Atmospheric BTEX concentrations in the vicinity of the crude oil refinery of the Baltic region

Among chemical industries, petroleum refineries have been identified as large emitters of a wide variety of pollutants. Benzene, toluene, ethylbenzene, and xylene (BTEX) form an important group of aromatic volatile organic compounds (VOCs) because of their role in the troposphere chemistry and the risk posed to human health. A very large crude oil refinery of the Baltic States (200,000 bbl/day) is situated in the northern, rural part of Lithuania, 10 km from the town of Ma?eikiai (Lithuania). The objectives of this study were: (1) to determine of atmospheric levels of BTEX in the region rural and urban parts at the vicinity of the crude oil refinery; and (2) to investigate the effect of meteorological parameters (wind speed, wind direction, temperature, pressure, humidity) on the concentrations measured. The averaged concentration of benzene varied from 2.12 ppbv in the rural areas to 2.75 ppbv in the urban areas where the traffic was determined to be a dominant source of BTEX emissions. Our study showed that concentration of benzene, as strictly regulated air pollutant by EU Directive 2008/50/EC, did not exceed the limit of 5 ppbv in the region in the vicinity of the crude oil refinery during the investigated period. No significant change in air quality in the vicinity of the oil refinery was discovered, however, an impact of the industry on the background air quality was detected. The T/B ratio (0.50-0.81) that was much lower than 2.0, identified other sources of pollution than traffic.     

A management system for end-of-life tyres: a Portuguese case study

The European Union introduced several policy instruments based in the extended producer responsibility (EPR) in order to improve the environmental performance of products and services through their life cycles. In this context, the Portuguese government decided to apply the EPR concept to tyres, and producers were obliged to constitute an end-of-life management system to promote the collection, recycling and reuse of end-of-life (EOL) tyres. This required producers, distributors, recyclers and retreaders to be identified and characterized, and local processing infrastructures to be analyzed. The information was used to design an economically optimised EOL tyre management system while promoting the activity of all EOL operators in order for the imposed collecting and recovery targets to be fulfilled. This paper discusses the interaction between the different governmental, private and academic institutions for the creation of the integrated management system for EOL tyres, the approach taken, the technical, political and legal aspects underneath them, as well as the environmental consequences induced by the creation of the management system. The results obtained during the first years of operation are reported and show an increase in the collection and recycling of EOL tyres and the consolidation of the collection and processing infrastructures.     

Traffic and catalytic converter - related atmospheric contamination in the metropolitan region of the city of Rio de Janeiro, Brazil

In this work, 24-h PM10 samples were collected in Rio de Janeiro, Brazil, and analysed for trace elements (Cd, Ce, Cu, La, Mo, Ni, Pb, Pd, Rh, Sb and Sn). The sampling was carried out at five locations (Bonsucesso; Centro, downtown city; Copacabana; Nova Igua?u and Sumaré) with different traffic densities and anthropogenic activities. An analytical method based on the EPA method for the determination of trace elements in airborne particulate matter (PM), using ultrasonic-assisted extraction and inductively coupled plasma mass spectrometry (ICP-MS) was applied. Our results suggest that vehicular traffic is the most important source of environmental pollution at the studied sites. The presence of Mo, Pd and Rh in the analysed filters reflects an additional source of pollution caused by the erosion and deterioration of automotive catalytic converters.     

Optical Resilience of the Paraíba do Sul River (Brazil) during a Toxic Spill of a Wood-Pulping Factory: The Cataguazes Accident

This study investigates the inherent optical properties (IOP) of a Brazilian river during a non-natural, anthropogenically mediated, toxic spill of a wood-pulping factory (the ‘Cataguazes accident’). The results indicated an outstanding transformation in the river water chromophoric dissolved organic matter (CDOM) pools. For instance, increases in CDOM absorption coefficients, a _CDOM (λ), which were averaged at specific spectral intervals, , ranged from 58-fold at the UV-B and UV-A ranges to 95-fold at the PAR range. As a result, the water color expressed as CDOM absorption at 440 nm, a _CDOM (440), varied from 4.16 to 365.03 m^-1. For S-coefficient, the variations ranged from ∼1.1 to 5.6-fold, respectively, at the 300–650 nm and UV-B range. The variability of S as a proxy of dissolved chromophores was thus clearly influenced by the spectral range used. Optical proportions were also investigated through the use of and S ratios at the UV-B, UV-A, and PAR ranges and, in the case of , also at the NIR range. This approach also showed clear variations between the water samples, likely reflecting changes in the composition of optically active substances in the river system. As a whole, the findings obtained here indicated that both the quantity and quality of the chromophoric material dissolved in the river water were greatly altered by the toxic spill. The changes in the optical properties of the river water, although extreme and likely with no parallel in the literature, were quite rapid as indicated by the optical resilience of the system. Overall, this study indicates that IOP might be thought, and possibly used, as a metric tool for monitoring the state of waters and aquatic ecosystems.     

A spatial-statistical approach for modeling the effect of non-point source pollution on different water quality parameters in the Velhas river watershed--Brazil

In this article, a methodology for evaluating the effect of land use/land cover on the quality of nearby stream water in a semiarid environment is described and tested on a large watershed in Southeastern Brazil. The approach aims at identifying the width of the riparian area having the strongest effect on different water quality parameters. The land use/land cover data were generated from remotely sensed data while water quality point data were supplied by a government agency. Testing was conducted for both the rainy and dry seasons in an effort to understand the direct effect of surface runoff. The approach combines cartographic modelling using a geographical information system (GIS) and statistics to establish the strength of the relationship between water quality, land use and the distance from the stream. Results suggest a strong relationship between land use/land cover and turbidity, nitrogen and fecal coliforms. They also suggest that each of these parameters has a unique behavior when distance from the stream is considered. Finally, although it was expected that the models would apply better during the wet season, some parameters had the opposite behavior and displayed a better fit during the dry season.     

Degradation and removal methods of antibiotics from aqueous matrices--a review

Over the past few years, antibiotics have been considered emerging pollutants due to their continuous input and persistence in the aquatic ecosystem even at low concentrations. They have been detected worldwide in environmental matrices, indicating their ineffective removal from water and wastewater using conventional treatment methods. To prevent this contamination, several processes to degrade/remove antibiotics have been studied. This review addresses the current state of knowledge concerning the input sources, occurrence and mainly the degradation and removal processes applied to a specific class of micropollutants, the antibiotics. In this paper, different remediation techniques were evaluated and compared, such as conventional techniques (biological processes, filtration, coagulation, flocculation and sedimentation), advanced oxidation processes (AOPs), adsorption, membrane processes and combined methods. In this study, it was found that ozonation, Fenton/photo-Fenton and semiconductor photocatalysis were the most tested methodologies. Combined processes seem to be the best solution for the treatment of effluents containing antibiotics, especially those using renewable energy and by-products materials.     

Herbicide toxicity,selectivity and hormesis of nicosulfuron on 10 Trichogrammatidae (Hymenoptera) species parasitizing Anagasta ( = Ephestia) kuehniella (Lepidoptera: Pyralidae) eggs

Selective agrochemicals including herbicides that do not affect non-target organisms such as natural enemies are important in the integrated pest management (IPM) programs. The aim of this study was to evaluate the herbicide toxicity, selectivity and hormesis of nicosulfuron, recommended for the corn Zea mays L. (Poaceae) crop, on 10 Trichogrammatidae (Hymenoptera) species. A female of each Trichogramma spp. or Trichogrammatoidea annulata De Santis, 1972 was individually placed in plastic test tubes (no choice) with a cardboard containing 45 flour moth Anagasta ( = Ephestia) kuehniella Zeller, 1879 (Lepidoptera: Pyralidae) eggs. Parasitism by these natural enemies was allowed for 48 h and the cardboards were sprayed with the herbicide nicosulfuron at 1.50 L.ha^?1, along with the control (only distilled water). Nicosulfuron reduced the emergence rate of Trichogramma bruni Nagaraja, 1983 females, but increased that of Trichogramma pretiosum Riley, 1879, Trichogramma acacioi Brun, Moraes and Smith, 1984 and T. annulata females. Conversely, this herbicide increased the emergence rate of Trichogramma brasiliensis Ashmead, 1904, T. bruni, Trichogramma galloi Zucchi, 1988 and Trichogramma soaresi Nagaraja, 1983 males and decreased those of T. acacioi, Trichogramma atopovilia Oatman and Platner, 1983 and T. pretiosum males. In addition, nicosulfuron reduced the sex ratio of T. galloi, Trichogramma bennetti Nagaraja and Nagarkatti, 1973 and T. pretiosum and increased that of T. acacioi, T. bruni, T. annulata, Trichogramma demoraesi Nagaraja, 1983, T. soaresi and T. brasiliensis. The herbicide nicosulfuron was “harmless” (class 1, <30% reduction) for females and the sex ratio of all Trichogrammatidae species based on the International Organization for Biological Control (IOBC) classification. The possible hormesis effect of nicosulfuron on Trichogrammatidae species and on the bacterium Wolbachia sp. (Rickettsiales: Rickettsiaceae) was also discussed.     

Study of new reinforcing materials for cementitious panel production

Environmental Science and Pollution Research - The development of building materials using new types of raw materials is currently on demand by society and the industry. It is intended to reduce...     

Alternative methods for the pilot-scale production and characterization of chitosan nanoparticles

Environmental Science and Pollution Research - This work describes the production/characterization of low molar mass chitosan nanoparticles derived from waste shrimp shells (SSC), as well as from a...