南京和北京气溶胶光学厚度与PM2.5质量浓度关系对比分析

利用南京与北京地区2014年5月1日—2019年10月31日的PM_2.5监测数据、气溶胶光学厚度观测资料以及同期MICAPS地面气象要素的观测资料,对两地PM_2.5浓度的变化规律及其与气溶胶光学厚度、气象要素的关系进行了分析和讨论,结果表明：南京与北京均呈现PM_2.5浓度冬季显著高于夏季,AOD冬季小于夏季的特征;对比而言,北京PM_2.5月均浓度高于南京地区;南京与北京的PM_2.5浓度与AOD均为正相关关系,PM_2.5浓度与AOD间相关性存在显著的季节差异,主要表现为夏季相关性大于冬季相关性;两地AOD与PM_2.5浓度均为正相关关系,在同一AOD水平下,相对湿度越大,PM_2.5浓度越大,气溶胶吸湿增长易造成污染物积累;南京PM_2.5浓度与能见度的r为0.57,而北京的r为0.83,两地的PM_2.5浓度与能见度的冬季相关性较夏季好,在高相对湿度下,同一PM_2.5浓度水平时,南京能见度较北京好.     

Effects of aeration frequency on leachate quality and waste in simulated hybrid bioreactor landfills

Research has been conducted to investigate the effects of daily aeration frequency on leachate quality and waste settlement in simulated hybrid landfill bioreactors. Four laboratory-scale reactors were constructed and operated for about 10 months to simulate different bioreactor operations, including one anaerobic bioreactor and three hybrid bioreactors with different aeration frequencies (one, two, and four times per day). Chemical oxygen demand (COD) and biochemical oxygen demand (BOD₅) reduced more than 96% of the initial concentrations in all aerated bioreactors. The differences of COD and BOD₅ reductions among tested aeration frequencies were relatively small. For ammonia nitrogen, the higher aeration frequency (two or four times per day) resulted in the quicker reduction. Overall, the concentrations of heavy metals (Cr, Co, Cu, Mn, Ni, and Zn) decreased over time except Cd and Pb. The reduction of redox-sensitive metal concentrations (Mn, Co, Ni, and Cu) was greater in aerated bioreactors than in anaerobic bioreactor. Settlement of municipal solid waste (MSW) was enhanced with higher frequency of aeration events (four times per day).

Implications: In recent years, hybird bioreactor landfill technology has gained a lot of attention. Appropriate aeration rate is crucial for hybrid bioreactor operation, but few studies have been done and different results were obtained. Research was conducted to investigate the effects of daily aeration frequency on leachate quality and waste settlement. Results indicated that aeration can effectively accelerate waste stabilization and remove organic carbon concentration and total nitrogen in the leachate.     

不同好氧预处理方式对餐厨垃圾产甲烷的影响

为了研究不同好氧预处理方式对餐厨垃圾厌氧消化产甲烷的影响,通过建立3个模拟厌氧生物反应器,研究了传统厌氧生物反应器C1、上层好氧预处理-厌氧生物反应器C2和底部好氧预处理-厌氧生物反应器C3 3种不同操作条件下的产甲烷过程.结果表明,挥发性有机酸的累积使C1始终处于产甲烷滞后阶段;而C2、C3的好氧预处理通过加快易水解酸化组分和过量挥发性有机酸的好氧降解,有效缓解了酸性抑制,产甲烷滞后时间明显缩短至10 d内.第32天C2停止上层曝气后,在27 d内甲烷浓度达到了50％以上,同时,产甲烷速率迅速上升,并在第81天可达到峰值773 mL/(kg·d).C3在第11天停止底部曝气后,虽然经过22 d的时间甲烷浓度即上升至50％,但之后产甲烷速率经历回落阶段后再次逐渐上升,在实验结束时仅达到517 mL/(kg·d).上层曝气的好氧预处理方式所需曝气时间相对较长,但其产甲烷启动快,与底部曝气相比,其后期的甲烷化过程更稳定并可达到较高的产甲烷速率.     

路面径流生态阻控技术研究——以改性麦饭石透水沥青路面为例

为强化透水沥青路面对路面径流中氮、磷的控制效果,采用铁盐联合碱热技术制备了涂层负载改性麦饭石蓄水层集料,并运用场发射扫描电子显微镜(SEM)、能谱分析仪(EDS)和X射线衍射(XRD)等手段对改性后麦饭石集料的表面形态、特征和化学成分进行了表征.同时,通过静态吸附试验对TP的吸附效果及其作用机理进行了对比研究.最后将改性麦饭石作为蓄水层集料应用于透水沥青路面中,通过模拟降雨和周期蓄水试验探究其净化机制.结果表明:相比于天然麦饭石,铁盐联合碱改性麦饭石的表面性状发生了明显变化,最大饱和吸附容量明显提高,对氨氮和磷酸盐的吸附容量分别从1.32 mg·g~(-1)和1.48 mg·g~(-1)提升到12.82 mg·g~(-1)和6.38 mg·g~(-1);降雨全过程中改性蓄水层路面对NH~+_4-N的整体去除效率可提高20%左右,对TP的净化效率至少可提高15%,蓄水阶段较模拟降雨阶段污染物的去除效果显著提高,改性后麦饭石蓄水层24 h后的出水水质均可达III类水标准,强化蓄水层和提高蓄水时间是提高路面径流净化效率的有效措施.因此,本实验中铁盐联合碱热技术制备的改性麦饭石可推荐用于海绵城市生态处理设施透水沥青路面中削减氨氮和总磷的污染负荷.     

植被根系及其土壤理化特征在高寒小嵩草草甸退化演替过程中的变化

以野外样地调查和室内分析法研究了不同退化演替阶段高寒小嵩草草甸的植被根系空间变化和土壤环境因子间的关系。结果表明,不同退化演替阶段高寒小嵩草草甸群落植被根系和蕴育植被根系的土壤量发生了明显的变化。特别是0~10 cm土层的植被根系在重度退化阶段显著高于其它退化演替阶段（P〈0.05）,而蕴育植被根系的＂载体＂量在重度退化阶段显著低于其它退化演替阶段（P〈0.05）,根土比（根和土的重量比）明显高于其它退化演替阶段（P〈0.05）;随着退化演替阶段的进行,高寒小嵩草草甸群落物种数、地上部分、植被根系锐减,群落结构和功能明显发生变化;不同退化演替阶段,植被根系（0~40 cm）的垂直分布、根土比与土壤容重、土壤含水量以及土壤中N、P含量存在一定的相关性;不同退化演替阶段高寒小嵩草草甸土壤理化特性的变化影响草地群落地上部分和植被根系;土壤的稳定性是草地生产稳定和恢复的重要因素,在评价与改良退化草地时,要充分了解土壤的退化程度。在高寒草甸地下根系取样方法难以统一,而且土壤表层根系和土壤很难难以分离,加之根系采样破坏性大、工作量大,根土比可能是指示高寒草甸退化程度相对可靠的量化指标。     

Application of FeIII-TAML/H2O2 system for treatment of fluoroquinolone antibiotics

Over the recent past, fluoroquinolone antibiotics (FQs) have raised extensive attention due to their potential to induce the formation of resistance genes and “superbugs”, thus various advanced oxidation techniques have been developed to eliminate their release into the environment. In the present study, the prototype tetraamido macrocyclic ligand (Fe^III-TAML)/hydrogen peroxide (H₂O₂) system is employed to degrade FQs (i.e., norfloxacin and ciprofloxacin) over a wide pH range (i.e., pH 6-10), and the reaction rate increases with the increase in pH level. The effect of dosage of Fe^III-TAML and H₂O₂ on the degradation of FQs is evaluated, and the reaction rate is linearly correlated with the added amount of chemicals. Moreover, the impact of natural organic matters (NOM) on the removal of FQs is investigated, and the degradation kinetics show that both NOM type and experimental concentration exhibit negligible influence on the oxidative degradation of selected antibiotics. Based on the results of liquid chromatography-high resolution mass spectrometry and theoretical calculations, the reaction sites and pathways of FQs by Fe^III-TAML/H₂O₂ system are further predicted and elucidated.     

A Highly Efficient Adsorbent Based on Starch-Graphene Oxide Architecture for Scavenging Aqueous Pb(II): Isotherms,Kinetics, Thermodynamics and Interaction Mechanism

Journal of Polymers and the Environment - Heavy metal pollution stems from the modern industry is a severe environmental problem. In this work, a highly efficient adsorbent based on starch-graphene...     

环渤海地区空气质量时空变化特征及动态预测

基于环渤海地区2017—2021年各城市空气质量指数(AQI)、污染物浓度与社会经济数据,利用数理统计、克里金插值法对环渤海地区AQI与污染物浓度的时空变化特征进行分析,运用皮尔逊相关性分析方法探讨AQI与污染物浓度、社会经济因素的相关关系,采用时间序列预测模型对2022年6月—2023年12月空气质量及污染物浓度进行预测。结果表明:环渤海地区AQI及污染物浓度大致呈逐年降低的趋势。AQI的逐月变化呈"W"形,O₃浓度的年内变化呈倒"V"形,其余污染物则呈现与O₃相反的变化趋势。AQI大致呈现西南高、东北低的空间分布特点,而污染物浓度分布具有明显的空间差异。环渤海地区5个代表性城市的AQI类别以良好为主,冬季首要污染物主要为PM_2.5、PM₁₀,夏季首要污染物以O₃为主。人口数量是影响AQI的主要因素,城市园林绿地面积对AQI具有一定影响。预测结果显示,未来环渤海地区AQI、主要污染物浓度(O₃除外)均呈现出随时间的推移逐渐下降的变化趋势。     

模拟生物反应器加速产甲烷过程研究

渗滤液原液回灌易导致填埋垃圾产甲烷过程的滞后,从而对甲烷收集利用产生不利影响。通过3根实验室模拟生物反应器,研究了原液回灌(C1)、渗滤液好氧预处理后回灌(C2)和原液回灌+垃圾层上部通风曝气(C3)3种填埋方式下的填埋气产气规律。结果表明,C1甲烷浓度经历短暂上升,达到19.5%后开始逐渐降低,产甲烷速率和产甲烷总量均很低;C2甲烷浓度逐渐上升,在第121天时甲烷浓度达到50%,产甲烷最高速率和产甲烷总量分别为0.31 L/(kg·d)和25.2 L/kg。在停止上部垃圾层通风曝气后,C3甲烷浓度迅速上升,在81 d时甲烷浓度便达到50%以上,最大产甲烷速率和产甲烷总量分别为0.22 L/(kg·d)和16.0 L/kg。对各模拟柱填埋气可回收性评价结果表明,C3填埋气可回收利用比例最高,C2略低,C1在实验期间内则无可回收利用气体产生。