Phthalates and the aquatic environment: Part II The bioconcentration and depuration of di-2-ethylhexyl phthalate (DEHP) and di-isodecyl phthalate (DIDP) in mussels (Mytilus edulis)

Mussels ($\text{Mytilus edulis}$) were exposed to di-2-ethylhexyl phthalate (DEHP) and to di-isodecyl phthalate (DIDP) over a period of 28 days. The bioconcentration factor (BCF) as measured by ¹⁴C analysis, reached estimated plateau levels corresponding to mean BCF values of approximately 2500 and 3500 for the DEHP and DIDP respectively. The mussels were then held in clean seawater for a further 14 days and ¹⁴C analysis showed a depuration half-life of approximately 3.5 days for both phthalates. During the whole 42 days of the experiment general observations on the health of the animals showed no evidence of any adverse effects.     

Structural characteristics of post-wildfire and clearcut landscapes

A continuing discussion in the field of ecology and forest management concerns the implications of clearcutting as a functional replacement for wildfire in disturbance-driven ecosystems. At the landscape level, spatial pattern has been shown to influence many ecologically important processes. Satellite imagery allows the evaluation of structural patterns created by alternative forest management activities at broad scales. In Northwestern Ontario, both clearcutting and wildfire have occurred over large contiguous areas. Spatial characteristics including composition, patch size, patch shape, and interspersion were calculated from classified Landsat Thematic Mapper (TM) data at two thematic scales and used to compare post-wildfire and clearcut landscapes. Patches in the clearcut landscape were found to be larger in size, and had a more irregular shape than those in the wildfire landscape. Differences in landscape structure were much more pronounced at broad scales than at fine thematic scales.     

Spatial modeling of harvest constraints on wood supply versus wildlife habitat objectives

We studied the effects of spatial and temporal timber harvesting constraints on competing objectives of sustaining wildlife habitat supply and meeting timber harvest objectives in a boreal mixedwood forest. A hierarchical modeling approach was taken, where strategic and tactical level models were used to project blocking and scheduling of harvest blocks. Harvest block size and proximity, together with short- and long-term temporal constraints, were adjusted in a factorial manner to allow creation of response-surface models. A new measure of the habitat mosaic was defined to describe the emergent pattern of habitat across the landscape. These models, together with multiple linear regression, were used to provide insight on convergence or divergence between spatial objectives. For example, green-up delay (defined as time required before a harvest block adjacent to a previously logged block can be scheduled for harvest) had an adverse effect on the amount of annual harvest area that could be allocated and blocked spatially, and habitat supply responded in an opposite direction to that of wood supply, where caribou, moose wintering, and marten habitat supply increased when harvest blocks were further apart, maximum block size smaller, and both a green-up delay and mesoscale stratification were applied. Although there was no "solution space" free of conflicts, the analysis suggests that application of the mesoscale stratification, together with a diversity of harvest block sizes and a between-harvest block proximity of 250 m, will perform relatively well with respect to wood supply objectives, and at the same time create a less fragmented landscape that better reflects natural forest patterns.     

Overhead drilling: Comparing three bases for aligning a drilling jig to vertical

Problem

Drilling overhead into concrete or metal ceilings is a strenuous task done by construction workers to hang ductwork, piping, and electrical equipment. The task is associated with upper body pain and musculoskeletal disorders. Previously, we described a field usability evaluation of a foot lever and inverted drill press intervention devices that were compared to the usual method for overhead drilling. Both interventions were rated as inferior to the usual method based on poor setup time and mobility.

Method

Three new interventions, which differed on the design used for aligning the drilling column to vertical, were compared to the usual method for overhead drilling by commercial construction workers (n = 16).

Results

The usual method was associated with the highest levels of regional body fatigue and the poorest usability ratings when compared to the three interventions.

Conclusion

Overall, the 'Collar Base' intervention design received the best usability ratings.

Impact on Industry

Intervention designs developed for overhead drilling may reduce shoulder fatigue and prevent subsequent musculoskeletal disorders. These designs may also be useful for other overhead work such as lifting and supporting materials (e.g., piping, ducts) that are installed near the ceiling. Workplace health and safety interventions may require multiple rounds of field-testing prior to achieving acceptable usability ratings by the end users.     

The development and application of remote sensing to monitor sand dune habitats

Sand dunes are complex systems that contain several habitats, often as mosaics or transitions between types. Several of these habitats are afforded protection under European Legislation and in the UK nationally within Special Areas of Conservation (SAC) and Sites of Special Scientific Interest (SSSI). Natural England has a statutory duty to report to Europe on the conservation status and condition of sand dunes; and is required to report to the UK Government on designated sites. To achieve this we have sought ways of capturing, analysing and interpreting data on the extent and location of sand dune habitats. This requires an ability to be able to obtain data over large areas of coastline in an efficient way. Natural England and Environment Agency Geomatics have worked collaboratively for over 16 years, sharing data and ecological knowledge. In 2012 work started to evaluate the use of remote sensing to map UK BAP and Annex I sand dune habitats. A methodology has now been developed and tested to map sand dune habitats. The key objective was to provide an operational tool that will help to map these habitats and understand change on sites around England. This has been achieved through analysis of LIDAR and Compact Airborne Spectrographic Imager (CASI) data using Object Orientated Image Analysis. Quality Control (QC) and accuracy assessments have shown this approach to be successful and 11 sites have been mapped to date. These techniques are providing a new approach to monitoring change in coastal vegetation communities and informing management of protected sites.     

Cross-sectional biomonitoring study of pesticide exposures in Queensland,Australia, using pooled urine samples

A range of pesticides are available in Australia for use in agricultural and domestic settings to control pests, including organophosphate and pyrethroid insecticides, herbicides, and insect repellents, such as N,N-diethyl-meta-toluamide (DEET). The aim of this study was to provide a cost-effective preliminary assessment of background exposure to a range of pesticides among a convenience sample of Australian residents. De-identified urine specimens stratified by age and sex were obtained from a community-based pathology laboratory and pooled (n = 24 pools of 100 specimens). Concentrations of urinary pesticide biomarkers were quantified using solid-phase extraction coupled with isotope dilution high-performance liquid chromatography–tandem mass spectrometry. Geometric mean biomarker concentrations ranged from <0.1 to 36.8 ng/mL for organophosphate insecticides, <0.1 to 5.5 ng/mL for pyrethroid insecticides, and <0.1 to 8.51 ng/mL for all other biomarkers with the exception of the DEET metabolite 3-diethylcarbamoyl benzoic acid (4.23 to 850 ng/mL). We observed no association between age and concentration for most biomarkers measured but noted a “U-shaped” trend for five organophosphate metabolites, with the highest concentrations observed in the youngest and oldest age strata, perhaps related to age-specific differences in behavior or physiology. The fact that concentrations of specific and non-specific metabolites of the organophosphate insecticide chlorpyrifos were higher than reported in USA and Canada may relate to differences in registered applications among countries. Additional biomonitoring programs of the general population and focusing on vulnerable populations would improve the exposure assessment and the monitoring of temporal exposure trends as usage patterns of pesticide products in Australia change over time.