Copper fractionation with dissolved organic matter in natural waters and wastewater--a mixed micelle mediated methodology (cloud point extraction) employing flame atomic absorption spectrometry

A cloud point extraction-preconcentration methodology for the speciation analysis of free and organically complexed metal species in natural waters is presented. The method is based on the neutralization of the electrostatic charge of the humate-metal complexes with a positively charged surfactant in a high ionic strength solution environment. The resulting complexes are conveniently solubilized in the micelles of a non-ionic surfactant medium and are thus separated from the bulk aqueous phase. Free metal species are also determined by complexation with a conventional chelating agent under mild conditions. The overall procedure is easy, rapid and allows for a high sample throughput in terms of massive analysis of many samples in the same time period. The method offers substantially low detection limits of 8.5 and 0.9 micrograms l-1 for bound and labile species respectively, with a calibration curve rectilinear in the wide range 40-150 micrograms l-1 for the humate associated and 4-40 micrograms l-1 for the free metal species. The method is free from interferences yielding recoveries in the range 97-102% for various samples of different matrixes.     

Groundwater Modeling of a Complex Hydrologic System in South Carolina Through the Use of Analytic Elements

The objective of this study is to evaluate the use of the Analytical Element Method (AEM) toward multiobjective, multiscale, ongoing modeling needs at complex hydrologic sites such as those managed by the US Department of Energy. This method presents several advantages over the traditional numerical methods that include absence of grid, natural incorporation of hydrologic features, and generation of an exact solution at every point in a flow field. The AEM with its semi-analytical formulation is particularly efficient in addressing what-if scenarios, the resolution of boundary conditions, and the incorporation of new data all of which are important aspects of remediation efforts in complex sites. Our model accounted for important hydrologic features in an area of the Savannah River Site, South Carolina that included river branches, artificial surface basins, monitoring wells, and the existence of heterogeneities. Our simulated heads were found to be in excellent agreement with the measured heads, with over 90% of the wells exhibiting a maximum discrepancy of less than 10 ft. The AEM was found to be a very efficient and fast method for the analysis of a flow field even when a limited number of elements was considered. The AEM was seen to lead to better physical understanding and resolution of the critical components of a groundwater system and it can offer significant advantages in using models to guide site characterization and remediation efforts.     

Environmental risk and liability management and its influence on profitability

Managing environmental risk and liability for corporations and consultants requires a prudent combination of insurance techniques, company risk control plans, pollution prevention, and the proper allocation of retention funds. This article presents a review of current risk management techniques used to shield profits from limited and catastrophic loss scenarios. We recommend that corporations and consulting firms integrate insurance and risk management planning to mitigate environmental liabilities, navigate business risks, and safeguard corporate performance..© 1999 John Wiley & Sons, Inc.