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采用以硫酸亚铁(FeSO4)为主要成分的复合脱水剂作为疏浚泥浆脱水剂(以下简称脱水剂),黄沙、炉渣、煤灰、石灰和粉煤灰分别作为疏浚底泥干化改良剂进行实验研究。结果表明,在脱水剂投加量为100 mg/L条件下,可以提高沉淀效率约20%;在投加脱水剂及5%石灰、粉煤灰、炉渣改良剂的条件下,底泥比阻值下降50%~70%;初期渗水速率提高6%~68%;与原泥相比,以黄沙、炉渣、煤灰为改良剂的底泥,经过4个月干化期后,承载力提高了30%~150%。本研究为疏浚底泥快速脱水干化提供了一种可行的技术途径。 相似文献
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铬渣的热解无害化处理 总被引:1,自引:0,他引:1
采用热解工艺无害化处理铬渣,探讨了稻秆在铬渣无害化处理中的作用.研究了热解温度、稻秆与铬渣质量比、铬渣粒径及保温时间对铬渣热解无害化处理的影响,并分析了热解前后热解产物中铬元素形态的变化.结果表明,热解工艺能有效地将铬渣中Cr(Ⅵ)还原,稻秆热解过程中产生的气相挥发分对Cr(Ⅵ)的还原起核心作用.较为适宜的热解条件:热解温度为400 ℃,稻秆与铬渣质量比为0.10,铬渣粒径<2 000 μm,保温时间为10 min.在该热解条件处理下,热解产物中的Cr(Ⅵ)质量浓度为121 mg/kg,低于热解前铬渣中的Cr(Ⅵ)(3 400 mg/kg).热解后,可交换态及碳酸盐结合态铬含量降低,大部分铬转化成了稳定的有机结合态和残渣态,极大地降低了铬渣的危害.第一作者:张大磊,男,1982生,博士研究生,研究方向为固体废弃物热处理. 相似文献
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Ma Yuhui Zheng Peiru Dai Wanqing Zheng Xiangyong He Shengbing Zhao Min 《Environmental science and pollution research international》2020,27(34):42571-42581
Environmental Science and Pollution Research - Constructed ditch wetland (CDW) is a combination of idle ditch and constructed wetland, which is typically used in rural areas to remove pollutants... 相似文献
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Variation of phytoplankton community before an induced cyanobacterial (Arthrospira platensis ) bloom
WANG Chong HUANG Yingying HE Shengbing LIN Yan WANG Xinze KONG Hainan 《环境科学学报(英文版)》2009,21(12):1632-1638
A cyanobacterial (Arthrospira platensis) bloom was induced in situ by nutrient manipulation in an enclosure. The succession of the
phytoplankton community and the water chemistry variations before the appearance of bloom, as well as their relationship, were
investigated. The cell pigment variations were studied simultaneously. The Pearson’s correlation analysis showed that there was
no significant correlation between water chemistry and green algal or cyanobacterial composition, indicating that water chemistry
variations were not suitable to be used as indicators for cyanobacterial-bloom early-warning. However, the diversity index of the
phytoplankton community decreased sharply before the bloom appeared. Therefore, the dynamics of phytoplankton community was
put forward to be an indicator for cyanobacterial-bloom early-warning. In addition, the cell pigment variations represented the changes
of community structure, which should be useful for studying the dynamics of phytoplankton community. 相似文献
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Use of zeolitized coal fly ash in the simultaneous removal of ammonium and phosphate from aqueous solution 总被引:1,自引:0,他引:1
Wu Deyi Hu Zhanbo Wang Xinze He Shengbing Kong Hainan 《Frontiers of Environmental Science & Engineering in China》2007,1(2):213-220
Discharge of wastewater containing nitrogen and phosphate can cause eutrophication. Therefore, the development of an efficient
material for the immobilization of the nutrients is important. In this study, a low calcium fly ash and high calcium fly ash
were converted into zeolite using the hydrothermal method. The removal of ammonium and phosphate that coexist in aqueous solution
by the synthesized zeolites were studied. The results showed that zeolitized fly ash could efficiently eliminate ammonium
and phosphate at the same time. Saturation of zeolite with Ca2+ rather than Na+ favored the removal of both ammonium and phosphate because the cation exchange reaction by the NH4
+ resulted in the release of Ca2+ into the solution and precipitation of Ca2+ with PO4
3− followed. An increase in the temperature elevated the immobilization of phosphate whereas it abated the removal of ammonium.
Nearly 60% removal efficiency for ammonium was achieved in the neutral pH range from 5.5 to 10.5, while the increase or decrease
in pH out of the neutral range lowered the adsorption. In contrast, the removal of phosphate approached 100% at a pH lower
than 5.0 or higher than 9.0, and less phosphate was immobilized at neutral pH. However, there was still a narrow pH range
from 9.0 to 10.5 favoring the removal of both ammonium and phosphate. It was concluded that the removal of ammonium was caused
by cation exchange; the contribution of NH3 volatilization to immobilization at alkaline conditions (up to pH level of 11.4) was limited. With respect to phosphate immobilization,
the mechanism was mainly the formation of precipitate as Ca3(PO4)2 within the basic pH range or as FePO4 and AlPO4 within acidic pH range. 相似文献
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固定相络合萃取剂处理水中苯酚的性能研究 总被引:12,自引:0,他引:12
采用固定相络合萃取剂 YH- 1对水中苯酚进行了萃取与反萃取实验研究 ,考察了组成比、废水 p H、起始浓度、流速及再生次数对 YH- 1萃取性能的影响。结果表明 ,当络合萃取剂与聚合物质量比为 2∶ 1,废水 p H<8时 ,通过单级或多级操作 YH- 1能有效地萃取高浓度含酚废水中的苯酚 ,且再生率达 99.3% ,明显优于活性炭。总之 ,固定相络合萃取剂 YH- 1是一种操作范围广、高效、易再生的处理含酚废水的新体系 相似文献
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The soluble microbial products (SMP) in the biological treatment effluent are generally of great amount and are poorly biodegradable. Focusing on the biodegradation of anaerobic SMP, the biological activated carbon (BAC) was introduced into the anaerobic system. The experiments were conducted in two identical lab-scale up-flow anaerobic sludge blanket (UASB) reactors. The high strength organics were degraded in the first UASB reactor (UASB1) and the second UASB (UASB2, i.e., BAC) functioned as a polishing step to remove SMP produced in UASB1. The results showed that 90% of the SMP could be removed before granular activated carbon was saturated. After the saturation, the SMP removal decreased to 60% on the average. Analysis of granular activated carbon adsorption revealed that the main role of SMP removal in BAC reactor was biodegradation. A strain of SMP-degrading bacteria, which was found highly similar to Klebsiella sp., was isolated, enriched and inoculated back to the BAC reactor. When the influent chemical oxygen demand (COD) was 10,000 mg/L and the organic loading rate achieved 10 kg COD/(m 3 ·day), the effluent from the BAC reactor could meet the discharge standard without further treatment. Anaerobic BAC reactor inoculated with the isolated Klebsiella was proved to be an effective, cheap and easy technical treatment approach for the removal of SMP in the treatment of easily-degradable wastewater with COD lower than 10,000 mg/L. 相似文献
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Wang Chao Yang Haoyuan Yang Can Liu Yihui Bai Liuyang Yang Shengbing 《Journal of Material Cycles and Waste Management》2023,25(4):2077-2086
Journal of Material Cycles and Waste Management - In this study, deep eutectic solvent synthesized by choline chloride (C5H14CINO) and oxalic acid dihydrate (C2H2O4·2H2O) was used to recycling... 相似文献
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Deyi Wu Zhanbo Hu Xinze Wang Shengbing He Hainan Kong 《Frontiers of Environmental Science & Engineering》2007,1(2):213-220
Discharge of wastewater containing nitrogen and phosphate can cause eutrophication. Therefore, the development of an efficient material for the immobilization of the nutrients is important. In this study, a low calcium fly ash and high calcium fly ash were converted into zeolite using the hydrothermal method. The removal of ammonium and phosphate that coexist in aqueous solution by the synthesized zeolites were studied. The results showed that zeolitized fly ash could efficiently eliminate ammonium and phosphate at the same time. Saturation of zeolite with Ca2+ rather than Na+ favored the removal of both ammonium and phosphate because the cation exchange reaction by the NH4 + resulted in the release of Ca2+ into the solution and precipitation of Ca2+ with PO4 3? followed. An increase in the temperature elevated the immobilization of phosphate whereas it abated the removal of ammonium. Nearly 60% removal efficiency for ammonium was achieved in the neutral pH range from 5.5 to 10.5, while the increase or decrease in pH out of the neutral range lowered the adsorption. In contrast, the removal of phosphate approached 100% at a pH lower than 5.0 or higher than 9.0, and less phosphate was immobilized at neutral pH. However, there was still a narrow pH range from 9.0 to 10.5 favoring the removal of both ammonium and phosphate. It was concluded that the removal of ammonium was caused by cation exchange; the contribution of NH3 volatilization to immobilization at alkaline conditions (up to pH level of 11.4) was limited. With respect to phosphate immobilization, the mechanism was mainly the formation of precipitate as Ca3(PO4)2 within the basic pH range or as FePO4 and AlPO4 within acidic pH range. 相似文献
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