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Yanan Bai Xiuning Wang Fang Zhang Raymond Jianxiong Zeng 《Frontiers of Environmental Science & Engineering》2022,16(3):34
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介绍可编程序控制器(PC)的由来,发展,特点及其在环境工程自动控制系统中的应用前景与应用实例。 相似文献
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Xiuning Hua Wei Wang Yue Hu Jie Zhu 《Journal of Material Cycles and Waste Management》2014,16(4):583-590
Traditional combustion of syngas derived from biomass has incurred numerous environmental problems, and syngas chemical looping combustion is environmentally friendly for syngas energy conversion. As a key part of chemical looping combustion, reactor configuration is noticeable. The dynamically operated packed bed reactor is an emerging conception applied to chemical looping combustion. Our attention is paid to the conversion of the oxygen carrier in the packed bed as the limited maximum conversion of the oxygen carrier in a packed bed is unclear. In this paper, the reaction front distribution during iron oxide reduced by CO is firstly proposed on the basis of chemical equilibrium and then validated by the effluent gas profile. Based on the reaction front distribution, the detail of the reduction stage in iron-based chemical looping combustion is analyzed to obtain the characteristics of reaction fronts. The reaction rates of reduction from Fe2O3 to Fe3O4, Fe3O4 to Fe0.947O and Fe0.947O to Fe are 5.280, 3.329 and 4.379 mol m?3 s?1, respectively. And the velocities of reaction front I, II, III are 0.605, 0.326, 0.044 cm min?1, respectively, which demonstrate the reaction front distribution. The methodology established in this paper can be used to study multiple reaction front system in the packed bed reactor. 相似文献
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Xiuning HUA Wei WANG Feng WANG 《Frontiers of Environmental Science & Engineering》2015,9(6):1130-1138
Chemical looping combustion is a promising technology for energy conversion due to its low-carbon, high-efficiency, and environmental-friendly feature. A vital issue for CLC process is the development of oxygen carrier, since it must have sufficient reactivity. The mechanism and kinetics of CO reduction on iron-based oxygen carriers namely pure Fe2O3 and Fe2O3 supported by alumina (Fe2O3/Al2O3) were investigated using thermo-gravimetric analysis. Fe2O3/Al2O3 showed better reactivity over bare Fe2O3 toward CO reduction. This was well supported by the observed higher rate constant for Fe2O3/Al2O3 over pure Fe2O3 with respective activation energy of 41.1±2.0 and 33.3±0.8 kJ·mol−1. The proposed models were compared via statistical approach comprising Akaike information criterion with correction coupled with F-test. The phase-boundary reaction and diffusion control models approximated to 95% confidence level along with scanning electron microscopy results; revealed the promising reduction reactions of pure Fe2O3 and Fe2O3/Al2O3. The boosting recital of iron-based oxygen carrier support toward efficient chemical looping combustion could be explained accurately through the present study. 相似文献
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Dioxin production is a worldwide concern because of its persistence and carcinogenic, teratogenic, and mutagenic effects. The pyrolysis-chemical looping combustion process of disposing solid waste is an alternative to traditional solid waste incineration developed to reduce the dioxin production. Based on the equilibrium composition of the Deacon reaction, pyrolysis gas oxidized by seven common oxygen carriers, namely, CuO, NiO, CaSO4, CoO, Fe2O3, Mn3O4, and FeTiO3, is studied and compared with the pyrolysis gas directly combusted by air. The result shows that the activity of the Deacon reaction for oxygen carriers is lower than that for air. For four typical oxygen carriers (CuO, NiO, Fe2O3, and FeTiO3), the influences of temperature, pressure, gas composition, and tar on the Deacon reaction are discussed in detail. According to these simulation results, the dioxin production in China, Europe, the United States, and Japan is predicted for solid waste disposal by the pyrolysis-chemical looping combustion process. Thermodynamic analysis results in this paper show that chemical looping combustion can reduce dioxin production in the disposal of solid waste. 相似文献
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Zhu Jie Wang Wei Lian Songjian Hua Xiuning Xia Zhou 《Journal of Material Cycles and Waste Management》2017,19(1):453-462
Journal of Material Cycles and Waste Management - Chemical looping hydrogen generation using iron oxides as oxygen carriers is a novel technology to convert carbonaceous substances into hydrogen.... 相似文献
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Dioxin production is a worldwide concern because of its persistence and carcinogenic, teratogenic, and mutagenic effects. The pyrolysis-chemical looping combustion process of disposing solid waste is an alternative to traditional solid waste incineration developed to reduce the dioxin production. Based on the equilibrium composition of the Deacon reaction, pyrolysis gas oxidized by seven common oxygen carriers, namely, CuO, NiO, CaSO4, CoO, Fe2O3, Mn3O4, and FeTiO3, is studied and compared with the pyrolysis gas directly combusted by air. The result shows that the activity of the Deacon reaction for oxygen carriers is lower than that for air. For four typical oxygen carriers (CuO, NiO, Fe2O3, and FeTiO3), the influences of temperature, pressure, gas composition, and tar on the Deacon reaction are discussed in detail. According to these simulation results, the dioxin production in China, Europe, the United States, and Japan is predicted for solid waste disposal by the pyrolysis-chemical looping combustion process. Thermodynamic analysis results in this paper show that chemical looping combustion can reduce dioxin production in the disposal of solid waste. 相似文献
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