Environmental monitoring of historical change in arsenic deposition with tree bark pockets

ICP-MS analysis recorded historical change (c. 1846 to 2002) in the arsenic concentration of bark included within the trunks (tree bark pockets) of two Japanese oak trees (Quercus crispula), collected at an elevated location approximately 10 km from the Ashio copper mine and smelter, Japan. The arsenic concentration of the bark pockets was 0.016 +/- 0.003 microg cm(-2) c. 1846 (n = 5) and rose 50-fold from c. 1875 to c. 1925, from approximately 0.01 to 0.5 microg cm(-2). The rise coincided with increased copper production in Ashio from local sulfide ores, from 46 tons per year in 1877 to 16,500 tons per year in 1929. Following a decline in arsenic concentration and copper production, in particular during the Second World War, a second peak was observed c. 1970, corresponding to high levels of production from both local (6,000 tons per year) and imported (30,000 tons per year) ores, smelted from 1954. Compared to the local ores, the contribution of arsenic from imported ores appeared relatively low. Arsenic concentrations declined from c. 1970 to the present following the closure of the mine in 1974 and smelter in 1989, recording 0.058 +/- 0.040 microg cm(-2) arsenic (n = 5) in surface bark collected in 2002. The coincident trends in arsenic concentration and copper production indicated that the bark pockets provided an effective record of historical change in atmospheric arsenic deposition.     

An Integrated Assessment of Climate Change and the Accelerated Introduction of Advanced Energy Technologies - An Application of MiniCAM 1.0

We report results from the application of an integrated assessment model, MiniCAM 1.0. The model is employed to explore the full range of climate change implications of the successful development of cost effective, advanced, energy technologies. These technologies are shown to have a profound effect on the future magnitude and rate of anthropogenic climate change. We find that the introduction of assumptions developed by a group of ‘bottom-up’ modelers for the LEESS scenarios into a ‘top-down’ model, the Edmonds-Reilly-Barns Model, leads to ‘top down’ emissions trajectories similar to those of the LEESS. The cumulative effect of advanced energy technologies is to reduce annual emissions from fossil fuel use to levels which stabilize atmospheric concentrations below 550 ppmv. While all energy technologies play roles, the introduction of advanced biomass energy production technology is particularly important. The consideration of all greenhouse related anthropogenic emissions, and in particular sulfur dioxide, is found to be important. We find that the consideration of sulfur dioxide emissions coupled to rapid reductions in carbon dioxide emissions leads to higher global mean temperatures prior to 2050 than in the reference case. This result is due to the short-term cooling impact of sulfate aerosols, which dominates the long-term warming impact of CO₂ and CH₄ in the years prior to 2050. We also show that damage calculations which use only mean global temperature and income may be underestimating damages by up to a factor of five. Disaggregating income reduces this to a factor of two, still a major error. Finally, the role of the discount rate is shown to be extraordinarily important to technology preference.     

Building a place-responsive society through inclusive local projects and networks

This paper presents the story of a project undertaken by researchers who are active participants in the national Australian debate over place and belonging. It arose from the desire to ground this debate, which brings issues of ecological sustainability, reconciliation and multiculturalism together, in more localised action aimed at building a 'place-responsive society'. The project was carried out as a case study in a region that combines part of the Sydney metropolitan area and the separate 'city' of the Blue Mountains, and involved a consultative committee and then a regional forum of conservationists, environmental educators and community workers. The researchers explored existing place-oriented initiatives in the region and developed practical projects for the future, most notably a proposal for 'totemic species' work within schools involving local Aboriginal people. The research demonstrated, more than anything else, that indigenous Australian approaches to 'place awareness' and nature conservation remain highly relevant in contemporary Australia. It also showed that bioregional awareness and the notion of place responsiveness can add value to more traditional approaches to nature conservation and environmental education. There are opportunities to galvanise local action that can integrate community and environmental work and revitalise professional practice in both areas, but the effort involves working constantly with difference and conflict.     

The case for carbon leakage and border adjustments: where do economists stand?

Environmental Economics and Policy Studies - While the EU is working toward the implementation of the world’s first Carbon Border Adjustment (CBA) Mechanism, a gap remains between the ways in...     

Cyclic Trends in Los Angeles Fine Participates

Noontime visibilities in downtown Los Angeles, averaged over the smog season of June through November, show two cycles of general deterioration and improvement. The improvement since 1962 is confirmed by available high volume filter data and conditions in 1974/75 are at least as good as at anytime since observations were begun in 1933. The decrease in frequency of “rule 57” days suggests that the improvement of the last decade and perhaps the cyclic variation of the past 40 years has been primarily of meteorological origin.     

Monitoring of carbon monoxide in residences with bulk wood pellet storage in the Northeast United States

The interest in biomass fuel is continuing to expand globally and in the northeastern United States as wood pellets are becoming a primary source of fuel for residential and small commercial systems. Wood pellets for boilers are often stored in basement storage rooms or large bag-type containers. Due to the enclosed nature of these storage areas, the atmosphere may exhibit increased levels of carbon monoxide. Serious accidents in Europe have been reported over the last decade in which high concentrations of carbon monoxide (CO) have been found in or near bulk pellet storage containers. The aim of this study was to characterize the CO concentrations in areas with indoor storage of bulk wood pellets. Data was obtained over approximately 7 months (December 2013 to June 2014) at 25 sites in New Hampshire and Massachusetts: 16 homes using wood pellet boilers with indoor pellet storage containers greater than or equal to 3 ton capacity; 4 homes with wood pellet heating systems with outdoor pellet storage; 4 homes using other heating fuels; and a university laboratory site. CO monitors were set up in homes to collect concentrations of CO in the immediate vicinity of wood pellet storage containers, and data were then compared to those of homes using fossil fuel systems. The homes monitored in this study provided a diverse set of housing stock spanning two and a half centuries of construction, with homes built from 1774 to 2013, representing a range of air exchange rates. The CO concentration data from each home was averaged hourly and then compared to a threshold of 9 ppm. While concentrations of CO were generally low for the homes studied, the need to properly design storage locations for pellets is and will remain a necessary component of wood pellet heating systems to minimize the risk of CO exposure.

Implications: This paper is an assessment of carbon monoxide (CO) exposure from bulk wood pellet storage in homes in New Hampshire and Massachusetts. Understanding the CO concentrations in homes allows for better designs for storage bins and ventilation for storage areas. Hence, uniform policies for stored wood pellets in homes, schools, and businesses can be framed to ensure occupant safety. Currently in New York State rebates for the installation of wood pellet boilers are only provided if the bulk pellet storage is outside of the home, yet states such as New Hampshire, Vermont, and Maine currently do not have these restrictions.     

Heterogeneous photocatalytic degradation of pesticides using decatungstate intercalated macroporous layered double hydroxides

Decatungstate W₁₀O₃₂ ^4? was efficiently intercalated between the layers of three-dimensionally ordered macroporous Mg₂Al-layered double hydroxide. The structural and textural properties of as-prepared intercalated compound were characterized using different solid-state characterization techniques such as X-ray powder diffraction, FTIR and Raman spectroscopies and electronic microscopy. The photocatalytic properties of immobilized W₁₀O₃₂ ^4? within Mg₂Al structure were investigated using 2-(1-naphthyl) acetamide (NAD) as a model of pesticide. The influence of different parameters such as amount of catalyst, pH and oxygen concentration were investigated. An optimal NAD degradation was obtained for a photocatalyst concentration of 60 mg l^?1. Under our experimental conditions, this heterogeneous photocatalyst induces photodegradation of 60 % of NAD after 17 h of irradiation at 365 nm and at pH 6.6. Interestingly, pesticide photodegradation leads to the mineralization of substrates to H₂O and CO₂ and the photocatalyst can be recycled and reused without any loss of activity over four cycles.