Economic assessment of flash co-pyrolysis of short rotation coppice and biopolymer waste streams

The disposal problem associated with phytoextraction of farmland polluted with heavy metals by means of willow requires a biomass conversion technique which meets both ecological and economical needs. Combustion and gasification of willow require special and costly flue gas treatment to avoid re-emission of the metals in the atmosphere, whereas flash pyrolysis mainly results in the production of (almost) metal free bio-oil with a relatively high water content. Flash co-pyrolysis of biomass and waste of biopolymers synergistically improves the characteristics of the pyrolysis process: e.g. reduction of the water content of the bio-oil, more bio-oil and less char production and an increase of the HHV of the oil. This research paper investigates the economic consequences of the synergistic effects of flash co-pyrolysis of 1:1 w/w ratio blends of willow and different biopolymer waste streams via cost-benefit analysis and Monte Carlo simulations taking into account uncertainties. In all cases economic opportunities of flash co-pyrolysis of biomass with biopolymer waste are improved compared to flash pyrolysis of pure willow. Of all the biopolymers under investigation, polyhydroxybutyrate (PHB) is the most promising, followed by Eastar, Biopearls, potato starch, polylactic acid (PLA), corn starch and Solanyl in order of decreasing profits. Taking into account uncertainties, flash co-pyrolysis is expected to be cheaper than composting biopolymer waste streams, except for corn starch. If uncertainty increases, composting also becomes more interesting than flash co-pyrolysis for waste of Solanyl. If the investment expenditure is 15% higher in practice than estimated, the preference for flash co-pyrolysis compared to composting biopolymer waste becomes less clear. Only when the system of green current certificates is dismissed, composting clearly is a much cheaper processing technique for disposing of biopolymer waste.     

环境危机管理经验研究

环境危机通常通过推动采用预防危机反复出现,并提高社会对危机事件迅速有效反应能力的措施,而成为改善环境管理的催化剂.回顾了美国、欧洲与日本的几个环境危机事例以及国家调整性政策的改变.总结出进行环境危机管理工作应该考虑:①紧急准备要求国家与地方权力机构应该通过仔细监测工业用有害化学品的使用情况、使用结果与运输情况,以及可能带来的环境影响,了解其潜在的环境灾难.要求从事可能会带来环境危机活动的责任方证明其已经制定了综合有效的应急反应计划.②排放有害物质的责任方要负责承担补救环境与人类健康损失所花费的全额成本.建立有效的责任计划可以推动对预防环境危机措施方面的投资.③发生环境危机时,采取的最基本措施是及时将有关危机性质与范围等情况通告应急反应权力机构及公众.以提高应急反应能力,保持公众的信任.④吸取经验预防环境危机事件再发生.独立调查委员会要探索发生环境事故的原因,并为预防工作提供意见或建议.⑤政府与行业有责任采取措施保护公众免受与有害物质排放和其他有害活动相关的潜在危害;在事故发生时能及时反应并使损害达到最低;对人类健康与环境造的成损害提供赔偿.     

国际环境执政理论研究进展透视

要想真正改善中国的环境条件,需要中国领导人和整个社会齐心合作,加强环境执政.在欧洲、日本和美国,环境执政手段正在发生变化.20世纪六七十年代起,国家政府开始积极致力于环境保护工作,是政策形成的初期阶段,而环境执政的主要特点是命令与控制的环境法规规范.这些法规一般技术性很强,关注特定污染物;虽然其过去在改善西方环境条件方面作出了重要贡献,人们还是日益认识到这种方式的局限性.因此,现在已开始采纳新的环境执政模式,其特点是多方利益相关者参与、决策过程更透明,重点从处理已发生的污染问题,向源头控制和更具预防性质的计划方式转变,也越来越重视以人类健康和生态系统的保护为目标的途径,而不再是简单减少某种污染物的排放水平.政府的成功取决于政府强化环境执政的种种步骤.     

The European Union and the Paris Climate Agreement: moving forward without the United States

<正>"Make our Planet Great Again!"These are the final words of the three-minute speech delivered in English by newly elected French President Emmanuel Macron(https://www.makeourplanetgreatagain.fr/home).The speech was made in response to US President Donald Trump's decision to take the United States out of the Paris Climate Agreement and to cut funding intended to support developing countries in adapting to climate     

Predicting applicants' job pursuit behavior from their selection expectations: the mediating role of the theory of planned behavior

Applicants' pretest expectations about the forthcoming selection procedure may serve as a key factor in applicants' decision‐making. The current study examined the validity of the theory of planned behavior (TPB) as an explanatory mechanism of the relationship between pretest selection expectations (warmth/respect, chance to demonstrate potential, difficulty of faking, unbiased assessment, feedback) and job pursuit behavior. Data were collected at two points in time, using a sample of applicants for the military. Selection expectations, job pursuit attitude, subjective norm, and controllability were significantly related to job pursuit intention. Job pursuit attitude mediated the relationship between selection expectations and job pursuit intention. Subjective norm and time lag were the only significant predictors of job pursuit behavior. Practical implications, strengths and limitations, as well as directions for further research are discussed. Copyright © 2008 John Wiley & Sons, Ltd.     

Application of the City Blueprint Approach to assess the challenges of water management and governance in Quito (Ecuador)

In this paper, we provide an assessment of the challenges of water, waste and climate change in the city of Quito by performing the City Blueprint Approach consisting of three assessment frameworks: (1) the Trends and Pressure Framework (TPF), (2) the City Blueprint Framework (CBF) and (3) the water Governance Capacity Framework (GCF). The TPF summarizes the main social, environmental and financial aspects that may affect urban water management. The CBF provides a clear overview of sustainable urban water management performance and its bottlenecks in municipalities and regions. The GCF comprises nine governance conditions which each consist of three indicators. The GCF provides insight in the most effective improvements to increase the governance capacity to address the identified urban water challenges. Our results show that poor wastewater treatment and long-term drinking water security are Quito’s main water challenges that may be jeopardized given the city’s rapid urbanization and economic pressure. The GCF analysis reveals that cooperation between stakeholders, implementing capacity and citizens’ awareness are the most important conditions for further development to find adequate solutions for Quito’s long-term drinking water security. We also suggest that more attention should be drawn to the transparency, accountability and participation principles. The results of Quito show that the City Blueprint Approach can serve as an affordable quick-scan to facilitate cities in their strategic planning to reach their sustainable development goals.     

Poly(3-hydroxybutyrate-co-3-hydroxyhexanoate)/Organomodified Montmorillonite Nanocomposites for Potential Food Packaging Applications

Poly(3-hydroxybutyrate-co-3-hydroxyhexanoate) (PHBHHx) is a versatile, biobased and biodegradable copolymer from the family of polyhydroxyalkanoates. This study aims to further ameliorate its properties in order to enhance its applicability for food packaging purposes through preparation of organomodified montmorillonite clay (OMMT) nanocomposites. Nanocomposites based on pure PHBHHx as well as commercial PHBHHx granulate, after a previous dry-mixing with OMMT in concentrations of 1, 3, 5 and 10 wt%, were prepared using melt blending and compression molding. Investigation of the samples showed well dispersed nanofiller and highly intercalated nanocomposites, resulting in a continuous decrease in gas permeability, lowering O₂, CO₂ and water vapor permeability with about 5–7 % and approximately 40 % at OMMT concentration of 1 and 10 wt%, respectively. Besides gas permeability, other properties were affected as well. Thermal stability of the samples increased gradually up to 5 wt% nanofiller, but was reduced at 10 wt%. In order to investigate the effects of OMMT and molecular weights on PHBHHx crystallization, nanocomposites were also produced by solvent-casting and compared to those obtained by melt-blending. Crystallization was retarded, because of severe lowering of molecular weight due to processing-induced chain scission, catalyzed by OMMT moisture. However, this reduction was counteracted for a large part by using commercial PHBHHx granulate, which has shown better crystallization properties. The samples were rendered increasingly more brittle, displaying higher Young’s modulus and severely reduced elongation at break. From this study it appeared that, upon viewing all affected properties as a whole, the sample based on commercial PHBHHx and containing 3 wt% OMMT shows most promise for possible applications, however further research must be performed in order to exploit their fullest potential.     

Bio‐Based Poly(3-hydroxybutyrate)/Thermoplastic Starch Composites as a Host Matrix for Biochar Fillers

Journal of Polymers and the Environment - Biochar is an excellent, but less-used candidate to serve as an alternative filler in poly(3-hydroxybutyrate) (PHB)-based composites. Increasing amounts of...