Factors affecting EDTA extraction of lead from lead-contaminated soils

The effects of solution:soil ratio, major cations present in soils, and the ethylenediaminetetraacetic acid (EDTA):lead stoichiometric ratio on the extraction of lead using EDTA were studied for three different Superfund site soils, one rifle range soil, and one artificially lead-contaminated soil. Extraction of lead from the lead-contaminated soils was not affected by a solution:soil ratio as low as 3:1 but instead was dependent on the quantity of EDTA present. Results of the experiments showed that the extraction efficiencies were different for each soil. If sufficiently large amount of EDTA was applied (EDTA-Pb stoichiometric ratio greater than 10), most of the lead were extracted for all soils tested except for a Superfund site soil from a lead mining area. The differences in extraction efficiencies may be due to the major cations present in soils which may compete with lead for active sites on EDTA. For example, iron ions most probably competed strongly with lead for EDTA ligand sites for pH less than 6. In addition, copper and zinc may potentially compete with lead for EDTA ligand sites. Experimental results showed that addition of EDTA to the soil resulted in a very large increase in metals solubility. The total molar concentrations of major cations extracted were as much as 20 times the added molar concentration of EDTA. For some of the soils tested, lead may have been occluded in the iron oxides present in the soil which may affect lead extraction. While major cations present in the soil may be one of the factors affecting lead extraction efficiency, the type of lead species present also play a role.     

An assessment of the recycling potential of materials basedon environmental and economic factors; case study in South Korea

As the generation of waste home appliances increases continuously with economic growth, the importance of recycling becomes more apparent. Many home appliances we use today are recyclable, and recyclable materials from the waste home appliances can be used to create new or refurbishing products. To do that, first of all, we have to know and consider the recyclable materials' recycling potential with environmental and economic information. In this study, an evaluation method to assess recycling potential considering both the environmental and economic factors was suggested for the materials recovered from waste home appliances. Life cycle assessment (LCA) method was applied to obtain the environmental score (S_Env) and an actual value and a static economic model was used to obtain the economic score (S_Eco). The recycling potential for recyclable materials was calculated by using the S_Env and S_Eco along with weighting factors derived from an analytical hierarchy process (AHP) method. With the calculated data and evaluation method for the recycling materials, this study could provide useful information for decision makers and product designers in the design for environment (DfE).     

Ammonia flow analysis in the domestic fertilizer industry of South Korea

Journal of Material Cycles and Waste Management - In this study, an ammonia flow analysis that presents how ammonia is used or handled in the South Korean fertilizer industry is developed using...     

An Estimation of Construction and Demolition Debris in Seoul,Korea: Waste Amount,Type, and Estimating Model

ABSTRACT

Construction and demolition (C&D) debris is generated at the site of various construction activities. However, the amount of the debris is usually so large that it is necessary to estimate the amount of C&D debris as accurately as possible for effective waste management and control in urban areas. In this paper, an effective estimation method using a statistical model was proposed. The estimation process was composed of five steps: estimation of the life span of buildings; estimation of the floor area of buildings to be constructed and demolished; calculation of individual intensity units of C&D debris; and estimation of the future C&D debris production. This method was also applied in the city of Seoul as an actual case, and the estimated amount of C&D debris in Seoul in 2021 was approximately 24 million tons. Of this total amount, 98% was generated by demolition, and the main components of debris were concrete and brick.