Adsorption of sugar beet herbicides to Finnish soils

Three sugar beet herbicides, ethofumesate, phenmedipham and metamitron, are currently used on conventional sugar beet cultivation, while new varieties of herbicide resistant (HR) sugar beet, tolerant of glyphosate or glufosinate-ammonium, are under field testing in Finland. Little knowledge has so far been available on the adsorption of these herbicides to Finnish soils. The adsorption of these five herbicides was studied using the batch equilibrium method in 21 soil samples collected from different depths. Soil properties like organic carbon content, texture, pH and partly the phosphorus and oxide content of the soils were tested against the adsorption coefficients of the herbicides. In general, the herbicides studied could be arranged according to their adsorption coefficients as follows: glyphosate>phenmedipham>ethofumesate approximately glufosinate-ammonium>metamitron, metamitron meaning the highest risk of leaching. None of the measured soil parameters could alone explain the adsorption mechanism of these five herbicides. The results can be used in model assessments of risk for leaching to ground water resulting from weed control of sugar beet in Finland.     

Spray charging of droplets in a wet scrubber

The experimental setup was designed to study the effect of natural charging of droplets during spraying (called spray electrification or spray charging) in a wet scrubber. The influence of nozzle material, liquid feed rate, and liquid composition on the specific charge (charge per unit volume of liquid) formed in spraying was measured. It was found that the nozzle material has no measurable effect on this specific charge. Increasing the liquid feed rate increases the specific charge significantly. Increasing solute (NaCl or NaOH) concentration increases the conductivity that decreases the formed specific charge. The same correlation between the specific charge and conductivity was also observed with real scrubbing liquids. It is proposed that the specific charge depends only on the value of liquid conductivity, not on liquid composition. The conductivity of the tested scrubbing liquids was high enough to suppress the formation of a high specific charge during spraying.     

Effects of soil phosphorus status on environmental risk assessment of glyphosate and glufosinate-ammonium

The increased use of herbicides poses a risk to the aquatic environment. Easy and economical methods are needed to identify the fields where specific environment protection measures are needed. Phosphorus (P) and organophosphorus herbicides compete for the same adsorption sites in soil. In this study the relationship between P obtained in routine Finnish agronomic tests (acid ammonium acetate [P(AC)]) and adsorption of glyphosate and glufosinate-ammonium was investigated to determine whether P(AC) values could be used in the risk assessment. The adsorption of glyphosate ((N-(phosphonomethyl)glycine) and glufosinate-ammonium (2-amino-4-(hydroxymethylphosphinyl)butanoic acid) was studied in a clay and a sandy loam soil enriched with increasing amounts of P added as potassium dihydrogen phosphate. Desorption was also determined for some P-enriched soil samples. The adsorption of both herbicides diminished with increasing P(AC) value. The correlations between Freundlich adsorption coefficients obtained in the adsorption tests and P(AC) were nonlinear but significant (r > 0.98) in both soils. The exponential models of the relationship between soil P(AC) values and glyphosate adsorption were found to fit well to an independent Finnish soil data set (P < 0.1 for glyphosate and P < 0.01 for glufosinate-ammonium). The desorption results showed that glufosinate-ammonium sorption is not inversely related to soil P status, and the high correlation coefficients obtained in the test of the model were thus artifacts caused by an abnormal concentration of exchangeable potassium in soil. The solved equations are a useful tool in assessing the leaching risks of glyphosate, but their use for glufosinate-ammonium is questionable.     

Comprehensive two-dimensional gas chromatography, a valuable technique for screening and semiquantitation of different chemical compounds in ultrafine 30 nm and 50 nm aerosol particles

Comprehensive two dimensional gas chromatography-time-of-flight mass spectrometry (GC×GC-TOF-MS) was used for screening and semiquantitation of semivolatile organic compounds in aerosol particles. As the volatility was a prerequisite parameter for the analysis, some compounds were transformed via derivatization such as silylation into more volatile ones. The identification of the analytes was made by comparing the GC retention indices and the TOF mass spectra with the NIST and the Golm metabolome database reference libraries. The data treatment was simplified by exploiting an additional classification of the identified compounds, namely the main functional group or specific element present in the molecule leading to different groups of compounds. This methodology was applied to identify compounds in 30 ± 4 nm, 50 ± 5 nm and total suspended particles (TSP) collected during spring and autumn of 2009 and summer of 2010 at the Station for Measuring Forest Ecosystem Atmosphere Relations (SMEAR II) at Hyyti?l? (Finland). The number of identified compounds was higher than 400, which were the most relevant compounds present in the samples, in terms of concentrations. The analysis of aerosol particles of different sizes, collected simultaneously, revealed that the number of compounds increased with the particle size whereas the normalized response factor decreased in most of the cases, aldehydes being an exception. This decrease could be associated with the formation or aggregation of new compounds onto the particles when they grow in the atmosphere.     

A new-generation safety contest in the construction industry – A long-term evaluation of a real-life intervention

A new-generation safety campaign has been taking place in southern Finland since 1997. The Finnish Construction Employer’s Association together with trade unions, safety inspectorates, and other institutions have been organising a safety contest based on the standardised TR-observation method. Safety inspectors conduct evaluation visits without previous notice to the sites, and best performing companies and sites are rewarded at annually held public seminars. Even though participation is voluntary, more than 70% of the total number of construction sites in the target area have participated in the contest, and the results have been successful. Deficiencies in protection against falling have decreased by 63%, in order and tidiness by 69%, and in working habits by 51%. The effectiveness is also evident in the accident figures. An estimated 4000 accidents and three fatalities are prevented each year, while other parts of the country during the same period show no improvement in accident risk. A key success factor may be the adoption among firms of a new, standardised safety monitoring method which has been used effectively by senior management teams. The method employs a combination of penalties and incentives in order to set and enforce new safety targets. Another success factor is the close co-operation between the construction industry, labour organisations and safety authorities.     

Pulverization of fibrous mineral wool waste

Journal of Material Cycles and Waste Management - The total annual volume of mineral wool waste in the 27 European Union countries is expected to increase to 2.5&nbsp;million tons per year by...