Catalytic degradation of toxic organic dye using an aluminum-doped Cu0.4Zn0.6-xAlxFe2O4 (x = 0.0, 0.2, 0.4, 0.6) spinel ferrite in a photo-Fenton system

Catalytic activity of spinel ferrite in breaking down toxic dye materials are promising due to their uniqueness. In this study, aluminum-doped copper zinc ferrite, Cu_0.4Zn_0.6-xAl_xFe₂O₄ (x = 0.0, 0.2, 0.4, 0.6), a catalyst for toxic dye degradation is synthesized through chemical co-precipitation route. The formation of the spinel ferrite catalyst is initially confirmed by Fourier transform infrared spectra, which shows the frequency of metal-oxygen bond vibration at 539 and 427 cm⁻¹ attributed to the tetrahedral and octahedral sites respectively. Higher intensity sharp peak of X-ray diffraction for (311) plane is the evidence for the phase purity and the formation of spinel ferrite. The crystallite size is found to decrease with the increase of Al³⁺ ion. The surface structure of the obtained particles is investigated using a scanning electron microscope. Analyses of the material's magnetic characteristics using a vibrating sample magnetometer (VSM) revealed that it is, in fact, a soft magnet, as evidenced by the loop of its hysteresis, which is narrow. The catalytic degradation of methylene blue dye under the mechanism of the photo-Fenton process is studied with the obtained spinel ferrites and the result is found to be as high as 96.5%. The process follows pseudo-second order kinetics and the Langmuir isotherm.     

A fuzzy goal programming with interval target model and its application to the decision problem of renewable energy planning

Environmental and Ecological Statistics - Optimizing sustainable renewable energy portfolios is one of the most complicated decision making problems in energy policy planning. This process involves...     

Toxicity of Water-Soluble Fractions of Four Fuels for Metamysidopsis insularis, an Indigenous Tropical Mysid Species

The toxicity of the water-soluble fraction (WSF) of four fuels (leaded gasoline, unleaded gasoline, diesel, Jet A-1) to Metamysidopsis insularis, an indigenous tropical mysid species was determined. Approximately 10 000 barrels (bbl) of fuel are consumed daily in Trinidad and Tobago, and about 50 000 bbl are exported. Accidental discharges at points of transfer as well as from inadequate storage facilities, can pose a significant contamination risk to the environment. Organisms were assayed with the WSF under both UV and fluorescent lights. The WSF was prepared using different fuel/seawater (v/v) mixtures. It was found that organisms exposed to diesel, Jet A-1 and unleaded gasoline showed similar toxicological responses under both light regimes, and were more toxic than the leaded gasoline. The results also showed that none of these fuels show photo-induced toxicity. The WSF of the 0.1% mixtures of unleaded gasoline, diesel and Jet A-1 were acutely toxic to M. insularis. However, for the leaded gasoline, only the 0.5% mixture was acutely toxic. The high toxicity of these fuels may be due to the presence of light, more soluble fractions. It is therefore likely that these fuels will have significant impacts in our local environment, if any spills occur.     

Surface‐ and deep‐level diversity in workgroups: examining the moderating effects of team orientation and team process on relationship conflict

The increased use of teams in organizations, coupled with an increasingly diverse workforce, strongly suggests that we should learn more about how team diversity affects functioning and performance. The purpose of this study was to explore the differential impact of surface‐level diversity (gender, ethnicity), deep‐level diversity (time urgency, extraversion), and two moderating variables (team orientation, team process) on relationship conflict over time. Hypotheses were tested by tracking 45 student project teams in a longitudinal design. Results revealed that team orientation and team process moderated the diversity–conflict link. Specifically, team orientation helped to neutralize the negative effects of surface‐level (gender) diversity on relationship conflict. In a similar manner, team processes worked to weaken the deleterious effects of deep‐level diversity (time urgency) on relationship conflict. In addition, relationship conflict resulted in lower perceived performance by team members. Copyright © 2004 John Wiley & Sons, Ltd.     

Investigation on the effect of sintering temperature on kaolin hollow fibre membrane for dye filtration

Despite its extraordinary price, ceramic membrane can still be able to surpass polymeric membrane in the applications that require high temperature and pressure conditions, as well as harsh chemical environment. In order to alleviate the high cost of ceramic material that still becomes one of the major factors that contributes to the high production cost of ceramic membrane, various attempts have been made to use low cost ceramic materials as alternatives to well-known expensive ceramic materials such as alumina, silica, and zirconia in the fabrication of ceramic membrane. Thus, local Malaysian kaolin has been chosen as the ceramic material in this study for the preparation of kaolin hollow fibre membrane since it is inexpensive and naturally abundant in Malaysia. Due to the fact that the sintering process plays a prominent role in obtaining the desired morphology, properties, and performances of prepared ceramic membrane, the aim of this work was to study the effect of different sintering temperatures applied (ranging from 1200 to 1500 °C) in the preparation of kaolin hollow fibre membrane via dry/wet phase inversion-based spinning technique and sintering process. The morphology and properties of membrane were then characterised by SEM, AFM, FTIR, XRD, and three-point bending test, while the performances of membrane were investigated by conducting water permeation and Reactive Black 5 (RB5) dye rejection tests. From the experimental results obtained, the sintering temperature of 1400 °C could be selected as the optimum sintering temperature in preparing the kaolin hollow fibre membrane with the dense sponge-like structure of separation layer that resulted in the good mechanical strength of 70 MPa with the appreciable water permeation of 75 L/h m² bar and RB5 rejection of 68%.     

The possible role of the seaweed Ulva fasciata on ameliorating hyperthyroidism-associated heart inflammations in a rat model

Environmental Science and Pollution Research - Cardiovascular diseases are key complications primarily associated with hyperthyroidism disorders. The present study sought to ameliorate...     

The COVID-19 pandemic: prediction study based on machine learning models

Environmental Science and Pollution Research - COVID-19 was first discovered in Wuhan, China in December 2019. It is one of the worst pandemics in human history. Recent studies reported that...     

A GIS-based approach for geospatial modeling of groundwater vulnerability and pollution risk mapping in Bou-Areg and Gareb aquifers,northeastern Morocco

Environmental Science and Pollution Research - Groundwater resources are the main supply of freshwater for human activities. Nevertheless, during the last 50 years, groundwater has become very...     

Climate change adaptation through local knowledge in the north eastern region of Bangladesh

Climate change adaptation in the low laying developing countries is becoming crucial at the present time. However, the local knowledge regarding climate change adaptation is not well focused. This study evaluates climate related perception and identifying various adaptation strategies in the low lying areas of North-Eastern Bangladesh. Six focus group discussions and 120 households?? survey were carried out to identify the major climate events in our study areas which were temperature change, drought, heavy rainfall and cyclone and storm surges. Furthermore, main livelihood problems arising from these events were lack of fish availability, scarcity of water in drought seasons and frequent flood in the rainy seasons. Results also revealed that a little portion (10%) of the respondents had well knowledge about the present climate change. However, seasonal livelihood and hazard calendar demonstrated that local people were increasingly changing their livelihood status with changing climatic hazards. At that situation local people tried to adapt themselves with the changing climate through changing their own behavior and introducing some adaptation strategies. We recognized total 16 adaptive measures in the study areas within which crop diversification, floating garden, duck rearing, cage aquaculture, wave protection walls, re-digging of canal and construction of embankments were popular. The present study revealed that local experiences in the face of climate change adaptation have merits which need special consideration. Continuous research and more incentives required for proper documentation and relegate the local adaptation knowledge in the tropic.     

Projected changes in heat wave characteristics in the eastern Mediterranean and the Middle East

According to observed twentieth century temperature trends and twenty-first century climate model projections, the region that encompasses the eastern Mediterranean and the Middle East (EMME) is identified as a climate change hot spot. We extend previous studies by a comprehensive climatology of heat waves in the EMME based on regional climate model simulations for the recent past and the end of the twenty-first century. A percentile-based definition of heat waves is used to account for local climatic conditions. Spatial patterns of several heat wave properties are assessed and associated with atmospheric circulation regimes over specific locations. To cover a range of possible future climates, we use three SRES emission scenarios. According to our results, all indices that characterize heat wave severity will strongly increase compared with the control period of 1961–1990. The northern part of the EMME could be exposed to increased heat wave amplitudes by 6–10 °C, and the southern part may experience 2–3 months more combined hot days and tropical nights. Heat wave peak temperatures will be higher due to the overall mean warming as well as stronger summer anticyclonic conditions. The projected changes will affect human health and the environment in multiple ways and call for impact studies to support the development of adaptation strategies.