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1.
Treatment of pharmaceutical wastewater containing antibiotics by O3 and O3/H2O2 processes 总被引:15,自引:0,他引:15
Ozonation of three different synthetic pharmaceutical formulation wastewater containing two human antibiotics and a veterinary antibiotic has been studied to enhance the their biodegradability. The effects of pH and initial chemical oxygen demand (COD) value as well as addition of hydrogen peroxide on ozonation process were investigated. Total organic carbon (TOC), COD, biochemical oxygen demand (BOD), and aromatic content (UV254) were the parameters followed to evaluate the performance of ozonation process. Comparison of the biodegradability of selected wastewaters containing different antibiotics confirmed that the variation of biodegradability was associated with the target compound. While BOD5/COD ratio of veterinary antibiotic formulation wastewater was increased from 0.077 to 0.38 with an applied ozone dosage of 2.96 g/l, this ratio for human antibiotic I and human antibiotic II was increased from 0 to 0.1 and 0.27 respectively. Moreover the results of this investigation showed that the ozonation process is capable of achieving high levels of COD and aromaticity removals at about their natural pH values. 相似文献
2.
Objective This study was done to estimate whether heavy metals in the air may affect endometrial chemical composition.
Materials and Methods A total of 30 albino Wistar rats were employed and randomly divided into three groups. The rats of Group 1 and 2 were acutely
and sub-chronically exposed to the gas form of heavy metals, respectively. Group 3 was used as a control group. Endometrial
tissue worth of heavy metals of the groups was measured in through using scanning electron microscope.
Results A statistically no significant difference was found for endometrial chemical composition of all of the heavy metals (chrome,
manganese, iron, cobalt, nickel, zinc and lead) between group 1 and 2 (p > 0.05). On the other hand, there was statistically significant difference for all of the heavy metals between group 1 and
group 3 (p < 0.05), while there was statistically significant difference for chrome, manganese, iron, cobalt and nickel (p < 0.05), but zinc and lead (p > 0.05) between group 2 and 3.
Conclusion Air pollutants of Pb and Zn resulting mostly from combustion of fossil fuels and certain special industrial process in Kirikkale
may be a risk factor for the high pregnancy loses by changing endometrial homeostasis. 相似文献
3.
Deniz Demirbilek Ayten Öztüfekçi Önal Veysel Demir Gulsad Uslu Hilal Arslanoglu-Isık 《Environmental monitoring and assessment》2013,185(11):9435-9449
Environmental monitoring of leachate quality from an open municipal solid waste dumping site in Tunceli, Turkey was studied in this research. The most commonly examined pollution parameters were determined on a seasonal basis. The annual average 5-day biological oxygen demand (BOD5) and chemical oxygen demand (COD) values of station points were measured as 70 and 425 mg/L, respectively, and also the average BOD5/COD ratio (a measure of biodegradability) was calculated as 0.20. The low ratio of biodegradability and slightly alkaline pH values in the leachate samples indicated that the site was characterized by methanogenic conditions. The mean ammonium-nitrogen (NH4 +-N) and corresponding phosphate (orthophosphate) values were assayed as 70 and 11 mg/L, respectively. The average solids content in the leachates was measured as 4,681 mg/L (total solids) and 144 mg/L (suspended solids). Very low concentrations of iron, manganese, copper, and zinc in the leachate samples were found and the concentration of cadmium was measured below detection limits. Excessive amount of nutrients and high organic and inorganic pollutant content in the leachates pose serious pollution potential to the environment. Since no drainage system or bio treatment exists in this open dumping site, high permeability of natural soil at the site and in the surrounding area and very fractured and crackled rocks under natural soil are indicators of high groundwater pollution potential in this site. 相似文献
4.
Orhon D Uslu O Meriç S Salihoglu I Filibeli A 《Environmental pollution (Barking, Essex : 1987)》1994,84(2):167-178
A number of studies have so far been conducted to assess the magnitude of pollution generated by domestic and industrial sources in the Istanbul Metropolitan Area. They indicate that a management scheme for wastewater treatment and disposal should involve a total discharge of 15.4 m3 s(-1) with a potential pollution load of 330 tons BOD5 day(-1) for 1990. A scheme of this magnitude inevitably requires careful evaluation of receiving water characteristics, both from an oceanographic and a quality standpoint. In this paper significant water quality parameters related to the Black Sea-Bosphorus Strait-Marmara Sea System are reviewed and incorporated in the evaluation of treatment and disposal alternatives. In this context, the pollution exchange between the Mamara Sea and Bosphorus is quantified, pollutant contents of the Mamara Sea and discharges from the Istanbul Metropolitan Area are compared, and a number of scenarios are evaluated to define the optimum treatment and disposal strategy. 相似文献
5.
Murat Cengiz Merih Otker Uslu Isil Balcioglu 《Journal of environmental management》2010,91(12):2590-2593
The destruction of antibiotic-resistant microorganisms at the source of contamination is necessary due to their adverse effects and to their increasingly widespread occurrence in the environment. To address this problem, Fenton and ozone oxidation processes were applied to synthetically contaminated cow manure to remove the tetM gene and its host, Escherichia coli HB101. The efficiency of the processes was evaluated by enumeration of E. coli HB101 and by PCR amplification of the tetM gene. The results of this study show that 56.60% bacterial inactivation (corresponding to a 0.36 log reduction) was achieved by a Fenton reagent dose of 50 mM H2O2 and 5 mM Fe2+ without acidifying the manure. Despite the high organic content of cow manure, 98.50% bacterial inactivation (corresponding to a 1.83 log reduction) was obtained by the ozonation process with an applied dose of 3.125 mg ozone/g manure slurry. The PCR study revealed that the band intensity of the tetM gene gradually decreased by increasing the Fenton reagent and the applied ozone dose. However, significantly high doses of oxidants would be required to completely eliminate bacterial pollution in manure. 相似文献
6.
Çıtak Ferhat Uslu Hakan Batmaz Oğuzhan Hoş Safa 《Environmental science and pollution research international》2021,28(45):63739-63750
Environmental Science and Pollution Research - This article attempts to explore the asymmetric impact of renewable energy and natural gas consumptions on CO2 emissions for the selected ten most... 相似文献
7.
A simple, fast, and low-cost analytical procedure was developed for trace-level determination of inorganic vanadium species by dispersive liquid–liquid microextraction in combination with spectrophotometry. Vanadium in pentavalent form, V(V), was quantitatively extracted into organic phase as 4-(2-pyridylazo)-recorcinol (PAR) complex in the presence of N-cetyl-N,N,N-trimethyl ammonium bromide (CTAB) as counter-ion. Vanadium (IV) was masked with 1,2-diaminocyclohexanetetraacetic acid to allow speciation analysis. Total vanadium was determined after oxidation of V(IV) to V(V). The main factors affecting preconcentration and spectrophotometric detection of vanadium species such as pH, concentration of PAR and CTAB, the type and volume of the extraction, and disperser solvents were optimized. The limit of detection and enhancement factor obtained under optimum conditions were found to be 0.06 μg L?1 and 98, respectively. Relative standard deviations for V(IV) and V(V) at 3.0 μg L?1 were less than 2.4%. The presented procedure was applied to environmental water samples for selective determination of vanadium species. Moreover, the method was applied to determination of vanadium in edible salt samples, due to its applicability in high-NaCl-containing solutions. The validity of proposed method was proven by spike recovery experiments and also independent analysis by inductively coupled plasma mass spectrometry. 相似文献
8.
The fatty acid compositions of several plant seed oils belong to Leguminosae and Umbelliferae families 总被引:1,自引:0,他引:1
Meryem Öztürk Ümit Geçgel Ahmet Duran Nurhan Uslu Mehmet Musa Özcan 《Environmental monitoring and assessment》2014,186(5):2795-2799
In samples with 1,009, 7,723, 7,618, 7,618, 1,004 and 1,009 number, oleic acid were found as 62.0, 77.0, 74.84, 71.55, 54.52 and 62.30 %, respectively. In other samples, oleic acid content was determined between 17.43 % (1,589) and 34.86 % (1,298). Linoleic acid content of seed oils ranged from 6.52 % (7,727) to 57.29 % (1,501). In addition, linolenic acid content was found between 0.22 % (7,618) and 46.91 % (1,589). Palmitic acid content of samples changed between 2.03 % (7,727) and 19.81 % (1,298). Capric acid was found at high level in 1,009 (8.53 %), 7,727 (37.31 %) and 1,004 (8.28 %) samples. Caproic acid was found in only 7,727 (3.38 %). 相似文献
9.
Rasime Demirel Burhan Sen Duygu Kadaifciler Aysegul Yoltas Suzan Okten Evrim Ozkale Derya Berikten Robert A. Samson Alev Haliki Uztan Neriman Yilmaz Ozlem Abaci Gunyar Halide Aydogdu Ahmet Asan Merih Kivanc Soner Ozdil Erhan Sakartepe 《Environmental monitoring and assessment》2017,189(7):362
Pathogenic and/or opportunistic fungal species are major causes of nosocomial infections, especially in controlled environments where immunocompromised patients are hospitalized. Indoor fungal contamination in hospital air is associated with a wide range of adverse health effects. Regular determination of fungal spore counts in controlled hospital environments may help reduce the risk of fungal infections. Because infants have inchoate immune systems, they are given immunocompromised patient status. The aim of the present study was to evaluate culturable airborne fungi in the air of hospital newborn units in the Thrace, Marmara, Aegean, and Central Anatolia regions of Turkey. A total of 108 air samples were collected seasonally from newborn units in July 2012, October 2012, January 2013, and April 2013 by using an air sampler and dichloran 18% glycerol agar (DG18) as isolation media. We obtained 2593 fungal colonies comprising 370 fungal isolates representing 109 species of 28 genera, which were identified through multi-loci gene sequencing. Penicillium, Aspergillus, Cladosporium, Talaromyces, and Alternaria were the most abundant genera identified (35.14, 25.40, 17.57, 2.70, and 6.22% of the total, respectively). 相似文献
10.