Soil sampling and analysis for volatile organic compounds

Concerns over data quality have raised many questions related to sampling soils for volatile organic compounds (VOCs). This paper was prepared in response to some of these questions and concerns expressed by Remedial Project Managers (RPMs) and On-Scene Coordinators (OSCs). The following questions are frequently asked:

1. Is there a specific device suggested for sampling soils for VOCs?
2. Are there significant losses of VOCs when transferring a soil sample from a sampling device (e.g., split spoon) into the sample container?
3. What is the best method for getting the sample from the split spoon (or other device) into the sample container?
4. Are there smaller devices such as subcore samplers available for collecting aliquots from the larger core and efficiently transferring the sample into the sample container?
5. Are certain containers better than others for shipping and storing soil samples for VOC analysis?
6. Are there any reliable preservation procedures for reducing VOC losses from soil samples and for extending holding times?

Guidance is provided for selecting the most effective sampling device for collecting samples from soil matrices. The techniques for sample collection, sample handling, containerizing, shipment, and storage described in this paper reduce VOC losses and generally provide more representative samples for volatile organic analyses (VOA) than techniques in current use. For a discussion on the proper use of sampling equipment the reader should refer to other sources (Acker, 1974; U.S. EPA, 1983; U.S. EPA, 1986a). Soil, as referred to in this report, encompasses the mass (surface and subsurface) of unconsolidated mantle of weathered rock and loose material lying above solid rock. Further, a distinction must be made as to what fraction of the unconsolidated material is soil and what fraction is not. The soil component here is defined as all mineral and naturally occurring organic material that is 2 mm or less in size. This is the size normally used to differentiate between soils (consisting of sands, silts, and clays) and gravels. Although numerous sampling situations may be encountered, this paper focuses on three broad categories of sites that might be sampled for VOCs:

1. Open test pit or trench.
2. Surface soils (<5 ft in depth).
3. Subsurface soils (>5 ft in depth).

     

Phytopumping for hydraulic control of an arsenic plume

Phytoremediation, the use of plants for in situ contaminant cleanup, is gaining new appreciation as an aesthetically pleasing, sustainable method that naturally makes use of solar power. Hybrid poplars are widely used because they grow rapidly and have high transpiration rates, making them advantageous for hydraulic control of groundwater. However, the tendency for trees and other vegetation to uptake metals may be a disadvantage in some settings due to potential redistribution of metals from groundwater to the ground surface. Therefore, a pilot test in the upper midwestern United States was implemented to evaluate the applicability of poplars to groundwater withdrawal and metals transport. © 2009 Wiley Periodicals, Inc.     

Nitrate and sediment fluxes from a California rangeland watershed

Long-term water quality records for assessing natural variability, impact of management, and that guide regulatory processes to safeguard water resources are rare for California oak woodland rangelands. This study presents a 20-yr record (1981-2000) of nitrate-nitrogen (NO(3)-N) and suspended sediment export from a typical, grazed oak woodland watershed (103 ha) in the northern Sierra Nevada foothills of California. Mean annual precipitation over the 20-yr period was 734 mm yr(-1) (range 366-1205 mm yr(-1)). Mean annual stream flow was 353 mm y(-1) (range 87-848 mm yr(-1)). Average annual stream flow was 48.1 +/- 16% of precipitation. Mean annual NO(3)-N export was 1.6 kg ha(-1) yr(-1) (range 0.18-3.6 kg ha(-1) yr(-1)). Annual NO(3)-N export significantly (P < 0.05) increased with increasing annual stream flow and precipitation. Mean daily NO(3)-N export was 0.004 kg ha(-1) d(-1) (range 10(-5) to 0.55 kg ha(-1) d(-1)). Mean annual suspended sediment export was 198 kg ha(-1) yr(-1) (range 23-479 kg ha(-1) yr(-1)). There was a positive relationship (P < 0.05) between annual suspended sediment export, annual stream flow and precipitation. Mean daily suspended sediment export was 0.54 kg ha(-1) d(-1) (range 10(-4) to 155 kg ha(-1) d(-1)). Virtually no sediment was exported during the dry season. The large variation in daily and annual fluxes highlights the necessity of using long-term records to establish quantitative water quality targets for rangelands and demonstrates the difficulty of designing a water quality monitoring program for these ecosystems.     

Farm factors associated with reducing Cryptosporidium loading in storm runoff from dairies

A systems approach was used to evaluate environmental loading of Cryptosporidium oocysts on five coastal dairies in California. One aspect of the study was to determine Cryptosporidium oocyst concentrations and loads for 350 storm runoff samples from dairy high use areas collected over two storm seasons. Selected farm factors and beneficial management practices (BMPs) associated with reducing the Cryptosporidium load in storm runoff were assessed. Using immunomagnetic separation (IMS) with direct fluorescent antibody (DFA) analysis, Cryptosporidium oocysts were detected on four of the five farms and in 21% of storm runoff samples overall. Oocysts were detected in 59% of runoff samples collected near cattle less than 2 mo old, while 10% of runoff samples collected near cattle over 6 mo old were positive. Factors associated with environmental loading of Cryptosporidium oocysts included cattle age class, 24 h precipitation, and cumulative seasonal precipitation, but not percent slope, lot acreage, cattle stocking number, or cattle density. Vegetated buffer strips and straw mulch application significantly reduced the protozoal concentrations and loads in storm runoff, while cattle exclusion and removal of manure did not. The study findings suggest that BMPs such as vegetated buffer strips and straw mulch application, especially when placed near calf areas, will reduce environmental loading of fecal protozoa and improve stormwater quality. These findings are assisting working dairies in their efforts to improve farm and ecosystem health along the California coast.     

Reproduction, larval development and functional relationships of the burrowing, spionid polychaete Dipolydora armata with the calcareous hydrozoan Millepora complanata

Dipolydora armata (Langerhans, 1880) is a small (4 to 5 mm) spionid polychaete found burrowing in the calcareous hydrozoan Millepora complanata Lamarck, 1816, on coral reefs at Barbados, West Indies. It excavates complex networks of interconnecting burrows and forms aggregations of worms in cavities within branches of the coral. Adult worms have a mixed feeding mode (suspension feeding and deposit feeding). Size–frequency distributions of worms in branch samples suggest that they mature in a single year and that reproduction occurs throughout the year. Burrow openings on the surface of the coral develop distinctive, erect spines caused by combined growth of worm tubes and host tissue. Millepore zooids were absent in the vicinity of tube openings and on spines, and thus the potential feeding surface of the coral will be reduced in heavily colonized branches. Burrows and openings were densest at the bases of millepore branches where weakening of the skeleton would be expected to occur. The absence of openings near the branch tips suggests difficulty in larval settlement there, amongst stinging zooids. Reproduction␣and larval development of the worms were examined, and a sequence of larval stages from one to 20 segments and a juvenile stage of 22 segments are described. Eggs are deposited in brood sacs attached to the burrow wall, and the larvae feed upon nurse eggs (adelphophagy). The presence of larvae and juveniles occurring free in the burrows suggests that larval development may be completed within the host coral as an alternative or in addition to a planktonic larval phase. Lack of provisional larval setae, early development of adult capillary setae, production of special spermatophores and a protracted breeding cycle in D. armata are all traits which would favour complete development within the host skeleton. Received: 6 March 1997 / Accepted: 25 October 1997