Density functional theory (DFT) studies of vanadium-titanium based selective catalytic reduction (SCR) catalysts

Based on density functional theory (DFT) and basic structure models, the chemical reactions on the surface of vanadium-titanium based selective catalytic reduction (SCR) denitrification catalysts were summarized. Reasonable structural models (non-periodic and periodic structural models) are the basis of density functional calculations. A periodic structure model was more appropriate to represent the catalyst surface, and its theoretical calculation results were more comparable with the experimental results than a non-periodic model. It is generally believed that the SCR mechanism where NH₃ and NO react to produce N₂ and H₂O follows an Eley-Rideal type mechanism. NH₂NO was found to be an important intermediate in the SCR reaction, with multiple production routes. Simultaneously, the effects of H₂O, SO₂ and metal on SCR catalysts were also summarized.     

Determination of Trace Organochlorinated Pesticides and Polychlorinated Biphenyls in Water

A modified steam distillation liquid-liquid extraction (SDE) device is developed for the enrichment of trace organochlorinated pesticides (OCPs) and polychlorinated biphenyls (PCBs) in up to one litre of water samples. One ml of n-hexane is sufficient to extract the analytes. The extract can be analysed directly by a capillary gas chromatography-electron capture detector. The recoveries range from 84.6 to 102.3% for OCPs and 80.5 to 106.2% for PCBs, respectively. Matrice materials such as lipids and humic substances were removed by the SDE method from the extract and no further cleanup and concentration steps were needed.     

硫磺回收装置标定及分析

本文对Ⅱ套SRU的标定结果，进行了比较详细的技术分析，在此基础上，对装置及其运行状况作出了评价，并提出了一些建设。     

布、洛、维、肖氏硬度的相关关系

进行了布、洛、维、肖氏硬度之间的回归分析,建立了洛氏硬度与布氏、维氏、肖氏硬度之间,以及布氏硬度与维氏、肖氏硬度之间的回归关系式.     

混凝气浮-过滤工艺处理机械加工废水的生产性试验研究

采用混凝气浮-过滤为主体工艺，对哈轴集团一厂区的生产废水进行了生产性试验研究。试验结果表明：在进水COD和油类分别为400mg／L和200mg／L的情况下，出水水质分别达到了60mg／L和10mg／L，去除率高达85％和95％。经济分析表明：废水的运行成本为1．4元／t，具有显著的经济效益。     

纳米材料对环境和健康的潜在危害

随着越来越多的纳米商品材料在生产和生活中的应用，纳米材料的环境安全问题逐渐引起关注，纳米科技和纳米材料的潜在风险及其负面影响已成为专家共识。文章综述了纳米材料对环境和生命健康带来的可能危害及其毒性特性，并认为深入研究纳米材料的环境安全问题将有助于建立正确生产，使用和处理纳米材料的科学规范。     

Method of pollution sources assessment in relation to residential site selection

Much investigation supports a high incidence of disease and death rates when people live in ambient polluted air for a long time. Thus, the location of residential sites is important from a public health viewpoint. The method outlined in this paper is useful for determining the location of residential sites based on pollution sources assessment.     

加强城市灾害应急管理能力建设确保城市的可持续发展

本文通过对我国城市化与经济发展的关系,分析了我国城市面临的灾害形势及城市应急管理中存在的问题,提出了加强城市应急能力建设的途径,可供国内各大中城市参考和借鉴.     

超临界水处理有机废物研究新进展

超临界水处理废物以通过添加氧化剂的超临界水氧化和不加氧化剂的超临界水萃取两种方式实现，超临界水氧化应用较多，与其它废物处理技术相比有显著优点。本文总结了超临界水氧化流程和反应机理，评述了添加剂，温度，压力及停留时间，催化剂等对超临界水氧化反应的影响，同时介绍了超临界水氧化和超临界水萃取的最新应用研究状况及尚需解决问题。     

前车之鉴--访美国环保协会首席经济学家杜丹德先生

上世纪六七十年代，美国发生过不少环境重大事故，有的造成了较大的人员伤亡，有的还是发生在国外。但如今，美国在应对环境危机的各个方面，如立法、机构、人员培训、行政程序、信息披露等方面都走在了世界的前面。那么，过去的几十年，美国又是走过了一条什么样的路程？他们遇到了怎样的困境？社会对此又有什么反应？近日，我刊对美国环保协会中国项目首席经济学家杜丹德（Daniel J．Dudek）博士进行了采访。[编者按]