of cobalt(II) and copper(II) with l‐Asparagine and adenine
Hülya Demircan Demir Mürşit Pekin Aysen Kurt Cücü Emre Dölen Hassan Y. Aboul‐Enein 《毒物与环境化学》2013,95(3-4):357-367
A potentiometric titration technique has been used to determine the stability constants for the various complexes of Co(II) and Cu(II) with L‐asparagine and from DNA base, e.g. adenine. Stability constants of ternary systems have been evaluated by the method suggested by Irwing‐Rossotti. In addition, the conditional constants were calculated as a function of pH. The maximum values of the conditional formation constants were found to be in accordance with the mixed‐ligand complex formation constants in a determined pH region. Furthermore, the molar fractions of different species from mixed complexes were calculated by means of formation constants. The values of stability constants of mixed‐ligand complexes at 25°C are as follows: log K= 5.25 for Co(II)‐L‐asparagine‐adenine; log K= 9.30 for Cu(II)‐L‐asparagine‐adenine. The ionic strength was kept constant at I = 0.20 with NaClO4. 相似文献
4.
Muezzinoglu Aysen Elbir Tolga Bayram Abdurrahman 《Water, Air, & Soil Pollution: Focus》2003,3(5-6):307-316
Future (24 h later) daily ground level SO2 concentration in Istanbul was modeled and predicted using a new and powerful technique, Artificial Neural Networks (ANN) in the case of meteorological parameters as input variables. Results show that the trend of SO2 from higher values in winter to lower values in spring and summer, and again to higher values towards winter can be correctly represented by the neural networks. The model better predicted the lower SO2 values in spring and summer seasons when compared to higher values in winter season because of the pattern distribution in training data sets. Beside the amount of the database, the more the variation of the values of the parameters in their own ranges, the more the network learns the database. As a result of this study, considerably successful results were obtained when considering the complex and nonlineer structure of the atmosphere, which is the source of the database. 相似文献
5.
This paper reports the utilization of 4-(2-pyridylazo) resorcinol (PAR) as a chelating reagent for in-column derivatization
and the determination of trace Co, Fe, and Ni ions by reversed-phase high-performance liquid chromatography with photodiode
array detector. A good separation of Co, Fe, and Ni chelates were achieved by using an Inertsil ODS-3 column and a mobile
phase, consisted of methanol–THF–water mixture (50:5:45) containing ammonium acetate buffer (pH 5.0) and PAR. After full optimization,
good repeatability of retention times (relative standard deviation (RSD) < 0.05%) and peak areas (RSD < 1.7%) was achieved
as well as a good linearity (r
2 > 0.9991). The detection limits (S/N = 3), expressed as micrograms per liter, were 0.50 (Co), 9.07 (Fe), and 2.00 (Ni). The applicability and the accuracy of
the developed method were estimated by the analysis of spiked water samples and certified reference material BCR 715 wastewater-SRM. 相似文献
6.
7.
Early diagenetic processes control the behavior, and more specifically the dissolved‐solid phase distribution of heavy metals in sediments. The depth distribution of Co, Mn, Cu, Zn, Ni, and Fe in sediment were determined in box cores from the Black Sea. The sequential analyses results of these metals indicate contrasting behavior of Mn and Co during early diagenesis, consistent with their respective chemistries and particle‐associations. The profiles of extractable trace metals in the cores are clearly related to sediment type or depositional environment. Topmost sections of the profiles for these elements are generally similar, i.e. rapid decrease in concentration below the sediment surface. 相似文献
8.
Aysen Muezzinoglu Tolga Elbir Abdurrahman Bayram 《Water, Air, & Soil Pollution: Focus》2003,3(5-6):317-333
As a first step to work out an abatement plan against air pollution, a local emission inventory with 1 hr temporal and 1 km spatial resolution in the city of Izmir and its surroundings was prepared. The study area consisted of a 200 × 170 km2 rectangle having the city of Izmir at the centre. The studied pollutants were total particulate matter (PM), sulfur oxides (SOx), nitrogen oxides (NOx), volatile organic compounds (VOC) and carbon monoxide (CO). Emissions of these pollutants were determined by estimation methods making use of suitable emission factors. Emission sources were evaluated in three categories; point, area and line sources. For year 2000 total emissions in the study area on an average day were estimated as 173 tons PM, 299 tons SOx, 136 tons NOx, 68 tons VOC and 320 tons CO. At the second part of the study, calculated emissions were transformed into air quality predictions in the area by using the Industrial Source Complex – Short Term (ISCST3) dispersion model. Model results were tested with monitoring data from urban air quality stations obtained during the year 2000. Results of the past, present and future air quality estimates in the region were discussed. In order to do so, future scenarios including various control technology applications were formulated and tested to see their effect on the future air quality. 相似文献
9.
Müezzinoglu A 《Environmental management》2000,26(1):47-57
A mediation exercise to resolve the ongoing dispute against these power plant projects at Aliağa was recommended and participated
in by the author in 1997. In this article the basis of the continuing environmental concern about the feared impacts of the
new power plants, procedure, and results of this mediation are mentioned. The basis of the “energy versus environment” dispute
in Aliağa are introduced. Mediation exercise and its end results have been criticized. 相似文献
10.
Batuhan Eren Engin Ismail Yücel Aysen Yilmaz 《Environmental monitoring and assessment》2017,189(7):347
This study investigates the assessment of uncertainty contribution in projected changes of high and low flows from parameterization of a hydrological model and inputs of ensemble regional climate models (RCM). An ensemble of climate projections including 15 global circulation model (GCM)/RCM combinations and two bias corrections (change factor (CF) and bias correction in mean (BC)) was used to generate streamflow series for a reference and future period using the Hydrologiska Byråns Vattenbalansavdelning (HBV) model with the 25 best-fit parameter sets based on four objective functions. The occurrence time of high flows is also assessed through seasonality index calculation. Results indicated that the inputs of hydrological model from ensemble climate models accounts for greater contribution to the uncertainty related to projected changes in high flows comparing to the contribution from hydrological model parameterization. However, the uncertainty contribution is opposite for low flows, particularly for CF method. Both CF and BC increases the total mean variance of high and low flows. The variability in the occurrence time of high flows through RCMs is greater than the variability resulted from hydrological model parameters with and without statistical downscaling. The CF provides more accurate timing than BC and it shows the most pronounced changes in flood seasonality. 相似文献