全文获取类型
收费全文 | 206篇 |
免费 | 3篇 |
国内免费 | 3篇 |
专业分类
安全科学 | 7篇 |
废物处理 | 13篇 |
环保管理 | 16篇 |
综合类 | 41篇 |
基础理论 | 42篇 |
污染及防治 | 57篇 |
评价与监测 | 20篇 |
社会与环境 | 14篇 |
灾害及防治 | 2篇 |
出版年
2023年 | 2篇 |
2022年 | 5篇 |
2021年 | 5篇 |
2020年 | 5篇 |
2019年 | 6篇 |
2018年 | 11篇 |
2017年 | 9篇 |
2016年 | 13篇 |
2015年 | 18篇 |
2014年 | 12篇 |
2013年 | 21篇 |
2012年 | 9篇 |
2011年 | 13篇 |
2010年 | 10篇 |
2009年 | 11篇 |
2008年 | 8篇 |
2007年 | 10篇 |
2006年 | 7篇 |
2005年 | 15篇 |
2004年 | 10篇 |
2003年 | 5篇 |
2002年 | 4篇 |
2001年 | 1篇 |
2000年 | 1篇 |
1992年 | 1篇 |
排序方式: 共有212条查询结果,搜索用时 31 毫秒
1.
Canterino M Marotta R Temussi F Zarrelli A 《Environmental science and pollution research international》2008,15(3):182-187
BACKGROUND: Synthetic musk compounds are widely used as additives in personal care and household products. The photochemical degradation of musk tibetene in aqueous solutions or in acetonitrile/water mixtures under different conditions was studied in order to assess its environmental fate. METHODS: Musk tibetene dissolved (or suspended) in water and/or acetonitrile/water mixtures was irradiated at different times by UV-light and by solar light. The irradiation mixtures were analyzed by NMR and TLC. The photoproducts formed were identified by GC-MS and NMR data. RESULTS: The experimental results indicated that musk tibetene was photodegradable in water or acetonitrile/water mixtures with half-life reaction times close to 20 minutes. The irradiation mixtures were separated by chromatographic techniques yielding three photoproducts (3,3,5,6,7-pentamethyl-4-nitro-3H-indole, 3,3,5,6,7-pentamethyl-4-nitro-1H-indoline and 3,3,5,6,7-pentamethyl-4-nitro-3H-indolinone) identified by means of spectroscopic analysis. DISCUSSION: The numerical modelling of the photodegradation concentration-time profiles gave (8.13 +/- 0.15) x 10(-2) and (1.34 +/- 0.04) x 10(-2) mol/E for the overall primary quantum yield of direct photolysis for musk tibetene and the major intermediate (3,3,5,6,7-pentamethyl-4-nitro-3H-indolinone), respectively, in the wavelength range 305-366 nm. The half-life times of photodegradation of the both substances varied from 1-1.5 hours at 20 degrees N during the summer season to 6-10 hours for highest latitudes in winter. CONCLUSIONS: Under solar light, musk tibetene was photolabile in acetonitrile and acetonitrile/water 1/1, while it was slowly degraded when suspended in water. In all media, musk tibetene was photodegraded into three photoproducts. By using a kinetic model, the overall primary quantum yields of direct photolysis of musk tibetene and its main photoproduct, in the wavelength range 305-366 nm, were estimated, indicating that the photodegradation rate for musk tibetene is faster than the photolysis rate of the major by-product. RECOMMENDATIONS AND PERSPECTIVES: The results indicate that, in order to assess the environmental impact of musk tibetene on the aquatic ecosystem, great attention should be focused on the major photoproduct which is proved to be more persistent than the parent compound under light irradiation. The predicted half-life times of direct photolysis for both substances ranged from 1-1.5 hours at 20 degrees N during the summer season to about 6-10 hours for highest latitudes in winter, indicating that, from a photochemical point of view, the environmental persistence of these substances increases by increasing the latitudes and during the cold seasons, making more realistic an intake of these xenobiotic molecules into the food chain of aquatic living organisms. Tanabe reports in his Editorial (Tanabe 2005) that "It is necessary to have knowledge of the global picture of synthetic musk pathways. So, it is conceivable that now is the time to study the transport, persistency, distribution, bioaccumulation and toxic potential of this new environmental menace on a global scale, especially in developing countries". Therefore, the future environmental analysis and investigations on the eco-toxicity of nitro musk compounds should take into account not only the presence of the parent compounds but also their photochemical intermediates or end-by-products. 相似文献
2.
Almeida Hanna N. Calixto Guilherme Q. Chagas Bruna M. E. Melo Dulce M. A. Resende Fabio M. Melo Marcus A. F. Braga Renata Martins 《Environmental science and pollution research international》2017,24(16):14142-14150
Environmental Science and Pollution Research - Biofuels have been seen as potential sources to meet future energy demand as a renewable and sustainable energy source. Despite the fact that the... 相似文献
3.
4.
Gosetti Fabio Robotti Elisa Bolfi Bianca Mazzucco Eleonora Quasso Fabio Manfredi Marcello Silvestri Simone Facchi Arianna Marengo Emilio 《Environmental science and pollution research international》2019,26(21):21274-21294
Environmental Science and Pollution Research - Rice cultivation requires a large use of pesticides and nutrients to control weed proliferation and improve production. The water quality of four... 相似文献
5.
6.
Zagonari F 《Journal of environmental management》2008,88(4):796-804
In this paper, a dynamic model is developed in which coastal quality can be improved, restored, or maintained by two distinct user groups; this is done by identifying a context that ensures an increase (or a greater increase) in coastal quality in terms of specific features that characterise the user groups. The results demonstrate that integrated coastal management is always better than non-integrated management. Moreover, when there is a low degree of interest in maintaining the coastal use over time, only integrated community-based (CB) coastal management will increase the coastal quality. Even when the interest in maintaining the coastal use over time is high, an integrated CB approach is preferred if the willingness to pay for coastal improvements is great and the marginal inefficiency of investments in coastal improvements is low, because the coastal quality improves to a greater extent; if not, only an integrated top-down (TD) approach to coastal management will increase the coastal quality. These results suggest that developing countries should always adopt a CB approach; in contrast, developed countries should adopt a CB approach where local stakeholders attach direct values to the coastal quality, and adopt a TD approach where the general population attaches indirect (option or existence) values to coastal quality. 相似文献
7.
8.
Baked Foams Based on Cassava Starch Coated with Polyvinyl Alcohol with a Higher Degree of Hydrolysis
Fabíola Azanha de Carvalho Ana Paula Bilck Fabio Yamashita Suzana Mali 《Journal of Polymers and the Environment》2018,26(4):1445-1452
The aims of this work were to produce trays based on cassava starch, coated with polyvinyl alcohol (PVA) with a higher degree of hydrolysis (98%), and to study the effects of the coating on the mechanical and water sorption properties of the trays. Two types of PVA were tested: SELVOL? 325 (degree of polymerization?=?1000–1500) and SELVOL? 107 (degree of polymerization?=?350–650). A decrease in the water absorption capacity of 50% was observed when the coated samples were compared with the control sample after 30 min of immersion in water. It was observed in both coated samples a reduction of the initial rate of water adsorption sorption and a decrease in hydrophilicity compared with the control sample. Tensile strength and elongation were increased with application of the coatings. The use of the two types of PVA resulted in materials with similar mechanical and water sorption properties. 相似文献
9.
Barbara Marchetti Francesco Corvaro Giancarlo Giacchetta Fabio Polonara Roberta Cocci Grifoni Mariella Leporini 《International Journal of Sustainable Engineering》2018,11(3):173-185
On the basis of the method for managing the end of life of CdTe photovoltaic panels previously proposed by the authors, a new method for the recycling of all types of thin-film panels (CdTe, a-Si and CIS/CIGS) has been developed and optimised under a research project founded by Enel Foundation and CRUI Foundation. The DGP process has been developed through a feasibility study carried out from three points of view: technical, environmental and economic. The process is composed by two sub-processes matched to each other, one suitable for CdTe panels (named DGPa) and the other one for a-Si and CIS/CIGS panels (DGPb). The Double Green Panel process is based mainly on mechanical treatments with a minimum use of chemicals and it is characterised by a greater level of automation and a high flexibility in production capacity. The potential environmental impacts of various configurations of the DGP process have been extensively analysed with LCA tool in order to develop an environmentally friendly process. The economic feasibility has been assessed through the Discounted Cash Flow Analysis (DCFA) method. The revenues associated to the recovery of valuable and common materials and the recycling costs have been taken into account. 相似文献
10.
Umberto Iemma Fabio Pisi Vitagliano 《International Journal of Sustainable Engineering》2018,11(2):122-134
The current work deals with multi-objective optimisations including financial merit factors in the multi-disciplinary conceptual design of a commercial aircraft with a specific focus on noise social cost. The results of optimisations using financial and performance-oriented objective functions have been analysed and combined in a multi-objective optimisation problem using a three-dimensional objective vector. The main novelty of the present work is the analysis of social cost noise fees effectiveness integrated in financial models embracing a wider group of stakeholders’ interests. The foundations of this research lie on the air traffic increase envisaged in the next decades and the contextual growth of the urban areas nearby airport facilities. This scenario requires the aeronautical industry to handle the environment challenge taking into account all the social and economic effects. Indeed, the consolidated technology has approached a saturation point, therefore breakthrough concepts and configurations are mandatory. This matter is addressed as a highly multi-disciplinary problem within conceptual design framework. The financial model proposed is shown to highlight the need of appropriate noise fees as instruments to push all stakeholders towards a technology radical renewal and encourage the aeronautical industry towards a shared strategy in the development of an eco-friendly commercial aviation system. 相似文献