Comparison of field-scale herbicide runoff and volatilization losses: an eight-year field investigation

An 8-yr study was conducted to better understand factors influencing year-to-year variability in field-scale herbicide volatilization and surface runoff losses. The 21-ha research site is located at the USDA-ARS Beltsville Agricultural Research Center in Beltsville, MD. Site location, herbicide formulations, and agricultural management practices remained unchanged throughout the duration of the study. Metolachlor [2-chloro--(2-ethyl-6-methylphenyl)--(2-methoxy-1-methylethyl) acetamide] and atrazine [6-chloro--ethyl--(1-methylethyl)-1,3,5-triazine-2,4-diamine] were coapplied as a surface broadcast spray. Herbicide runoff was monitored from a month before application through harvest. A flux gradient technique was used to compute volatilization fluxes for the first 5 d after application using herbicide concentration profiles and turbulent fluxes of heat and water vapor as determined from eddy covariance measurements. Results demonstrated that volatilization losses for these two herbicides were significantly greater than runoff losses ( < 0.007), even though both have relatively low vapor pressures. The largest annual runoff loss for metolachlor never exceeded 2.5%, whereas atrazine runoff never exceeded 3% of that applied. On the other hand, herbicide cumulative volatilization losses after 5 d ranged from about 5 to 63% of that applied for metolachlor and about 2 to 12% of that applied for atrazine. Additionally, daytime herbicide volatilization losses were significantly greater than nighttime vapor losses ( < 0.05). This research confirmed that vapor losses for some commonly used herbicides frequently exceeds runoff losses and herbicide vapor losses on the same site and with the same management practices can vary significantly year to year depending on local environmental conditions.     

ENERGY BALANCE OF A CORN RESIDUE-COVERED FIELD DURING SNOWMELT1

ABSTRACT: Transport of agricultural chemicals in runoff and recharge waters from snowmelt and soil thawing may represent a significant event in terms of annual contaminant loadings in temperate regions. Improved understanding of the melt dynamics of shallow snowpacks is necessary to fully assess the implications for water quality. The objective of this study was to measure the energy balance components of a corn (Zea mays L.) stubble field during the melting of its snowcover. Net radiation (Rn), soil (G), sensible (H), and latent (Q) heat fluxes were measured in a field near Ames, Iowa, during the winter of 1994–1995. Energy consumed by melting including change in energy storage of the snowpack was determined as the residual of the measured energy balance. There was continuous snowcover at the field site for 71 days (maximum depth = 222 mm) followed by an open period of 11 days before additional snowfall and a second melt period. The net radiation and snow melt/energy storage change (5) terms dominated the energy balance during both measurement intervals. Peak daily sensible and latent heat fluxes were below 100 W m^?2 on all days except the last day of the second melt period. There was good agreement between predicted and measured values of H and Q during the melting of an aged snow layer but poorer agreement during the melt of fresh snow. Both snowpacks melted rapidly and coincident changes in soil moisture storage were observed. Improved estimates of Q and H, especially for partially open surfaces, will require better characterization of the surface aerodynamic properties and spatially-representative surface temperature measurements.