Multivariate optimization of Cd(II) biosorption onto Ulmus tree leaves from aqueous waste

Ulmus tree leaves were successfully used as a novel and efficient biosorbent for removing cadmium, (Cd(II)), from aqueous solutions in a batch system. A multivariate strategy for optimization of removal efficiency conditions of Cd(II) was carried out. A 2³ full factorial design with three center points (9 runs) was performed for screening the main variables and reducing the large number of experimental runs. Initial concentration of metal ion (C _m), amount of sorbent (m), and pH were considered as the three main variables at two different levels. The maximum removal efficiency of Cd(II) was achieved within 1 h contact time. It was found that all the main factors and their interactions were significant at p < 0.05. Doehlert response surface methodology was utilized (13 runs) for finding a suitable mathematical model. The analysis of variance and some statistical tests such as lack-of-fit, coefficient of determination (R ²), and residual distribution plot confirmed the validity of the model. The optimum conditions for maximum removal of Cd(II) by Ulmus tree leaves were found as pH = 3.4, m (amount of sorbent) = 0.128 g, C _m (initial concentration of metal ion) = 12.1 mg L^?1.     

Accumulation and elimination of cadmium and lead in juvenile milkfish during sublethal exposure

Pollution of aquatic environments by trace metals is a worldwide environmental problem. Metal pollutants are increasingly being released into the environment as a result of industrialization. In this study, the bioaccumulation of cadmium and lead in young juvenile milkfish liver (Chanos chanos) was investigated after exposure to three sublethal concentration of each pollutants (1/20, 1/10, and 1/5 LC₅₀ of 96-h LC₅₀) for acute time 12, 24, and 96 h and subchronically for 7, 14, and 21 days. Cadmium and lead accumulation in liver increased with the exposure period and concentrations of pollutant. Compared to controls, the uptake of cadmium is much higher than that of lead. Accumulation factors showed an increase with exposure time and for lead an inverse relationship between accumulation factor and exposure concentration. The elimination of the two pollutants during the 30 days depuration was investigated after 30 days depuration time. During this phase, cadmium and lead concentrations decreased.     

Simultaneous Determination and Optimization of Titan Yellow and Reactive Blue 4 Dyes Removal Using Chitosan@hydroxyapatite Nanocomposites

Journal of Polymers and the Environment - Chitosan (CS) and hydroxyapatite (HA) nanocomposites have been prepared and used for the simultaneous removal of Titan Yellow (TY) and Reactive Blue 4 (RB...