Conservation Policies for Protected Areas (Wetlands) in Greece: A Survey of Local Residents' Attitude

This study was carried out in 32 communities neighbouring four Ramsar wetlands in Northern Greece. In particular, it concerns the study of local residents' attitude regarding the ways of management and exploitation of the wetlands and their sociological features, using the opinion poll method (1600 questionnaires were distributed). The aim of this investigation is the evaluation of findings for planning of effective management and conservation policy of wetlands, incorporating the opinions of local residents. Further protection of the wetlands, awareness of local residents of the value of wetlands, tourism or agriculture development (in some cases), as well as more governmental support, became obvious results from this research.     

Large-eddy simulation of low-level jet-like flow in a canopy

The computational method of Large-Eddy Simulations has been used to study the weak, neutrally stable drainage flow within tree canopies. The computational results show that a secondary velocity maximum that resembles a jet is formed within the canopy under the nocturnal flow conditions. This jet-like flow is important in the analysis and measurements of the net ecosystem-atmosphere exchange (NEE) for carbon dioxide (CO₂). A uniformly distributed, plane source was placed within the canopy in order to simulate the nocturnal production of CO₂. The NEE is calculated as the sum of the integration of the rate of change of the concentration of CO₂ over the computational domain, the vertical turbulent flux measured directly by eddy-covariance (EC) method, and the advection terms, which are not taken into account in the EC method. Numerical results of the velocity and concentration fields, within and above the canopy, are presented and their impact on the CO₂ transport is investigated in detail. The computational results show that 15–20% of NEE is drained out by the advection process under the canopy. The results also show that the turbulent fluctuations in the lateral direction are also significant and may result in 2–5% CO₂ transport.     

Organochlorine and mercury contamination in fish tissues from the River Nestos, Greece

Polychlorinated biphenyls (PCBs), hexachlorocyclohexane (HCH) isomers, dichlorodiphenyltrichloroethane (DDT) and its metabolites, other organochlorine pesticides such as hexachlorobenzene (HCB), chlordane compounds (CHLs, including trans-chlordane and cis- and trans-nonachlor) and the heavy metal mercury were quantified in muscle and liver of the European chub (Leuciscus cephalus, Linnaeus, 1758) and in the muscle of the barbel (Barbus cyclolepis, Heckel, 1837) at two sampling sites of the River Nestos, Greece. PCBs in muscle and DDTs in the liver tissues were the predominant organochlorinated contaminants. Among the PCBs, congeners 47 (up to 9.60 ng g(-1) wet wt.), 180 (up to 1.15 ng g(-1) wet wt.) and 190 (up to 1.50 ng g(-1) wet wt.) were the most frequent and abundant. The contamination degree by the sum of PCBs on the fish tissue samples from the River Nestos is lower or similar to PCB levels found in other ecosystems. Among the organochlorine pesticides, essentially only p,p'-DDD, p,p'-DDE and alpha-, beta- and gamma-HCH were found, with the former appearing at mean levels up to 30.71 ng g(-1) wet wt. From a public health standpoint, residue organochlorine pesticide levels from our work are considerably lower than the recommended tolerance limits. Finally, mean values of Hg in chub were significant lower (up to 31.04 ng g(-1) wet wt.) compared to those detected on barbel (up to 169.27 ng g(-1) wet wt.). The concentrations of Hg in fresh water fish from the River Nestos did not exceed WHO and US EPA health guidelines, and were suitable for human consumption.     

Effect of clarification process on the removal of pesticide residues in red wine and comparison with white wine

The aim of this study was to determine the potential of seven clarifying agents to remove pesticides in red wine. The presence of pesticides in wine consists a great problem for winemakers and therefore, results on pesticide removal by clarification are very useful for taking a decision on the appropriate adsorbent. The selection of an efficient adsorbent can be based on data correlating pesticide removal in red wine to pesticides' properties, given the great number and variety of pesticides used. So, this experimental work is focused on the collection of results with regard to pesticide removal by clarification using a great number of pesticides and fining agents. A Greek red wine, fortified with single solutions and mixtures of 23 or 9 pesticides was studied. The seven fining agents, used at two concentrations, were activated carbon, bentonite, polyvinylpolypyrrolidone (PVPP), gelatin, egg albumin, isinglass-fish glue, and casein. Pesticides were selected with a wide range of properties (octanol–water partition coefficient (log K_ow) 2.7–6.3 and water solubility 0.0002–142) and belong to 11 chemical groups. Solid phase extraction (SPE) followed by gas chromatography (GC) with electron capture detector (ECD) were performed to analyze pesticide residues of the clarified fortified wine. The correlation of the clarifying agents' effectiveness to pesticide's chemical structure and properties (log K_ow, water solubility) was investigated. The antagonistic and/or synergistic effects, occurring among the pesticides in the mixtures, were calculated by indices. Pesticide removal effectiveness results of the red wine were compared to those obtained from a white wine under the same experimental conditions and discussed. The order of decreasing adsorbent effectiveness (mixture of 23 pesticides) was: activated carbon 40% > gelatin 23% > egg albumin 21% > PVPP 18% > casein 12% > bentonite 7%. Isinglass showed 12% removal at the highest permitted concentration. In the case of 9 pesticides mixture, the effectiveness was quite higher but the order remained the same compared to 23 pesticides mixture. The removal of each pesticide from its single solution was generally the highest (particularly for hydrophobic pesticides). Adsorption on fining agents is increased by increasing hydrophobicity and decreasing hydrophilicity of organic pesticide molecules.     

Secondary flow within a river bed and contaminant transport

We have developed a numerical method to simulate the transport of non-sorbing contaminants within the sediment layer of a stream and the leaching of these contaminants in the steam. Typical stream bottom surfaces are uneven with triangularly shaped undulation forms. The flow of the water above such triangular surfaces causes external pressure changes that result in a “pumping effect” and a secondary flow within the sediment. The latter causes a significant contaminant advection within the sediment layer. The flow field in the porous sediment layer is obtained by solving numerically Darcy’s equations. The unsteady mass transfer equation is solved by using a finite-difference method with an up-wind scheme. The effects of parameters, such as channel slope, hydraulic head and dispersion, are studied by quantitatively comparing the numerical results of the total mass flow rate from the contaminant source, the concentration front propagation, and the contaminant mass flow rate into the water column. The “pumping effect,” increases the flow in the vertical direction and, thus, enhances the vertical advective mass transport of the contaminant. This bedform-shape induced flow is largely responsible for the mass transfer of contaminants into the water column. The numerical results also show that the mechanical dispersion inside the sediment bed will significantly increase the contaminant mass flow rate from the source.