Interinstrument comparison of remote-sensing devices and a new method for calculating on-road nitrogen oxides emissions and validation of vehicle-specific power

Emissions of nitrogen oxides (NOx) by vehicles in real driving environments are only partially understood. This has been brought to the attention of the world with recent revelations of the cheating of the type of approval tests exposed in the dieselgate scandal. Remote-sensing devices offer investigators an opportunity to directly measure in situ real driving emissions of tens of thousands of vehicles. Remote-sensing NO₂ measurements are not as widely available as would be desirable. The aim of this study is to improve the ability of investigators to estimate the NO₂ emissions and to improve the confidence of the total NOx results calculated from standard remote-sensing device (RSD) measurements. The accuracy of the RSD speed and acceleration module was also validated using state-of-the-art onboard global positioning system (GPS) tracking. Two RSDs used in roadside vehicle emissions surveys were tested side by side under off-carriageway conditions away from transient pollution sources to ascertain the consistency of their measurements. The speed correlation was consistent across the range of measurements at 95% confidence and the acceleration correlation was consistent at 95% confidence intervals for all but the most extreme acceleration cases. VSP was consistent at 95% confidence across all measurements except for those at VSP ≥ 15 kW t^?1, which show a small underestimate. The controlled distribution gas nitric oxide measurements follow a normal distribution with 2σ equal to 18.9% of the mean, compared to 15% observed during factory calibration indicative of additional error introduced into the system. Systematic errors of +84 ppm were observed but within the tolerance of the control gas. Interinstrument correlation was performed, with the relationship between the FEAT and the RSD4600 being linear with a gradient of 0.93 and an R² of 0.85, indicating good correlation. A new method to calculate NOx emissions using fractional NO₂ combined with NO measurements made by the RSD4600 was constructed, validated, and shown to be more accurate than previous methods.

Implications: Synchronized remote-sensing measurements of NO were taken using two different remote-sensing devices in an off-road study. It was found that the measurements taken by both instruments were well correlated. Fractional NO₂ measurements from a prior study, measurable on only one device, were used to create new NO_x emission factors for the device that could not be measured by the second device. These estimates were validated against direct measurement of total NO_x emission factors and shown to be an improvement on previous methodologies. Validation of vehicle-specific power was performed with good correlation observed.     

巴西亚马孙流域热带森林的开垦与大豆生产:以朗多尼亚州维列纳市为例

近来巴西大豆生产的增长引发了环境保护团体以及一些学者对于亚马孙盆地的热带自然环境正在向大豆种植地转换的关注.大豆生产的支持者则认为大豆是区域的一种可行性农产品;对于环境的关注是没有根据的,因为新的大豆种植地正在替代已经被砍伐的林地或者是转换了的土地.两种观点虽被提出却都没有对大豆生产扩充区的土地利用与土地覆被(LULC)状况进行过综合研究与估量.本案例研究是在巴西的朗多尼亚州,亚马孙盆地西南部的维列纳市(Vimena),通过遥感手段对1996～2001年以来该市大豆种植面积的大幅度增加所伴随的土地利用与土地覆被变化状况进行评估.结果表明虽然森林变成了大豆生产基地,但是大部分的大豆生产的增长归功于对已有土地的微量扩充、已伐林地的转换以及更高的单位产量.     

Who cleans up the oil? A microeconomic study

Although oil spill cleanup requirements have existed in the United States for years, recent increases in oil imports and marine transportation of petroleum products as well as growing environmental concern have exposed a new industry, the Oil Spill Cleanup Industry. This paper explores some of the microeconomic aspects of this industry which has come under increased scrutiny by the general public, big business, and the federal government.In addition to a brief history and definition, several basic questions about the economic viability of the oil spill cleanup industry are raised and explored, and the impact on the industry of cleanup from government sources is examined, both from the perspective of present operations and from apparent future increases in federal participation. The primary dilemma facing the industry, that of providing continued and immediate supply while confronted with stochastic demand, is discussed. The effects of the large spill on the industry both in terms of revenue and ability to meet cleanup requirements is also considered.Information for the paper is drawn from past and continuing involvement in the U.S. Coast Guard's Marine Environmental Protection Program by both authors. The statistical evidence presented here was compiled through personal interviews and from two computerized Coast Guard information systems; PIRS (the Pollution Incident Reporting System), and SKIM (the Spill Cleanup Equipment Inventory System).     

VEGETATION INFLUENCE ON SMALL STREAM SILTATION1

ABSTRACT: A meandering stream channel was simulated in the Hydraulics Laboratory at Colorado State University and a series of tests was conducted using four types of vegetation to evaluate the potential effects of vegetation on sediment deposition and retention in a stream channel. The data collected included average flow velocity, flow depth, length of vegetation, density of vegetation, cross-sectional area of the vegetative stem, wetted perimeter of the vegetative stem, and injection and flushing time. The findings indicated that the vegetation could retain from 30 to 70 percent of the deposited sediments. The ability of vegetation to entrap and retain sediment is related to the length and cross-sectional area of the vegetation. The variables describing the flow and the vegetative properties were combined to form a predictive parameter, the sedimentation factor (S_d) that can be compared with the amount of sediment entrapped by vegetation in a stream system. A relation was developed correlating vegetation length to sediment retention after flushing for flexibility and rigid vegetation.     

DENSITY CURRENT INTRUSIONS IN AN ICE-COVERED URBAN LAKE1

ABSTRACT: Evidence is presented that snowmelt runoff from an urban watershed can produce density current intrusions (underflows) in a lake. Several episodes of density current intrusions are documented. Water temperatures and salinities measured near the bottom of a 10 m deep Minneapolis lake during the late winter warming periods in 1989, 1990, 1991, and 1995 show significant rapid changes which are correlated with observed higher air temperatures and snowmelt runoff. The snowmelt runoff entering this particular lake (Ryan Lake) has increased electrical conductivity, salinity, and density. The source of the salinity is the salt spread on urban streets in the winter. Heating of littoral waters in spring may also contribute to the occurrence of the sinking flows, but is clearly not the only cause.     

Employers′ knowledge of the hazard communication standard requirements and the perceived barriers to compliance

This study examined employers′ perceived knowledge of the Hazard Communication Standard (HCS) requirements prior to the inspection in which they were cited for an HCS violation. A lack of staff available to implement the HCS program was identified as having a significant impact upon compliance (p < 01). The perceived difficulty with compliance was also examined by the violations received by the organization. Those organizations cited for failing to have a written program identified a lack of staff available to implement the HCS requirements as having a greater impact upon compliance than those not cited for written program violations (p < 05). Suggested methods for improving the overall compliance with the HCS may include using the many compliance resources available through insurance companies, safety organizations, and state programs. Areas for further research include identifying the availability, use, and effectiveness of the outside safety and health compliance resources.     

Speciation of organotins in polyvinyl chloride pipe via X-ray absorption spectroscopy and in leachates using GC-PFPD after derivatisation

Three different polyvinyl chloride (PVC) pipe types were subjected to de-ionized water exposures over the course of at least 180 days. Water exposed to the pipe was analyzed for organotin speciation and concentration. Organotin concentrations were the highest during the first 1-5 days. The species and concentrations of organotins leached varied by pipe type. Data were normalized by surface area in order to compare laboratory results with results from a residential pipe system. For one pipe type, the lowest non-zero concentrations from the laboratory tests overestimated organotin concentrations in solution when compared with water samples from the same pipe type in a residence. For organotin exposure estimates, a range of 0.1 ng m(-2) to 10 ng m(-2) could be used for mature pipes (e.g. in use for 1 year). These estimates should be refined with more field study, however, due to the high variation in organotin species and concentrations leached as a function of pipe type, accuracy within an order of magnitude may be optimal as, in many instances, the type of pipe installed or buried may be unknown. X-ray absorption spectroscopy (XAS) was used to identify organic and inorganic tin species in reference materials and the PVC samples. Monobutyl tin was identified as the primary organotin species in the pipes. Results from the XAS analyses also indicate that the technique shows promise for distinguishing between inorganic tin and organotins. Furthermore, organotins may be distinguished between mono-, di-, and tri-ligand species using XAS.     

Comparative Analysis of Management Regimes and Medicinal Plant Trade Monitoring Mechanisms for American Ginseng and Goldenseal

Abstract: Two popular and profitable native North American medicinal plants, American ginseng (    Panax quinquefolius ) and goldenseal (   Hydrastis canadensis ), both of which are listed in Appendix 2 of the Convention on International Trade in Endangered Species of Wild Fauna and Flora (CITES), are monitored under disparate domestic strategies that are designed to satisfy CITES requirements. The P. quinquefolius program has benefited the species by encouraging U.S. states to enact laws to protect wild populations and regulate collection, and by establishing a transparent system under which harvest, commerce, and export can be monitored, evaluated, and controlled routinely. But certain programmatic constraints, such as insufficient funding and gaps in biological monitoring, undermine its effectiveness as a management strategy for the species. The joint industry and government H. canadensis initiative is intended to give commercial traders more responsibility in monitoring plant trade and the federal government access to information that may otherwise be difficult to obtain without the help of traders. I examined the structure, successes, and deficiencies of the P. quinquefolius program, promising features of the evolving H. canadensis program, Turkey's management of geophytes, and other sources of information from federal agencies that might contribute to more effective management of medicinal plants in the United States. Although the main goal of domestic monitoring programs for P. quinquefolius and H. canadensis is to implement their CITES listings, it is conceivable that similar programs could be established for non–CITES medicinal plants, thereby minimizing or replacing the need for CITES protection.     

Training Captive-Bred or Translocated Animals to Avoid Predators

Abstract: Animal reintroductions and translocations are potentially important interventions to save species from extinction, but most are unsuccessful. Mortality due to predation is a principal cause of failure. Animals that have been isolated from predators, either throughout their lifetime or over evolutionary time, may no longer express appropriate antipredator behavior. For this reason, conservation biologists are beginning to include antipredator training in pre-release preparation procedures. We describe the evolutionary and ontogenetic circumstances under which antipredator behavior may degenerate or be lost, and we use principles from learning theory to predict which elements can be enhanced or recovered by training. The empirical literature demonstrates that training can improve antipredator skills, but the effectiveness of such interventions is influenced by a number of constraints. We predict that it will be easier to teach animals to cope with predators if they have experienced ontogenetic isolation than if they have undergone evolutionary isolation. Similarly, animals should learn more easily if they have been evolutionarily isolated from some rather than all predators. Training to a novel predator may be more successful if a species has effective responses to similar predators. In contrast, it may be difficult to teach proper avoidance behavior, or to introduce specialized predator-specific responses, if appropriate motor patterns are not already present. We conclude that pre-release training has the potential to enhance the expression of preexisting antipredator behavior. Potential training techniques involve classical conditioning procedures in which animals learn that model predators are predictors of aversive events. However, wildlife managers should be aware that problems, such as the emergence of inappropriate responses, may arise during such training.