INCORPORATING NATURAL VARIABILITY,UNCERTAINTY, AND RISK INTO WATER QUALITY EVALUATIONS USING DURATION CURVES1

ABSTRACT: Quantifying natural variability, uncertainty, and risk with minimal data is one of the greatest challenges facing those engaged in water quality evaluations, such as development of total maximum daily loads (TMDL), because of regulatory, natural, and analytical constraints. Quantification of uncertainty and variability in natural systems is illustrated using duration curves (DCs), plots that illustrate the percent of time that a particular flow rate (FDC), concentration (CDC), or load rate (LDC; “TMDL”) is exceeded, and are constructed using simple derived distributions. Duration curves require different construction methods and interpretations, depending on whether there is a statistically significant correlation between concentration (C) and flow (Q), and on the sign of the C‐Q regression slope (positive or negative). Flow DCs computed from annual runoff data vary compared with an FDC developed using all data. Percent exceedance for DCs can correspond to risk; however, DCs are not composed of independent quantities. Confidence intervals of data about a regression line can be used to develop confidence limits for the CDC and LDC. An alternate expression to a fixed TMDL is suggested as the risk of a load rate being exceeded and lying between confidence limits. Averages over partial ranges of DCs are also suggested as an alternative expression of TMDLs. DCs can be used to quantify watershed response in terms of changes in exceedances, concentrations, and load rates after implementation of best management practices.     

IMPACT OF COAL SURFACE MINING ON THREE OHIO WATERSHEDS - SURFACE-WATER HYDROLOGY1

ABSTRACT: A study was conducted to determine the effects of mining and reclaiming originally undisturbed watersheds on surface-water hydrology in three small experimental watersheds in Ohio. Approximately six years of data were collected at each site, with differing lengths of premining (Phase 1), mining and reclamation (Phase 2), and post-reclamation (Phase 3) periods. Mining and reclamation activities showed no consistent pattern iii base-flow, and caused slightly more frequent higher daily flow volumes. Phase 2 activities can cause reductions in seasonal variation in double mass curves compared with Phase 1. Restoration of seasonal variations was noticeably apparent at one site during Phase 3. The responses of the watersheds to rainfall intensities causing larger peak flow rates generally decreased due to mining and reclamation, but tended to exceed responses observed in Phase 1 during Phase 3. Natural Resources Conservation Service (NRCS) curve numbers increased due to mining and reclamation (Phase 2), ranging from 83 to 91. During Phase 3, curve numbers remained approximately constant from Phase 2, ranging from 87 to 91.     

污染源普查数据质量评估方法研究

结合第一次全国污染源普查工作实际,给出普查数据质量评估指标,提出污染源普查数据质量评估内容。在此基础上,研究普查数据质量检验评估方法,确立普查数据质量评估体系,为计算机辅助污染源普查质量评估建立理论基础。     

Inputs and losses by surface runoff and subsurface leaching for pastures managed by continuous or rotational stocking

Pasture management practices can affect forage quality and production, animal health and production, and surface and groundwater quality. In a 5-yr study conducted at the North Appalachian Experimental Watershed near Coshocton, Ohio, we compared the effects of two contrasting grazing methods on surface and subsurface water quantity and quality. Four pastures, each including a small, instrumented watershed (0.51-1.09 ha) for surface runoff measurements and a developed spring for subsurface flow collection, received 112 kg N ha(-1) yr(-1) and were grazed at similar stocking rates (1.8-1.9 cows ha(-1)). Two pastures were continuously stocked; two were subdivided so that they were grazed with frequent rotational stocking (5-6 times weekly). In the preceding 5 yr, these pastures received 112 kg N ha(-1) yr(-1) after several years of 0 N fertilizer and were grazed with weekly rotational stocking. Surface runoff losses of N were minimal. During these two periods, some years had precipitation up to 50% greater than the long-term average, which increased subsurface flow and NO(3)-N transport. Average annual NO(3)-N transported in subsurface flow from the four watersheds during the two 5-yr periods ranged from 11.3 to 22.7 kg N ha(-1), which was similar to or less than the mineral-N received in precipitation. Flow and transport variations were greater among seasons than among watersheds. Flow-weighted seasonal NO(3)-N concentrations in subsurface flow did not exceed 7 mg L(-1). Variations in NO(3)-N leached from pastures were primarily due to variable precipitation rather than the effects of continuous, weekly rotational, or frequent rotational stocking practices. This suggests that there was no difference among these grazing practices in terms of NO(3)-N leaching.     

CeO_2/Fe_2O_3对高浓度苯酚废水微波诱导的氧化催化

对高浓度苯酚废水提出了用复合催化剂CeO2/Fe2O3进行微波诱导催化氧化的降解方法,并与单一催化剂Fe2O3的催化氧化效果进行了比较,对两者的表观反应动力学进行了分析,结果表明复合催化剂的催化效果比单一催化剂的催化效果高15%以上,其主要原因是CeO2/Fe2O3复合物具有很强的催化能力和较高的干电流变活性,有利于电子的迁移和羟基自由基·OH的形成,从而有利于苯酚的氧化降解。     

Runoff water quality during drought in a zero-order georgia piedmont pasture: nitrogen and total organic carbon

Approximately 11% of the Southern Piedmont (1.8 million ha) is used for pasture and hay production, mostly under low-input management. Few studies have investigated in the region long-term nitrogen and carbon losses in surface runoff, which can be significant. We present 1999 to 2009 hydrologic and water quality data from a rotationally grazed, 7.8-ha, zero-order pasture (W1) near Watkinsville in the Georgia Piedmont. Annual rainfall was 176 to 463 mm below the long-term average (1240 mm) in 7 of the 11 yr. There were 20 runoff events during 86 mo of below-average rainfall (deficit period), compared with 54 events during 46 mo of nondeficit period. Mean event flow-weighted concentration (in mg L) was 0.96 for nitrate-nitrogen (NO-N), 0.97 for ammonium-nitrogen (NH-N), 3.70 for total nitrogen (TN), and 9.12 for total organic carbon (TOC) ( = 43-47; limited due to instrument problem). Nutrient loads (in kg ha per event) averaged 0.04 for NO-N, 0.03 for NH-N, 0.19 for TN, and 0.54 for TOC. Total loads for N and TOC were 6 to 11 times greater from nondeficit than from deficit periods. The observed N concentrations, while well below maximum drinking water standard limits, could pose risk for eutrophication, which can be stimulated at lower concentrations. However, the ability of headwater streams, such as the one downstream of W1, to reduce nutrient concentrations might partially alleviate this concern. The results of this study point to the need to use a long-term dataset that includes measurements made in drought and wet years when evaluating the efficacy of water quality standards.     

IMPACT OF SURFACE COAL MINING ON THREE OHIO WATERSHEDS –PHYSICAL CONDITIONS AND GROUND-WATER HYDROLOGY1

ABSTRACT: A study was conducted over a six-year period in East-Central Ohio to determine the effects of surface mining and reclamation on physical watershed conditions and on ground-water hydrology in three ground-water zones in three small experimental watersheds. Mining disturbances in watersheds adjacent to the experimental sites affected ground-water levels in the undisturbed experimental watersheds prior to actual mining in the experimental sites. New subsurface flow paths, with different characteristics, formed during mining and reclamation. At all three sites mining dewatered the saturated zone above the underclay of the mined coal seam. Mining and reclamation affected ground-water levels below the mined coal seam in the middle and lower zones within at least two sites. Ground-water level recovery in the mined upper saturated zone was slow and irregular both temporally and spatially after reclamation. Hydraulic conductivities of postmining (Phase 3) spoil were generally greater than those of Phase 1 bedrock, but wide spatial variability was observed. Modelers need to be aware of the complexities of new flow paths and physical characteristics of subsurface flow media that are introduced by mining and reclamation, including destruction of the upper-zone clay.     

德尔菲法在归纳主要环境问题中的应用

尝试用德尔菲法归纳建德市的主要环境问题,对15位专家的2轮咨询结果进行统计分析,筛选出15个指标组合成10个主要环境问题,较好地反映了建德市的环境污染现状和变化趋势。     

IMPACT OF COAL SURFACE MINING AND RECLAMATION ON SUSPENDED SEDIMENT IN THREE OHIO WATERSHEDS1

ABSTRACT: Prior to PL95–87 little research had been conducted to determine the impacts of mining and reclamation practices on sediment concentrations and yields on a watershed scale. Furthermore, it was unknown whether sediment yield and other variables would return to undisturbed levels after reclamation. Therefore, three small watersheds, with differing lithologies and soils, were monitored for runoff and suspended sediment concentrations during three phases of watershed disturbances: undisturbed watershed condition, mining and reclamation disturbances, and post‐reclaimed condition. Profound increases in suspended‐sediment concentrations, load rates, and yields due to mining and reclamation activities, and subsequent drastic decreases after reclamation were documented. Even with increases in runoff potential, reductions in suspended‐sediment concentrations and load rates to below or near undisturbed‐watershed levels is possible by using the mulch‐crimping technique and by removing diversions. Maximum concentrations and load rates occurred during times of active disturbances that exposed loose soil and spoil to high‐intensity rains. Sediment concentrations remained elevated compared with the undisturbed watershed when diversions were not well maintained and overtopped, and when they were not removed for final reclamation. Diversions are useful for vegetation establishment, but should be maintained until they are removed for final reclamation after good vegetative cover is established.     

REGIONALIZATION OF STORM HYETOGRAPHS1

ABSTRACT: Regionalization of design storms can enhance their utility. Otherwise they have to be separately developed for different regions. Huff curves developed from point rainfall data collected at Coshocton, Ohio, and Chicago, Illinois, and from area-averaged Illinois and Texas precipitation data, are compared. The curves are similar in shape and position, with some visual differences depending on quartile. Kolmogorov-Smirnov tests showed no significant differences in moat of the comparisons. Where significant differences existed, they may not represent real differences due to the small number of storms sampled. Consequently, regionalization of Huff curves from Ohio to Illinois to Texas may be appropriate. The comparison of Huff curves is affected to an unknown degree both by the effects of area averaging of data and by basis. of-development differences. The effects of observed differences in Huff curves on watershed response variables (e.g., peak flow) requires further study.