The origin and fate of arsenic in coalbed natural gas-produced water ponds

Coalbed natural gas (CBNG)-produced water contains small amounts of trace metals that can accumulate over time in produced water retention ponds. Within the Powder River Basin (PRB) of Wyoming, high concentrations of trace metals in pond water and their effect on shallow groundwater are potential concerns. A pond with a maximum As concentration of 146 microg L(-1) was studied in detail to determine the potential for groundwater pollution and to explain the cause for the high concentration of As. Infiltration characteristics, subsurface hydrology, our fall and pond water quality, isotope signatures, and trace metal balances were examined to assess the hydrology and geochemistry of the pond. The results indicated minimum or no infiltration of pond water and no measurable contamination of the shallow groundwater. The high As concentrations in the pond were determined to be the result of semi-continuous inputs of CBNG-produced water with low As concentrations (0.20-0.48 microg L(-1)), exasperated by low pond volumes during drought conditions. Because of reduced infiltration and high evaporation rates, As became concentrated over time. Reduced infiltration was most likely caused by the high sodium concentration and high sodium adsorption ratio of the CBNG-produced water, which disrupt soil structure. The findings for the pond and the techniques used may serve as a template for future impact assessments of other CBNG-produced water ponds and are relevant for the approximately 4000 ponds currently permitted in the PRB and for future ponds. Further studies are recommended in the use of playa landforms to store marginal-quality produced water.     

Soil moisture‐based drought monitoring at different time scales: a case study for the U.S. Great Plains

Short‐term agricultural drought and longer term hydrological drought have important ecological and socioeconomic impacts. Soil moisture monitoring networks have potential to assist in the quantification of drought conditions because soil moisture changes are mostly due to precipitation and evapotranspiration, the two dominant water balance components in most areas. In this study, the Palmer approach to calculating a drought index was combined with a soil water content‐based moisture anomaly calculation. A drought lag time parameter was introduced to quantify the time between the start of a moisture anomaly and the onset of drought. The methodology was applied to four shortgrass prairie sites along a North‐South transect in the U.S. Great Plains with an 18‐year soil moisture record. Short time lags led to high periodicity of the resulting drought index, appropriate for assessing short‐term drought conditions at the field scale (agricultural drought). Conversely, long time lags led to low periodicity of the drought index, being more indicative of long‐term drought conditions at the watershed or basin scale (hydrological drought). The influence of daily, weekly, and monthly time steps on the drought index was examined and found to be marginal. The drought index calculated with a short drought lag time showed evidence of being normally distributed. A longer data record is needed to assess the statistical distribution of the drought index for longer drought lag times.