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排序方式: 共有193条查询结果,搜索用时 15 毫秒
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Renata S. L. Martins Denis M. S. Abessa Adalgiza Fornaro Sueli I. Borrely 《Environmental monitoring and assessment》2014,186(2):1183-1194
Wet deposition is an important process that removes pollutants from the atmosphere and transfers them to waters and soil. The goal of this study was to assess the biological effects of the atmospheric contamination of rainwater in the metropolitan area of São Paulo (MASP) using Daphnia similis, Ceriodaphnia dubia, and Vibrio fischeri. Experimental assays were carried out according to standard toxicity methodology. Twenty-three rainwater samples were collected from October 2007 to December 2008, at the Nuclear Research Institute (IPEN), in MASP. Major ions were determined by ionic chromatography, which showed NH4 + and NO3 ? as prevalent ions. Ecotoxicological results confirmed toxic potential of rainwater, as all samples were toxic to D. similis and C. dubia. The V. fischeri luminescence reduction confirmed those negative effects of rainwater and percentage inhibition of relative luminescence ranged from 0.2 to 0.9 for 16 samples. Worse conditions were observed during the rainy season, suggesting convective rains are more effective in transferring contaminants and toxicity from atmosphere to surface. 相似文献
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Hardiljeet K. Boparai Meera Joseph Denis M. O’Carroll 《Environmental science and pollution research international》2013,20(9):6210-6221
Nano zerovalent iron (nZVI) is an effective remediant for removing various organic and inorganic pollutants from contaminated water sources. Batch experiments were conducted to characterize the nZVI surface and to investigate the effects of various solution properties such as pH, initial cadmium concentration, sorbent dosage, ionic strength, and competitive ions on cadmium removal by nZVI. Energy-dispersive X-ray and X-ray photoelectron spectroscopy results confirmed removal of Cd2+ ions by nZVI through adsorption. Cd2+ adsorption decreased in the presence of competitive cations in the order: Zn2+?>?Co2+?>?Mg2+?>?Mn2+?=?Cu2+?>?Ca2+?>?Na2+?=?K+. Higher concentrations of Cl? significantly decreased the adsorption. Cadmium removal increased with solution pH and reached a maximum at pH 8.0. The effects of various solution properties indicated Cd2+ adsorption on nZVI to be a chemisorption (inner-sphere complexation) process. The three surface complexation models (diffuse layer model, constant capacitance model, and triple layer model) fitted well to the adsorption edge experimental data indicating the formation of nZVI–Cd bidentate inner-sphere surface complexes. Our results suggest that nZVI can be effectively used for the removal of cadmium from contaminated water sources with varying chemical conditions. 相似文献
4.
Chemical sequestration is a natural process taking place in sediments and soils which reduces the availability of hydrophobic compounds such as polycyclic aromatic hydrocarbons (PAHs). The rate of sequestration following the release of PAHs into the aquatic environment is still unexplored. To measure kinetic parameters and investigate governing factors of adsorption and sequestration of individual PAHs, natural sediment slurries were spiked with [2H]-PAHs and periodically extracted with a high molecular weight surfactant solution to determine changes in the available fraction over periods of 7-28 days. Dissolved and/or colloidal [2H]-PAHs were first adsorbed on particles within 4-7 days. Adsorbed molecules became slowly sequestered into sediment particles and were gradually more difficult to extract over a period of 17-20 days. An empirical model based on a three-compartment dynamic system was developed to quantify the sequestration rate constants of a group of seven selected PAHs. The sequestration process was assumed to be a first-order consecutive and irreversible two-stage reaction. The model was tested with lowly contaminated marine sediment and moderately contaminated freshwater sediment. Adsorption rate constants ranged between 0.056 h(-1) and 0.017 h(-1) and were approximately ten times higher than sequestration rate constants. Light PAHs were faster to enter into the sequestration process whereas colloidal dispersion of heavier less soluble PAHs reduced their adsorption rates. Although quite simple, this model was efficient to compute kinetic parameters for most PAHs studied and predict that only a small proportion of adsorbed PAHs would remain extractable after one month. 相似文献
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Denis Meuthen Ingolf P. Rick Timo Thünken Sebastian A. Baldauf 《Die Naturwissenschaften》2012,99(12):1063-1066
Many animal species are able to perceive light wavelengths beyond those visible to humans. While numerous species are additionally sensitive to short wavelengths (UV), long wavelengths such as the near-infrared spectrum (NIR) are supposed to be unsuitable for visual perception. Here, we experimentally show that under exclusive NIR illumination, the cichlid fish Pelvicachromis taeniatus displays a clear foraging response towards NIR reflecting prey. Additional control experiments without prey indicate that the observed behavior is not a mere response to the NIR environment. These results give first evidence for NIR visual sensitivity in a functional context and thus challenge the current view about NIR perception. 相似文献
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Building regional priorities in forests for development and adaptation to climate change in the Congo Basin 总被引:1,自引:0,他引:1
Denis J. Sonwa Johnson N. Nkem Monica E. Idinoba Mekou Y. Bele Cyprain Jum 《Mitigation and Adaptation Strategies for Global Change》2012,17(4):441-450
Indentifying common priorities in shared natural resource systems constitutes an important platform for implementing adaptation
and a major step in sharing a common responsibility in addressing climate change. Predominated by discourses on REDD + (Reduced
Emissions from Deforestation and Forest Degradation and conservation, sustainable management of forests and enhancement of
forest carbon stocks in developing countries) with little emphasis on adaptation there is a risk of lack of policy measures
in addressing climate change in the Congo Basin. Forest products and ecosystem services provide security portfolios for the
predominantly rural communities, and play major roles in national development programmes in both revenue and employment opportunities.
Thus, raising the profile of forests in the policy arena especially in the twin roles of addressing climate change in mitigation
and adaptation and achieving resilient development is crucial. Within the framework of the Congo Basin Forests and Climate
Change Adaptation project (COFCCA) project, science policy dialogue was conducted to identify and prioritize forest based
sectors vulnerable to climate change but important to household livelihoods and national development. The goal of the prioritization
process was for the development of intervention in forest as measures for climate change adaptation in Central Africa. Participants
constituted a wide range of stakeholders (government, Non Governmental Organizations, research institutions, universities,
community leaders, private sectors etc.) as representatives from three countries directly involved in the project: Cameroon,
Central African Republic and Democratic Republic of Congo. Building on national priorities, four forest related sectors were
identified as common priorities at the regional level for focus on climate change adaptation. These sectors included: (1)
energy with emphasis on fuel wood and Charcoal; (2) Water principally quality, quantity, accessibility, etc.; (3) Food with emphasis on Non Timber Forest Products, and (4) Health linked to healthcare products (medicinal plants). Using these prioritized sectors, the project focused on addressing the impacts of climate change on local communities and the development of adaptation strategies in the three pilot countries
of the Congo Basin region. The four sectors constitute the key for development in the region and equally considered as priority sectors in the poverty
reduction papers. Focused research on these sectors can help to inject the role of forests in national and local development
and their potentials contributions to climate change adaptation in national and public discourses. Mainstreaming forest for
climate change adaptation into national development planning is the key to improve policy coherence and effectiveness in forest
management in the region. 相似文献
9.
ABSTRACT: Both L-moment and nonparametric frequency analyses were performed on a series of annual maximum floods from New Brunswick, Canada. The L-moment analysis concluded that the data were generated from a unimodal Generalized Extreme Value (GEV) distribution. However, the nonparametric frequency analysis indicated that a majority of stations followed nonunimodal mixed distributions since peak flows occur during different seasons and are the result of different generating mechanisms. The coupling of L-moment and nonparametric analyses facilitates mixed distribution identification. Thus, the nonparametric method helps in identifying underlying probability distribution, especially when samples arise from mixed distributions. 相似文献
10.
Hesti Lestari Tata Meine van Noordwijk Denis Ruysschaert Rachmat Mulia Subekti Rahayu Elok Mulyoutami Atiek Widayati Andree Ekadinata Riswan Zen Adji Darsoyo Rahayu Oktaviani Sonya Dewi 《Mitigation and Adaptation Strategies for Global Change》2014,19(6):693-713
Tripa is the last remaining peat-swamp forest that harbours a potentially viable Sumatran orangutan (Pongo abelii) sub-population in a formally but not effectively protected area. It appears to be a simple showcase where current efforts to financially support reducing emissions from deforestation and forest degradation (REDD+) converge with biodiversity and social co-benefits. In practice, however, situation is more complex. REDD+ efforts interact with global palm oil trade and regulatory approaches (the moratorium) to achieve national goals for emissions reduction under umbrella of nationally appropriate mitigation actions (NAMA). To contextualize this debate, we assessed (i) land-use history and formal basis of palm-oil companies’ rights; (ii) carbon (C) stocks, historical emission levels and potential emissions that can be avoided; (iii) economic benefits of land-use options and opportunity costs of avoiding emissions; (iv) biodiversity and environmental services; and (v) alternative options for “high C stock development” and employment generation. Natural forest cover declined (54 % in 1995, 18 % in 2009) while oil palm increased 4–39 %. Aboveground C stocks decreased from 148 Mg ha?1 in 1990 to 61 Mg ha?1 in 2009, leading to average annual emissions of 14.5 Mg (carbon dioxide) CO2e ha?1 year?1. While 41 % of these emissions yield less than American Dollar (USD) 5 of current economic benefits per Mg CO2e emitted and might be compensated by REDD+, nearly all new emissions derive from a breach of existing laws, regulations and voluntary palm-oil standards. Substantial investment in alternative employment is needed, rather than carbon payments per se, to support livelihoods in a low carbon emissions economy. 相似文献