碳素纤维在近岸海洋污染物磷酸盐、硅酸盐处理中的应用

对碳素纤维进行氧化改性,利用改性后的碳素纤维处理近岸污染海水,重点研究了改性碳素纤维对海水中活性磷酸盐和活性硅酸盐的吸附作用。考察了碳素纤维液相改性时间、碳素纤维投加量、活性磷酸盐初始浓度、活性硅酸盐初始浓度、吸附时间、海况、pH值等单因素对近岸海洋污染物磷酸盐、硅酸盐吸附效果的影响。研究结果表明:改性碳素纤维对硅酸盐的吸附效果较好,去除率可达70%,对活性磷酸盐的去除率为31%左右。通过正交实验确定改性碳素纤维材料修复模拟近岸海水的优化条件为:碳素纤维改性时间为1.5 h,投加量为0.01 g,硅酸盐初始浓度为3mg/L,磷酸盐初始浓度为20 mg/L,海况为3级,pH值为8,吸附时间为3 h。在此条件下,碳素纤维对磷酸盐的去除率可达31.06%,硅酸盐去除率可达70.88%。     

Scientist and Policy-Maker Response Types and Times in Suburban Watersheds

Differences between scientist and policy-maker response types and times, or the “how” and “when” of action, constrain effective water resource management in suburbanizing watersheds. Policy-makers are often rushed to find a single policy that can be applied across an entire, homogeneous, geopolitical region, whereas scientists undertake multiyear research projects to appreciate the complex interactions occurring within heterogeneous catchments. As a result, watershed management is often practiced with science and policy out of synch. Meanwhile, development pressures in suburban watersheds create changes in the social and physical fabric and pose a moving target for science and policy. Recent and anticipated advances in the scientific understanding of urbanized catchment hydrology and pollutant transport suggest that management should become increasingly sensitive to spatial heterogeneities in watershed features, such as soil types, terrain slopes, and seasonal watertable profiles. Toward this end, policy-makers should encourage funding scientific research that characterizes the impacts of these watershed heterogeneities within a geopolitical zoning and development framework.     

Scientist and policy-maker response types and times in suburban watersheds

Differences between scientist and policy-maker response types and times, or the “how” and “when” of action, constrain effective water resource management in suburbanizing watersheds. Policy-makers are often rushed to find a single policy that can be applied across an entire, homogeneous, geopolitical region, whereas scientists undertake multiyear research projects to appreciate the complex interactions occurring within heterogeneous catchments. As a result, watershed management is often practiced with science and policy out of synch. Meanwhile, development pressures in suburban watersheds create changes in the social and physical fabric and pose a moving target for science and policy. Recent and anticipated advances in the scientific understanding of urbanized catchment hydrology and pollutant transport suggest that management should become increasingly sensitive to spatial heterogeneities in watershed features, such as soil types, terrain slopes, and seasonal watertable profiles. Toward this end, policy-makers should encourage funding scientific research that characterizes the impacts of these watershed heterogeneities within a geopolitical zoning and development framework.     

二氧化氯消毒前后污水毒性的变化及消毒条件的影响

采用发光细菌试验和umu试验,分别考察了二氧化氯投加量和反应时间对污水二氧化氯消毒后急性毒性和遗传毒性变化的影响.结果表明,随着二氧化氯消毒剂投加量的增加,消毒后水样的急性毒性不断增大,但遗传毒性逐渐减小后趋于稳定.随着反应时间的延长,二氧化氯的消耗量不断增大,消毒后水样的急性毒性先增大后减小,遗传毒性逐渐减小后趋于稳定.由于消毒条件对污水急性毒性和遗传毒性有着不同的影响,说明污水中产生急性毒性和产生遗传毒性的物质不同,对于某一种污水,通过控制消毒条件可以使消毒后污水的急性毒性和遗传毒性都较低.     

iTree‐Hydro: Snow Hydrology Update For The Urban Forest Hydrology Model1

Yang, Yang, Theodore A. Endreny, and David J. Nowak, 2011. iTree‐Hydro: Snow Hydrology Update for the Urban Forest Hydrology Model. Journal of the American Water Resources Association (JAWRA) 47(6):1211–1218. DOI: 10.1111/j.1752‐1688.2011.00564.x Abstract: This article presents snow hydrology updates made to iTree‐Hydro, previously called the Urban Forest Effects—Hydrology model. iTree‐Hydro Version 1 was a warm climate model developed by the USDA Forest Service to provide a process‐based planning tool with robust water quantity and quality predictions given data limitations common to most urban areas. Cold climate hydrology routines presented in this update to iTree‐Hydro include: (1) snow interception to simulate the capture of snow by the vegetation canopy, (2) snow unloading to simulate the release of snow triggered by wind, (3) snowmelt to simulate the solid to liquid phase change using a heat budget, and (4) snow sublimation to simulate the solid to gas phase via evaporation. Cold climate hydrology routines were tested with research‐grade snow accumulation and weather data for the winter of 1996‐1997 at Umpqua National Forest, Oregon. The Nash‐Sutcliffe efficiency for open area snow accumulation was 0.77 and the Nash‐Sutcliffe efficiency for under canopy was 0.91. The USDA Forest Service offers iTree‐Hydro for urban forest hydrology simulation through http://www.iTreetools.org .     

中国地区多溴联苯醚在不同环境介质中的监测进展

多溴联苯醚(Polybrominated diphenyl ethers, PBDEs)为一类新型的溴代阻燃剂,广泛应用于塑料制品、纺织品、电路板和建筑材料等领域。随着生产量和使用量的增加,PBDEs已造成全球环境污染,其带来的环境问题已引起各国关注。同时PBDEs的长距离迁移性和难降解性,使其在环境介质中进行富集,从而加重污染。归纳了中国地区PBDEs的监测进展,分别从大气、水体、沉积物和土壤中PBDEs的污染水平以及原因进行了分析和探讨。在此基础上,对于我国PBDEs的研究方向提出了展望。     

毒死蜱的微波辅助无极汞灯光降解机理研究

毒死蜱是目前全球应用最广泛的有机磷杀虫剂之一,光化学降解是其主要的环境降解途径.文章研究了毒死蜱在水相中微波辅助无极汞灯(MW-EDML)下光降解过程,并应用LC-MS法对其降解产物进行了鉴定.同时,采用量子化学方法中的密度泛函数方法B3LYP/6-31G(d)基组计算了毒死蜱的量子化学参数,探讨了其光降解特性与分子结...     

Analysis of Daily Peaking and Run‐of‐River Operations with Flow Variability Metrics,Considering Subdaily to Seasonal Time Scales

Environmental flows are an important consideration in licensing hydropower projects as operational flow releases can result in adverse conditions for downstream ecological communities. Flow variability assessments have typically focused on pre‐ and post‐dam conditions using metrics based on daily averaged flow values. This study used subdaily and daily flow data to assess environmental flow response to changes in hydropower operations from daily peaking to run‐of‐river. An analysis tool was developed to quantify flow variability metrics and was applied to four hydropower projects. Significant differences were observed between operations at the 99% confidence level in the median flow values using hourly averaged flow datasets. Median daily rise and fall rates decreased on average 34.5 and 27.9%, respectively, whereas median hourly rise and fall rates decreased on average 50.1 and 50.6%, respectively. Differences in operational flow regimes were more pronounced in the hourly averaged flow datasets and less pronounced or nonexistent in the daily averaged flow datasets. These outcomes have implications for the development of ecology‐flow relationships that quantify effects of flow on processes such as fish stranding and displacement, along with habitat stability. Results indicate that flow variability statistics should be quantified using subdaily datasets to accurately represent the nature of hydropower operations, especially for daily peaking facilities.     

Effect of copper on the degradation of pesticides cypermethrin and cyhalothrin

The influence of coexisting copper (Cu) ion on the degradation of pesticides pyrethroid cypermethrin and cyhalothrin in soil and photodegradation in water system were studied.Serial concentrations of the pesticides with the addition of copper ion were spiked in the soil and incubated for a regular period of time,the analysis of the extracts from the soil was carried out using gas chromatography (GC).The photodegradation of pyrethroids in water system was conducted under UV irradiation.The effect of Cu~(2 ) on the pesticides degradation was measured with half life (t_(0.5)) of degradation.It was found that a negative correlation between the degradation of the pyrethroid pesticides in soil and Cu addition was observed.But Cu~(2 ) could accelerate photodegradation of the pyrethroids in water.The t_(0.5) for cyhalothrin extended from 6.7 to 6.8 d while for cypermethrin extended from 8.1 to 10.9 d with the presence of copper ion in soil.As for photodegradation,t_(0.5) for cyhalothrin reduced from 173.3 to 115.5 rain and for cypermethrin from 115.5 to 99.0 min.The results suggested that copper influenced the degradation of the pesticides in soil by affecting the activity of microorganisms.However, it had catalyst tendency for photodegradation in water system.The difference for the degradation efficiency of pyrethroid isomers in soil was also observed.Copper could obviously accelerate the degradation of some special isomers.     

2003~2018年干旱对中国森林绿度异常的影响

基于卫星观测和气象再分析数据提取2003~2018年间中国森林绿度异常现象(月尺度LAI长期趋势的累积偏差), 并分析干旱对森林绿度异常影响的时空动态变化, 探究不同森林类型的干旱敏感性.结果表明: ①干旱导致的绿度异常现象频率分布呈现出南高北低的空间格局, 而高强度异常现象主要分布于中国的东北与西南地区.②2003~2018年间绿度异常严重程度呈现显著增加趋势(即绿度异常强度指数下降), 变化率为: -0.06/a(P<0.05), 而绿度异常面积比率下降, 变化率为-0.0049/a.③中国森林对干旱胁迫较为敏感的区域主要分布于云南北部与大兴安岭北部, 这是由区域的地质和气候特点以及植被类型共同作用导致的.④干旱主导区不同森林类型的干旱敏感性依次为: 阔叶林>针叶林>混交林, 绿度异常与SPEI回归斜率依次为1.8>1.3>1.2.⑤针叶林遭受的干旱强度最高, 2003~2018年间统计的SPEI中位数为-1.65, 绿度异常现象也最为严重, 多年绿度异常指数中位数为-1.81, 说明干旱强度而非敏感性主导了森林绿度异常的现象.