Evidence of reproductive disturbance in Astyanax lacustris (Teleostei: Characiformes) from the Doce River after the collapse of the Fundão Dam in Mariana,Brazil

Environmental Science and Pollution Research - The Fundão Dam collapsed, on November 5th, 2015, dumping more than 50 million/m3 of iron ore tailings, enriched with metals, into the Doce River...     

2,4-Dichlorophenoxyacetic acid (2,4-D) photodegradation on WO3-TiO2-SBA-15 nanostructured composite

Environmental Science and Pollution Research - A current environmental problem is the uncontrolled use of various pesticides that are harmful to the environment and public health. The herbicide...     

Degradability and Sediment Sorption of an Alcohol Polyglycol Ether Surfactant Putatively Useful for the Control of Red Swamp Crayfish in Rice Fields

This work reports studies of the degradation rates of a fattyalcohol polyglycol ether non-ionic surfactant, Genapol OXD-080, putatively useful for the control of red swamp crayfish (Procambarus clarkii Girard) in rice fields under laboratory and field conditions. The influence of temperature,sediment site specificity and sorption were taken into account.The degradation kinetics of the surfactant depends on the experimental conditions: type of inocula and temperature. Thedistribution of this chemical in aquatic systems was also examined. Genapol OXD-080 was removed into the sedimentsreadily after application, and sorption was considered the majorpath of removal from the water phase. Data suggest that furtherstudies are required regarding the effects of Genapol OXD-080 in aquatic organisms resident in rice fields, in parallelwith the development of technologies related with the use ofsurfactants to control P. clarkii populations.     

Effect of Cross-Linking Waste Protein with Dialdehydes on Its Biodegradation Under Anaerobic Conditions

Most native polymers used in processing and application technologies are admittedly disposable from the environment in a biologic manner, but products possess low mechanical strength. One of the paths to increasing this attribute (if feasible) is their cross-linking, which may, however, affect their readiness to biodegradation. In the presented work this condition was observed on the example of waste protein (Hykol B) cross-linking by means of glutardialdehyde and glyoxal. Degree and course of cross-linking were determined through impedance spectroscopy. The objective of this work also was to obtain data for constructing a sensor capable of following the cross-linking course in real time, for potential industrial application of Hykol in continuous production. Impedance spectroscopy proved to be applicable even to this kind of material marked by considerable water content and exhibiting relatively high electric conductivity; so far it had been used only for materials of low conductivity. An aqueous environment inoculated with digested anaerobic sludge from a municipal wastewater treatment plant was selected for modeling anaerobic conditions. The relation was studied between cross-linking degree given by content of cross-linking agent (determined by impedance spectroscopy) and biodegradation degree under anaerobic conditions. It was confirmed that network density as given by quantity of added agent not only reduced breakdown degree but also slowed the course of the process. This fact is particularly obvious with cross-linking by means of glyoxal; network density is thus dependent on type of employed substance, which affect type and structure of created network. That not merely forms an obstacle during polymer swelling and dissolution but also prevents access of bacteria to source of metabolized organic carbon.     

The methylic versus the ethylic route: considerations about the sustainability of Brazilian biodiesel production

Brazil is considered one of the world’s leading producers of biofuels given the predominance of ethanol fuel in its energy matrix. However, despite the prominence of Brazil in ethanol production, the vast majority of biodiesel production plants in Brazil use methanol instead of ethanol as the alcohol for transesterification reaction, as is generally the case in the rest of the world. The aim of this paper is therefore to examine the transesterification process in the Brazilian biodiesel production in terms of sustainability. In this regard, it was necessary to evaluate the way in which the industrial process is currently carried out, the role of government incentives or subsidies for the use of ethanol to produce biodiesel, and the investments of companies in technology development for the same purpose. This study presents indications that the development of the biodiesel market in Brazil is still oriented toward a production model which is inconsistent with the environmental and social aspects of sustainability.     

Esterification of sugarcane bagasse by citric acid for Pb2+ adsorption: effect of different chemical pretreatment methods

In this study, different pretreatment strategies of sugarcane bagasse prior to citric acid modification were investigated in terms of Pb²⁺ adsorption capacity. Pretreatment strategies included the use of NaOH, HCl, and C₂H₅OH in various concentrations. In order to fundamentally understand how these pretreatment methods affect the modification of sugarcane bagasse by citric acid as well as the Pb²⁺ adsorption capacity of sugarcane bagasse, three main components of sugarcane bagasse namely cellulose, hemicellulose, and lignin were isolated and esterified by citric acid under the same conditions. ATR-FTIR, XPS, SEM, and an analysis of the number of carboxylic acid groups were used to investigate the physicochemical and chemical properties of the materials. These three components were proved to participate in adsorption and induce the esterification with citric acid. Hence, pretreatment with ethanol and 0.01 M NaOH which could retain cellulose, hemicellulose, and lignin in sugarcane bagasse achieved a high Pb²⁺ adsorption capacity, i.e., 122.4 and 97 mg/g after the esterification with citric acid. In contrast, pretreatment with 0.5 M NaOH and 0.1 M HCl removed lignin and hemicellulose, leading to the lowest value of approximately 45 mg/g for citric acid esterified-pretreated sugarcane bagasse. XPS analysis and number of carboxylic group measurement confirmed the esterification between bagasse and citric acid. To understand the adsorption mechanism of adsorbent, two kinetic models including pseudo-first-order model and pseudo-second-order model were applied. The experimental data were well described by the pseudo-second-order model. The adsorption isotherm data were fitted Langmuir and Freundlich.

     

Steel mill waste application in soil: dynamics of potentially toxic elements in rice and health risk perspectives

Environmental Science and Pollution Research - Potentially toxic elements (PTEs) are of great concern in steel mill wastes. Therefore, in order to use them as potential fertilizers in soil, risk...     

Magnetic photocatalysts from δ-FeOOH and TiO2 and application in reactions for degradation of methylene blue and paracetamol with UV-C and sunlight

Environmental Science and Pollution Research - Water contamination is a common problem, especially considering dyes and drugs disposal. A possible and effective treatment method to remove these...