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1.
Identification of reactive oxygen species (ROS) that contribute to bisphenol-A (BPA) degradation and monitoring of BPA at various concentrations in human serum under Fenton reaction conditions were carried out using electron spin resonance (ESR) spectrophotometry and high performance liquid chromatography with electrochemical detection (HPLC-ECD). BPA recovery decreased with increasing Fe concentration and time, both with a Fenton reaction using Fe(II), and with a Fenton-like reaction using Fe(III). In these reactions, BPA dose-dependently decreased the intensity of 5,5-dimethyl-1-pyrroline-N-oxide (DMPO)-*OH, up to 1 microg/ml BPA, and no change in DMPO-O(2)(?-) intensity was observed. The decrease in BPA recovery was inhibited strongly by addition of serum under Fenton-like reaction conditions, and there was a negative correlation between turbidity and BPA recovery. To clarify the mechanism by which serum inhibits BPA degradation, the relationship between BPA recovery and sample turbidity, and characteristics of the precipitates were investigated using spectrophotometry and X-ray analysis. The precipitate formed in the serum-containing sample consisted of C, S, O, P and Fe. BPA degradation was also inhibited under Fenton-like reaction conditions in phosphate buffered saline (PBS), and a precipitate consisting of O, P, and Fe appeared. Precipitates also appeared in authentic albumin and gamma-globulin when sulfate was added with Fenton reagents. After precipitate removal, both Fe and protein concentrations in the supernatant of the protein solutions with sulfate decreased with increasing Fe addition. We demonstrate here that hydroxyl radical generation from Fenton or Fenton-like reactions can degrade BPA, and that serum strongly inhibits BPA degradation, not only by competing with BPA for hydroxyl radicals, but also by trapping Fe with oxidative components present in the serum. 相似文献
2.
To elucidate the life history of neustonic animals, growth and reproductive patterns were investigated in the hermaphroditic
pedunculate barnacle Lepas anserifera in field and laboratory experiments in Wakayama, western Japan from 2006 to 2008. The effects of temperature (19, 24 or 29°C)
and food availability (once or twice a week) on growth and reproduction were also studied in the laboratory. The barnacles
grew and matured rapidly, especially in the field: individuals on the average grew from 3 mm to more than 12 mm in capitulum
length within 15 days and some were brooding. High temperature and high food availability resulted in greater growth. High
temperature also resulted in earlier maturation of both testes and ovaries, whereas the effect of food availability was less
clear. The rapid growth and maturation, together with earlier maturation at higher temperatures, may be an adaptation to ephemeral
floating objects to which they attach. 相似文献
3.
Kosuke Toshiki Pham Quy Giang Kevin Roy B.Serrona Takahiro Sekikawa Jeoung-soo Yu Baasandash Choijil Shoichi Kunikane 《环境科学学报(英文版)》2015,28(2):178-186
Currently, most developing countries have not set up municipal solid waste management systems with a view of recovering energy from waste or reducing greenhouse gas emissions. In this article, we have studied the possible effects of introducing three energy recovery processes either as a single or combination approach, refuse derived fuel production,incineration and waste power generation, and methane gas recovery from landfill and power generation in Ulaanbaatar, Mongolia, as a case study. We concluded that incineration process is the most suitable as first introduction of energy recovery. To operate it efficiently,3Rs strategies need to be promoted. And then, RDF production which is made of waste papers and plastics in high level of sorting may be considered as the second step of energy recovery.However, safety control and marketability of RDF will be required at that moment. 相似文献
4.
Kosuke Toshiki Pham Quy Giang Kevin Roy B. Serrona Takahiro Sekikawa Jeoung-soo Yu Baasandash Choijil Shoichi Kunikane 《环境科学学报(英文版)》2015
Currently, most developing countries have not set up municipal solid waste management systems with a view of recovering energy from waste or reducing greenhouse gas emissions. In this article, we have studied the possible effects of introducing three energy recovery processes either as a single or combination approach, refuse derived fuel production, incineration and waste power generation, and methane gas recovery from landfill and power generation in Ulaanbaatar, Mongolia, as a case study. We concluded that incineration process is the most suitable as first introduction of energy recovery. To operate it efficiently, 3Rs strategies need to be promoted. And then, RDF production which is made of waste papers and plastics in high level of sorting may be considered as the second step of energy recovery. However, safety control and marketability of RDF will be required at that moment. 相似文献
5.
Yoshiro Ono Hidehito Uemura Yoshinori Kanjo Osami Kawara Toshiki Ayano 《Journal of Material Cycles and Waste Management》2000,2(1):38-42
Construction waste such as road pavement and concrete is estimated to constitute about 50% of the total industrial waste in
Japan, and the recycling of such material has recently become a prominent topic among construction engineers. It has also
been suggested that various types of industrial waste be utilized as components of construction materials. This paper investigates
the environmental safety of certain materials in terms of the elutions and genotoxicities of these substances. The substances
extracted from some materials, such as emulsifier, ash, and sediment, were found to have genotoxic characteristics. The dose-related
responses of the various materials and their genotoxic strengths are shown.
Received: June 16, 1998 / Accepted: September 7, 1999 相似文献
6.
So Kazama Toshiki Aizawa Toru Watanabe Priyantha Ranjan Luminda Gunawardhana Ayako Amano 《Sustainability Science》2012,7(1):45-54
Flooding and inundation are annual events that occur during the rainy season in Cambodia, and inundation has a strong relationship
with human health. This study simulated the coliform bacteria distribution using a hydraulic model and estimated the impact
of inundation on public health using a dose–response model. The model parameters were calibrated using field survey data from
Cambodia and obtained good agreement with the coliform group count distribution. The results suggest that the impact of inundation
on human health is most noticeable in residential areas. The annual average risk of infection during medium-sized flood events
is 0.21. The risk due to groundwater use ranges from 0.12 to 0.17 in inundation areas and reaches as high as 0.23 outside
the inundation areas. The risk attributed to groundwater use is therefore higher than that for surface water use (0.02–0.06),
except in densely populated areas at the city center. There is a high risk for infection with waterborne disease in residential
areas, and the annual average risk during small flood events is 0.94. An assessment of possible countermeasures to reduce
the risk shows that the control of inundation may bring more risk to public health in Cambodia. Shallower inundation water
(<0.3 m) leads to a higher risk of infection, but if the depth is greater than 2 m, the risk is low in residential areas.
The simulated results explain the spatial distributions of infection risk,, which are vitally important for determining the
highest priority places with relatively high risk and will be helpful for decision makers when considering the implementation
of countermeasures. 相似文献
7.
Yusaku?SakataEmail author Thallada?Bhaskar Md. Azhar?Uddin Akinori?Muto Toshiki?Matsui 《Journal of Material Cycles and Waste Management》2003,5(2):113-124
Dehalogenation is a key technology in the feedstock recycling of mixed halogenated waste plastics. In this study, two different methods were used to clarify the effectiveness of our proposed catalytic dehalogenation process using various carbon composites of iron oxides and calcium carbonate as the catalyst/sorbent. The first approach (a two-step process) was to develop a process for the thermal degradation of mixed halogenated waste plastics, and also develop dehalogenation catalysts for the catalytic dehydrochlorination of organic chlorine compounds from mixed plastic-derived oil containing polyvinyl chloride (PVC) using a fixed-bed flow-type reactor. The second approach (a single-step process) was the simultaneous degradation and dehalogenation of chlorinated (PVC) and brominated (plastic containing brominated flame retardant, HIPS–Br) mixed plastics into halogen-free liquid products. We report on a catalytic dehalogenation process for the chlorinated and brominated organic compounds formed by the pyrolysis of PVC and brominated flame retardant (HIPS–Br) mixed waste plastics [(polyethylene (PE), polypropylene (PP), and polystyrene (PS)], and also other plastics. During dehydrohalogenation, the iron- and calcium-based catalysts were transformed into their corresponding halides, which are also very active in the dehydrohalogenation of organic halogenated compounds. The halogen-free plastic-derived oil (PDO) can be used as a fuel oil or feedstock in refineries. 相似文献
8.
Chris Fook Sheng Ng Kayo Ueda Hiroshi Nitta Ayano Takeuchi 《Environmental monitoring and assessment》2013,185(10):8767-8776
We conducted a multicity time-series study using monitoring data to assess seasonal patterns of short-term ozone–mortality association among elderly aged 65 years and over in Japan. Daily exposure to ambient ozone was computed using hourly measurements of photochemical oxidants available at multiple monitoring stations in each city. Effects of ozone on daily all-cause non-accidental, cardiovascular, and respiratory mortality were estimated using distributed lag linear models, controlling for confounding by temporal, day of the week, temperature, and flu epidemics. City-level effect estimates were combined using inverse variance meta-analysis. In spring and autumn, a 10-ppbv increase of daily maximum 8-h average ozone concentration in the previous 3 days was associated with 0.69 % (95 % confidence interval (CI): 0.27–1.10), 1.07 % (0.34–1.82), and 1.77 % (0.78–2.77) increases in daily all-cause, cardiovascular, and respiratory mortality, respectively. Forward displacement of respiratory mortality was large during the cold season despite lower ozone concentration. Results were generally independent of fine particulate matter and nitrogen dioxide. Findings suggest significant mortality effects of short-term ozone exposure among the elderly during the moderate season. Those with underlying respiratory diseases were susceptible, even during winter. 相似文献
9.
Kosuke Toshiki Pham Quy Giang Kevin Roy B. Serron Takahiro Sekikaw Jeoung-soo Yu Baasandash Choijil Shoichi Kunikane 《环境科学学报(英文版)》2015
Currently, most developing countries have not set up municipal solid waste management systemswith a viewof recovering energy fromwaste or reducing greenhouse gasemissions. In this article, we have studied the possible effects of introducing three energy recovery processes either as a single or combination approach, refuse derived fuel production, incineration and waste power generation, and methane gas recovery from landfill and power generation in Ulaanbaatar, Mongolia, as a case study. We concluded that incineration process is the most suitable as first introduction of energy recovery. To operate it efficiently, 3Rs strategies need to be promoted. And then, RDF production which is made of waste papers and plastics in high level of sortingmay be considered as the second step of energy recovery. However, safety control and marketability of RDF will be required at that moment. 相似文献
10.
Tomoyuki Imai Toshiki Matsui Yasuhiko Fujii Tasuku Nakai Suminori Tanaka 《Journal of Material Cycles and Waste Management》2001,3(2):103-109
A new iron oxide catalyst, which has a superior oxidation activity in carbon monoxide and polyethylene (PE) combustion, was
synthesized by an aqueous solution reaction. Catalytic oxidation of carbon monoxide over six kinds of hematite obtained from
the goethite was done using a microcatalytic pulse reactor, and the composition of the hematite with the highest oxidation
activity was determined. With the aim of suppressing dioxin formation on combustion, incineration tests of solid wastes in
PE refuse bags with and without the goethite were carried out using a commercial semibatch-type incinerator with a combustion
chamber of 6.2 m3. The result confirmed that the concentration of dioxins in the flue gas decreased considerably when the refuse was incinerated
in PE bags manufactured with goethite.
Received: July 24, 2000 / Accepted: October 18, 2000 相似文献