Steel mill waste application in soil: dynamics of potentially toxic elements in rice and health risk perspectives

Environmental Science and Pollution Research - Potentially toxic elements (PTEs) are of great concern in steel mill wastes. Therefore, in order to use them as potential fertilizers in soil, risk...     

Heavy metals in water, sediment and tissues of Liza saliens from Esmoriz–Paramos lagoon, Portugal

Esmoriz–Paramos lagoon is an ecosystem of great ecological importance that is located on the northwest coast of Portugal and has been degraded as a result of industrial and anthropogenic activities. Concentrations of heavy metals (Cr, Cu, Pb and Zn) were measured in water, sediment and in tissues (liver and muscle) of Liza saliens, which is the dominant fish from the lagoon. Comparisons between metal concentrations in water and sediments were made with those in tissues of fish caught at the lagoon. Metals in water were quantified predominantly bound to particulate and equalled or exceeded the limit of chronic reference values. Metal concentrations in sediments varied among sampled sites. The relative order of concentrations was “Zn > Cu ∼ Pb > Cr” the same pattern observed for metals in water. Metals in fish tissues showed higher concentrations in liver (262 mg Cu·Kg⁻¹ and 89 mg Zn·Kg⁻¹) than in muscle (<3 mg Cu·Kg⁻¹ and 26 mg Zn·Kg⁻¹), while Pb and Cr were not detected. These results suggest that Cu and Zn are the metals of major concern in the lagoon. Mullet detritivorous feeding habits, bioaccumulation pattern and the high sediment metals concentrations relative to the water suggest that sediments can be the most important source of contamination in this ecosystem. The positive relationship found between Cu in liver and fish length demonstrates that time of exposure is a crucial factor in bioaccumulation. Condition indices (K and HSI) in mullets from the lagoon were higher compared to mullets from sea, suggesting abnormal condition in the lagoon population. We conclude that metals chronic exposure in the lagoon can impose considerable fish stress. The results also show that the lagoon is an area of environmental concern.     

Chthamalus montagui as biomonitor of metal contamination in the northwest coast of Portugal

The concentrations of seven metals (Cd, Cr, Cu, Fe, Mn, Ni and Zn) were determined in coastal seawaters and soft and hard tissues of the barnacle Chthamalus montagui from the northwest coast of Portugal to assess the potential use of C. montagui as biomonitor of metal contamination. The results of this study showed that C. montagui soft tissues can be used for monitoring metal bioavailabilities in these coastal seawaters: (1) there were significant correlations (p?相似文献   

Goose barnacle Pollicipes pollicipes as biomonitor of metal contamination in the northwest coast of Portugal

The main objective of this work was to assess the potential use of goose barnacle Pollicipes pollicipes as biomonitor of metal contamination in northwest (NW) coast of Portugal. The concentrations of Cd, Cr, Cu, Fe, Mn, Ni and Zn were determined in coastal seawaters and tissues of P. pollicipes, which allowed establishing correlations between metals in coastal seawaters and P. pollicipes and calculating metal bioaccumulation factors (BAFs). The results of this study showed that P. pollicipes soft tissues can be used for monitoring metal contamination in these coastal seawaters: (1) there were significant correlations (p??0.05); (2) soft tissues were sensitive to spatial variations of metal bioavailabilities and their concentrations ranged 0.70-2.22?mg?Cd?kg(-1), 0.49-1.40?mg?Cr?kg(-1), 1.37-2.07?mg?Ni?kg(-1), 2.4-3.3?mg?Cu?kg(-1), 5-59?mg?Mn?kg(-1), 134-578?mg?Fe?kg(-1)and 728-1,854?mg?Zn?kg(-1); (3) mean logarithmic bioaccumulation factors (log BAF) of Fe, Cd and Zn were higher, 5.57, 5.47 and 4.41, respectively, than mean log BAFs of Cr, Mn, Cu and Ni, 4.18, 4.14, 3.98 and 3.51, respectively. In contrary, P. pollicipes shell plates were not considered ideal material to monitor metal bioavailabilities in these coastal seawaters. Regarding the very high concentrations of Zn obtained in the coastal seawaters and P. pollicipes soft tissues, the NW coast of Portugal should be classified as "Class III/IV - Remarkably/Highly Polluted".     

Salt marsh plants as key mediators on the level of cadmium impact on microbial denitrification

The fate of excess nitrogen in estuaries is determined by the microbial-driven nitrogen cycle, being denitrification a key process since it definitely removes fixed nitrogen as N₂. However, estuaries receive and retain metals, which may negatively affect this process efficiency. In this study, we evaluated the role of salt marsh plants in mediating cadmium (Cd) impact on microbial denitrification process. Juncus maritimus and Phragmites australis from an estuary were collected together with the sediment involving their roots, each placed in vessels and maintained in a greenhouse, exposed to natural light, with tides simulation. Similar non-vegetated sediment vessels were prepared. After 3 weeks of accommodation, nine vessels (three per plant species plus three non-vegetated) were doped with 20 mg/L Cd²⁺ saline solution, nine vessels were doped with 2 mg/L Cd²⁺ saline solution and nine vessels were left undoped. After 10 weeks, vessels were dissembled and denitrification potential was measured in sediment slurries. Results revealed that the addition of Cd did not cause an effect on the denitrification process in non-vegetated sediment but had a clear stimulation in colonized ones (39 % for P. australis and 36 % for J. maritimus). In addition, this increase on denitrification rates was followed by a decrease on N₂O emissions and on N₂O/N₂ ratios in both J. maritimus and P. australis sediments, increasing the efficiency of the N₂O step of denitrification pathway. Therefore, our results suggested that the presence of salt marsh plants functioned as key mediators on the degree of Cd impact on microbial denitrification.     

Does ISO 14001 work in Brazil?

As a result of increasing global awareness about the importance of the environment, depletion of natural resources and legal pressures for companies to manage their processes in a sustainable manner, ISO 14001 systems have been gaining increasingly more importance in the organizational scenario. These elements are even more critical in emerging nations due to less awareness and fewer demands by governments and the population in relation to environmental issues. Therefore, the main objective of this study is to verify the benefits and difficulties of Environmental Management Systems based on ISO 14001 at industries in the state of São Paulo – Brazil (an emerging country) by conducting a survey to subsidize the proposal for actions in the public, academic and private sectors to promote the use of this standard of reference and strengthen its results in Brazil. A questionnaire was sent to 194 companies from the National Institute of Metrology, Standardization and Industrial Quality database. 69 answered, representing a return rate of 35.36%. The main benefits identified are related to the development of preventive environmental actions, reduction in the consumption of power, water, gas and fuel oil, and a positive influence on other internal management processes. The main difficulties are related to cost increases from ISO 14001 management systems and the constant changes in environmental legislation in Brazil. Some actions are proposed at the end of the analyses to intensify the use and improve the results of this standard, such as changes in government legislation and its collective development and implementation in industries.     

Power models and average ship parameter effects on marine emissions inventories

Maritime greenhouse gas emissions are projected to increase significantly by 2050, highlighting the need for reliable inventories as a first step in analyzing ship emission control policies. The impact of ship power models on marine emissions inventories has garnered little attention, with most inventories employing simple, load-factor-based models to estimate ship power consumption. The availability of more expansive ship activity data provides the opportunity to investigate the inventory impacts of adopting complex power models. Furthermore, ship parameter fields can be sparsely populated in ship registries, making gap-filling techniques and averaging processes necessary. Therefore, it is important to understand of the impact of averaged ship parameters on ship power and emission estimations. This paper examines power estimation differences between results from two complex, resistance-based and two simple, load-factor-based power models on a baseline inventory with unique ship parameters. These models are additionally analyzed according to their sensitivities toward average ship parameters. Automated Identification System (AIS) data from a fleet of commercial marine vessels operating over a 6-month period off the coast of the southwestern United States form the basis of the analysis. To assess the inventory impacts of using averaged ship parameters, fleet-level carbon dioxide (CO₂) emissions are calculated using ship parameter data averaged across ship types and their subtype size classes. Each of the four ship power models are used to generate four CO₂ emissions inventories, and results are compared with baseline estimates for the same sample fleet where no averaged values were used. The results suggest that a change in power model has a relatively high impact on emission estimates. They also indicate relatively little sensitivity, by all power models, to the use of ship characteristics averaged by ship and subtype.

Implications: Commercial marine vessel emissions inventories were calculated using four different models for ship engine power. The calculations used 6 months of Automated Identification System (AIS) data from a sample of 248 vessels as input data. The results show that more detailed, resistance-based models tend to estimate a lower propulsive power, and thus lower emissions, for ships than traditional load-factor-based models. Additionally, it was observed that emission calculations using averaged values for physical ship parameters had a minimal impact on the resulting emissions inventories.     

Short- and medium-term effects of experimental nitrogen fertilization on arthropods associated with Calluna vulgaris heathlands in north-west Spain

We studied the short- and medium-term effects of experimental nitrogen fertilization (3 and 15 months after the treatment) on the arthropods of Calluna vulgaris heathlands in NW Spain. Three heathland sites were selected with two permanent plots per site: control and fertilized. Ammonium nitrate fertilizer (56 kg N ha(-1) yr(-1)) was applied monthly and insects were caught using pitfall traps. We found mainly species-level responses to nitrogen addition. Seven species (e.g. Lochmaea suturalis) showed a consistent trend (benefited or harmed) in both periods and were proposed as possible reliable indicators of the effects of nitrogen deposition in these ecosystems. We also found variable arthropod trophic-group responses: (a) herbivores (leaf beetles, true bugs) increased in abundance on a short-term scale; (b) predators (carabid beetles, true bugs) showed opposite and less clear responses in both periods. Further long-term studies are needed to determine the mechanisms underlying the observed arthropod responses.     

Environmental monitoring of water resources around a municipal landfill of the Rio Grande do Sul state,Brazil

Environmental Science and Pollution Research - In Brazil, landfills are commonly used as a method for the final disposal of waste that is compliant with the legislation. This technique, however,...