Endosulfan transport: I. Integrative assessment of airborne and waterborne pathways

To reduce endosulfan (C9H6O3Cl6S; 6,7,8,9,10,10-hexachloro-1,5, 5a,6,9,9a-hexahydro-6,9-methano-2,4,3-benzodioxathiepin 3-oxide) contamination in rivers and waterways, it is important to know the relative significances of airborne transport pathways (including spray drift, vapor transport, and dust transport) and waterborne transport pathways (including overland and stream runoff). This work uses an integrated modeling approach to assess the absolute and relative contributions of these pathways to riverine endosulfan concentrations. The modeling framework involves two parts: a set of simple models for each transport pathway, and a model for the physical and chemical processes acting on endosulfan in river water. An averaging process is used to calculate the effects of transport pathways at the regional scale. The results show that spray drift, vapor transport, and runoff are all significant pathways. Dust transport is found to be insignificant. Spray drift and vapor transport both contribute low-level but nearly continuous inputs to the riverine endosulfan load during spraying season in a large cotton (Gossypium hirsutum L.)-growing area, whereas runoff provides occasional but higher inputs. These findings are supported by broad agreement between model predictions and observed typical riverine endosulfan concentrations in two rivers.     

Toxic Effect of a Pesticide, Diflubenzuron on Freshwater Microinvertebrate (Tetrahymena pyriformis)

Harmful bugs affect food production,directly by the qualitativeor quantitative reduction of the harvests,or indirectly while servinglike vectors of several illnesses of the plants and human[1].Many chemical products are used by human for a long time inthe…     

Development and testing of a micro wind tunnel for on-site wind erosion simulations

Wind erosion processes affect soil surfaces across all land uses worldwide. Understanding the spatial and temporal scales of wind erosion is a challenging undertaking because these processes are diverse and highly variable. Wind tunnels provide a useful tool as they can be used to simulate erosion at small spatial scales. Portable wind tunnels are particularly valued because erosion can be simulated on undisturbed soil surfaces in the field. There has been a long history of use of large portable wind tunnels, with consensus that these wind erosion simulation tools can meet real world aerodynamic criteria. However, one consequence of striving to meet aerodynamic reality is that the size of the tunnels has increased, making them logistically difficult to work with in the field and resulting in a tendency to homogenise naturally complex soil surfaces. This homogenisation is at odds with an increasing awareness of the importance that small scale processes have in wind erosion. To address these logistical and surface homogenisation issues we present here the development and testing of a micro wind tunnel (MWT) designed to simulate wind erosion processes at high spatial resolution. The MWT is a duct-type design—0.05 m tall 0.1 m wide and with a 1.0 m working section. The tunnel uses a centrifugal motor to suck air through a flow‐conditioning section, over the working section and then through a sediment collection trap. Simulated wind velocities range from 5 to 18 m s^?1, with high reproducibility. Wind speeds are laterally uniform and values of u _* at the tunnel bed (calculated by measuring the pressure gradients within the MWT) are comparable with those of larger tunnels in which logarithmic profiles can be developed. Saltation sediment can be added. The tunnel can be deployed by a single person and operated on slopes ranging from 0 to 10°. Evidence is presented here that the MWT provides new and useful understanding of the erodibility of rangelands, claypans and ore stockpiles.     

Analysis of polychlorobiphenyls from used transformers for polychlorodibenzofurans

The results of analyses for polychlorodibenzofuran (PCDF) content in two samples of polychlorobiphenyl (PCB) from used electrical transformers are presented and discussed. In neither sample was there evidence for enhanced PCDF concentrations even though one of them had been subjected to overheating while in service.     

Polychlorodibenzo-p-dioxins and dibenzofurans in technical pentachlorophenol - results of a collaborative analytical exercise

Results of analyses of eight samples of technical pentachlorophenol conducted by three different analytical methods are presented and discussed.     

Genetic homogeneity and circum-Antarctic distribution of two benthic shrimp species of the Southern Ocean, Chorismus antarcticus and Nematocarcinus lanceopes

During the last years, molecular studies revealed significant population differentiation and cryptic species within various benthic and pelagic marine Antarctic taxa. This is unexpected due to the lack of obvious barriers to gene flow and strong current systems. Using mitochondrial (COI, 16S rDNA) and nuclear (28S rDNA: D2) gene fragments, we tested whether two circum-Antarctic benthic shrimps with planktotrophic larvae, Chorismus antarcticus and Nematocarcinus lanceopes, show patterns of regional differentiation. For both species, the 16S and the 28S fragment were invariant. However, for COI we found 24 different haplotypes for Chorismus antarcticus and 54 for Nematocarcinus lanceopes. No significant differentiation was observed among populations or regions. Furthermore, we found signatures of a population expansion in the late Pleistocene hinting at an impact of large-scale glaciations in particular on the shallow-water shrimp Chorismus antarcticus, supporting a (re)colonization and demographic expansion of this shrimp species in response to climate oscillation.     

Long term changes in polychlorodibenzo-p-dioxin concentrations in wood treated with technical pentachlorophenol

Wood samples treated with technical pentachlorophenol (PCP), technical sodium pentachlorophenoxide (NaPCP) and octachlorodibenzo-p-dioxin have been exposed outdoors for periods up to $\text{2}\text{1}\text{2}$ years. Analysis of extracts from the samples show that photolytic reductive dechlorination of highly chlorinated dibenzo-p-dioxins to less chlorinated isomers occurs. However there is no discernible increase in polychlorodibenzo-p-dioxin concentrations in the technical PCP treated wood presumably because further photolytic reactions and volatilisation compete effectively with the photolytic formation. There is no evidence for formation of octachlorodibenzo-p-dioxin (OCDD) in technical PCP treated wood in this study, probably because photolytic destruction and volatilisation compete effectively with formation reactions when the initial OCDD concentration is relatively high.