Assay of some volatile compounds in human exhalation

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Societal Concerns about Pork and Pork Production and Their Relationships to the Production System

Pork producers in Western Europe moreand more encounter a variety of societalconcerns about pork and pork production. Sofar, however, producers predominantly focusedon low consumer prices, therewith addressingjust one concern. This resulted in an intensiveand large-scale production system, decreasinglyrelated to the area of farm land, andaccompanied with increasing concerns aboutsafety and healthiness of pork, animal welfare,environmental pollution, and others.An overview was given of possible concernsabout West-European pork production with theconsumers, citizens, and producers, and thoseconcerns are traced back to the pork productionsystem. The various kinds and qualities ofinformation about the pork production system onwhich possible concerns are based have beenworked out extensively in this paper. Knowledgeabout the aspects of pork production that cangive rise to concerns can be used in two ways.First, the communication about those aspectstowards consumers and citizens can be adjustedor extended to give them better possibilitiesto make food choices or to develop their ownopinions about pork production. Second,producers could change the pork productionsystem such that it better satisfies consumersand citizens. Such adaptations are wellpossible, as three pork quality schemes, whichhave been evaluated, illustrate. However, mostof these adaptations can only be carried out atthe cost of the present low consumer prices andwill not occur spontaneously on a large scale.Therefore, accounting for the type andrelevance of the concerns, legislation isnecessary to address societal concerns in abalanced way such that pork production systemsbecome acceptable for the majority of oursociety.     

Climate engineering and human rights

ABSTRACT

In this Forum, three scholars discuss how climate engineering will pose novel human rights challenges, and may well force reconsideration of how human rights are applied as a guide to action. Following a short introduction, the first section introduces three competing approaches to human rights, arguing views which emphasize fairness or attempt to maximize satisfaction are more promising than one viewing human rights as inviolable ‘side-constraints’. The second section draws lessons from climate migration that are relevant for climate engineering in terms of incorporating a human rights approach to duties, rights, and participation. The final section compares the ‘needs-based’ and ‘rights-based’ approaches to humanitarian work in the face of climate change and climate engineering, raising concerns for duty-bearers and right-holders. The Forum’s conclusion draws together points of overlap and suggests a path forward for policy and research on this topic.     

Are seed and dispersal characteristics of plants capable of predicting colonization of post-mining sites?

Seed characteristics play an important role in the colonization and subsequent persistence of species during succession in disturbed sites and thus may contribute to being able to predict restoration success. In the present study, we investigated how various seed characteristics participated in 11 spontaneous successional series running in different mining sites (spoil heaps, extracted sand and sand-gravel pits, extracted peatlands, and stone quarries) in the Czech Republic, Central Europe. Using 1864 samples from 1- to 100-years-old successional stages, we tested whether species optimum along the succession gradient could be predicted using 10 basic species traits connected with diaspores and dispersal. Seed longevity, diaspore mass, endozoochory, and autochory appeared to be the best predictors. The results indicate that seed characteristics can predict to a certain degree spontaneous vegetation succession, i.e., passive restoration, in the mining sites. A screening of species available in the given landscape (regional and local species pools) may help to identify those species which would potentially colonize the disturbed sites. Extensive databases of species traits, nowadays available for the Central European flora, enable such screening.     

Sample storage and extraction efficiencies in determination of polycyclic and nitro musks in sewage sludge

Analytical technology is continuously improving, developing better methods for isolating and concentrating trace compounds in environmental samples. Polycyclic and nitro musks (PNMs) are one group of emerging trace compounds detected in municipal wastewater. Differences in sample storage, preparation, and extraction methods for their measurement have led to variability in results. We analyzed 11 PNMs by GC/MS and compared the results of different storage times and extraction methods (supercritical fluid (SFE) or microwave-assisted (MAE)) for 202 samples of primary sludge, waste activated sludge (WAS), raw sludge, and aerobically/anaerobically digested biosolids collected from Canadian municipal wastewater treatment plants. Sixty-three air-dried samples were extracted by SFE, and 139 air-dried, centrifuged, or filtered samples were extracted by MAE. The mean surrogate recoveries were 89% (standard deviation (SD)=11%) for d(10)-anthracene by SFE and 88% (SD=14%) for d(10)-phenanthrene by MAE. Storage study results showed that PNM concentrations changed by a mean of 7% and 9% for primary sludge and WAS respectively after four weeks and decreased up to 25% after 13.5 months of storage in amber glass containers at -18 degrees C. Air-drying of sludge at room temperature caused losses of about 50% of PNM concentrations compared to centrifugation. The proportions of PNMs present in the liquid phase of sludge samples were less than 5% compared to proportions in the sludge solids. The most complete liquid-solid separation was achieved by filtration of frozen/thawed sludge samples, producing a liquid phase that contained less than 1% of the total musk content of the sample.     

Aggregation and ecotoxicity of CeO₂ nanoparticles in synthetic and natural waters with variable pH, organic matter concentration and ionic strength

The influence of pH (6.0-9.0), natural organic matter (NOM) (0-10 mg C/L) and ionic strength (IS) (1.7-40 mM) on 14 nm CeO₂ NP aggregation and ecotoxicity towards the alga Pseudokirchneriella subcapitata was assessed following a central composite design. Mean NP aggregate sizes ranged between 200 and 10000 nm. Increasing pH and IS enhanced aggregation, while increasing NOM decreased mean aggregate sizes. The 48 h-E_rC20s ranged between 4.7 and 395.8 mg CeO₂/L. An equation for predicting the 48 h-E_rC20 (48 h-E_rC20 = −1626.4 × (pH) + 109.45 × (pH)² + 116.49 × ([NOM]) − 14.317 × (pH) × ([NOM]) + 6007.2) was developed. In a validation study with natural waters the predicted 48 h-E_rC20 was a factor 1.08-2.57 lower compared to the experimental values.     

Multi-GCM projections of future drought and climate variability indicators for the Mediterranean region

Future climate conditions for the Mediterranean region based on an ensemble of 16 Global Climate Models are expressed and mapped using three approaches, giving special attention to the intermodel uncertainty. (1) The scenarios of mean seasonal temperature and precipitation agree with the projections published previously by other authors. The results show an increase in temperature in all seasons and for all parts of the Mediterranean with good intermodel agreement. Precipitation is projected to decrease in all parts and all seasons (most significantly in summer) except for the northernmost parts in winter. The intermodel agreement for the precipitation changes is lower than for temperature. (2) Changes in drought conditions are represented using the Palmer Drought Severity Index and its intermediate Z-index product. The results indicate a significant decrease in soil moisture in all seasons, with the most significant decrease occurring in summer. The displayed changes exhibit high intermodel agreement. (3) The climate change scenarios are defined in terms of the changes in parameters of the stochastic daily weather generator calibrated with the modeled daily data; the emphasis is put on the parameters, which affect the diurnal and interdiurnal variability in weather series. These scenarios indicate a trend toward more extreme weather in the Mediterranean. Temperature maxima will increase not only because of an overall rise in temperature means, but partly (in some areas) because of increases in temperature variability and daily temperature range. Increased mean daily precipitation sums on wet days occurring in some seasons, and some parts of the Mediterranean may imply higher daily precipitation extremes, and decreased probability of wet day occurrence will imply longer drought spells all across the Mediterranean.     

Nitrous oxide (N2O) emissions from waste and biomass to energy plants.

Following the Kyoto protocol with respect to reducing emissions of greenhouse gases emissions, and EU energy policy and sustainability in waste management, there has been an increased interest in the reduction of emissions from waste disposal operations. From the point of view of nitrous oxide (N2O) emissions, waste incineration and waste co-combustion are very acceptable methods for waste disposal. In order to achieve very low N2O emissions from waste incineration, particularly for waste with higher nitrogen content (e.g. sewage sludge), two factors are important: temperature of incineration over 900 degrees C and avoiding the selective non-catalytic reduction (SNCR) de-NO(X) method based on urea or ammonia treatments. The more modern selective catalytic reduction (SCR) systems for de-NO(X) give rise to negligible sources of N2O.     

Functional autotrophy of Heteroxenia fuscescens (Anthozoa: Alcyonaria): carbon assimilation and translocation of photosynthates from symbionts to host

The association of the alcyonarian Heteroxenia fuscescens (Ehrb.) with its cytosymbiotic algae shows structural and physiological adaptations optimizing the living together of the two partners as one functional unit. To enhance the energetic contribution of the autotrophic partner, the organization of the heterotrophic partner bears typical plant-like imprints. Up to 20% of the inorganic C photosynthetically fixed was translocated to the host (=2 mg C mg d.w.^-1 d^-1). This net C gain by the host is used for anabolic purposes including the deposition of storage material. Especially the wax-esters and triglycerides of the host-in contrast to those of the symbionts-were intensively labelled. The in-vivo ¹⁴C-fixation of zooxanthellae is more than double the in-vitro fixation. In both symbionts and host, the lipids show the highest relative ¹⁴C-incorporation. In particular the polyol component was strongly labelled. After 120 min of continuous incubation, approximately 40 labelled intracellular metabolites were detectable in the ethanol/water soluble fractions of zooxanthellae. Glycerol is the main low-molecular weight carbohydrate being transferred. This is corroborated by the deacylation of lipids of the host.