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排序方式: 共有55条查询结果,搜索用时 15 毫秒
1.
TPH-contaminated Mexican Refinery Soil: Health Risk Assessment and the First Year of Changes 总被引:4,自引:0,他引:4
Iturbe R Flores RM Flores CR Torres LG 《Environmental monitoring and assessment》2004,91(1-3):237-255
The soil of a coastal Mexican refinery is quite contaminated, especially by hydrocarbons, with detected concentrations up to 130000 mg kg(-1) as TPHs (total petroleum hydrocarbons). The main sources of contamination are pipelines, valves, and old storage tanks, besides the land disposal of untreated hydrocarbon sediments derived from the cleaning of storage tanks. A health risk assessment (HRA) was carried out in order to measure the risk hazard indexes and clean-up standards for the refinery soil. HRA suggested the following actions to be taken: benzene concentrations must be reduced in eight of the 16 studied refinery zones to 0.0074-0.0078 mg kg(-1). Also, vanadium concentration must be reduced in two zones up to a concentration of 100 mg kg(-1). In only one of all of the studied zones, benzo(a)pyrene concentration must be reduced to 0.1 mg kg(-1). After 1 yr, TPHs showed a diminution of about 52%. Even though TPHs concentrations were variable, during 1999 the average concentrations were as much as 15.5 times the goal concentration. For year 2000, TPHs concentrations were only 7.4-fold the proposed value. For the 1999-2000 period, PAHs (polycyclic aromatic hydrocarbons) concentrations decreased by 82%. Some PAHs with 2, 3, 4, and 5 aromatic rings were removed up to 100% values. 相似文献
2.
Hijano CF Domínguez MD Gimínez RG Sínchez PH García IS 《Environmental monitoring and assessment》2005,111(1-3):75-88
The evaluation of certain vascular plants that grow in the city of Madrid as biomonitors of SO2 air pollution in urban environments has been carried out. Total concentration of sulphur in leaves of the chosen higher plants
as well as other parameters in close relation to this contaminant (visible injury symptoms, chlorophyll a- and b-content and
peroxidase activity) have been determined in order to study the spatial distribution and temporal changes in SO2 deposition. Results obtained show that coniferous species such as Pinus pinea, were more sensitive to SO2 atmospheric concentration than leafy species as Quercux ilex subspecies ballota and, in the same way, bush species, such asPyracantha coccinea and Nerium oleander, were more sensitive than wooded species, such as Cedrus deodaraandPinus pinea, respectively. There is a higher accumulation of sulphur in vegetable species located near highways and dense traffic incidence
roads and near areas with high density of population. The minimum values for accumulation of SO2 were registered in winter and spring seasons (from January to April) due to the vegetative stop; while maximum values are
obtained during the summer season (from June to September), due to the stoma opening. The highest increments in sulphur concentration,
calculated as the difference between two consecutive months, are obtained in May and June for all considered species except
forCedrus deodara and Pyracantha coccinea, both species have few seasonal changes during the whole year. Some species are more sensitive to natural washing than others,
showing a decrease in sulphur concentration after rainfall periods. 相似文献
3.
Laboratory-scale studies were aimed at elucidating the physico-chemical aspects on the removal process of crystal violet (CV) from waters and solid substrates. The laponite clay (RD) and sand were chosen for the double aim at investigating them as CV adsorbents for water treatment and as substrates which mime the soil components. Sand is very effective in removing CV from waters. The cyclodextrins (CDs) were exploited as solubility-enhancement agents to remove CV from the solid substrates. They are powerful solvent media because they extract the CV from sand forming water-soluble CV/CD inclusion complexes and do not show affinity for sand. Optimum performance was shown by the modified CDs (i.e. hydroxypropyl-β-cyclodextrin and methyl-β-cyclodextrin). A linear correlation between the logarithm of the equilibrium constant for the CV/CD inclusion complexes formation (Kcpx) and the maximum amount of CV extracted from sand in the columns experiments at a flow rate of 1.5 ml min−1 was drawn. This relationship predicts that CDs with Kcpx < 180 M−1 are not suitable for CV removal from sand. CDs failed to displace CV from RD because they generate the formation of RD clusters where CV remains entrapped. 相似文献
4.
Oil spills due to oil pipelines is a very frequent problem in Mexico. Petroleos Mexicanos (PEMEX), very concerned with the
environmental agenda, has been developing inspection and correction plans for zones around oil pipelines pumping stations
and pipeline right-of-way. These stations are located at regular intervals of kilometres along the pipelines. In this study,
two sections of an oil pipeline and two pipeline pumping stations zones are characterized in terms of the presence of Total
Petroleum Hydrocarbons (TPHs) and Polycyclic Aromatic Hydrocarbons (PAHs). The study comprehends sampling of the areas, delimitation
of contamination in the vertical and horizontal extension, analysis of the sampled soils regarding TPHs content and, in some
cases, the 16 PAHs considered as priority by USEPA, calculation of areas and volumes contaminated (according to Mexican legislation,
specifically NOM-EM-138-ECOL-2002) and, finally, a proposal for the best remediation techniques suitable for the contamination
levels and the localization of contaminants. 相似文献
5.
Stefano Grigolato Omar Mologni Andrea Rosario Proto Giuseppe Zimbalatti Raffaele Cavalli 《Environmental monitoring and assessment》2018,190(2):88
The use of helicopter rises discussion about environmental noise propagation especially when it operates in proximity of environmentally sensitive areas (ESAs) for an extended period because of its potential implications in wildlife behaviours. In order to support decisions on helicopter logging operation management in proximity of ESAs, this study focused on (i) analysing the noise spectrum of a light-lift helicopter during logging operations and on (ii) assessing the noise propagation in the surrounding environments. This study investigated a helicopter logging operation for wood fuel extraction in the eastern part of the Italian Alps. The potential disturbance area covered for the entire helicopter logging operation was evaluated by a specific GIS application according to hearing sensitivity of the most sensitive wildlife species in the study area (different strigiform species). The noise level at the ground appeared to be affected by the location regardless both the use of equivalent continuous sound pressures level dB(A) (LAeq) and the single-event level (SEL) noise metrics. The lowest values were recorded when the helicopter was flown over the sound meter level located under the forest canopy, while the highest was recorded when the helicopter was unhooking the loads at the landing. The GIS application highlighted the consistent of the exceeded noise area (weighted to strigiform hearing range and sensitivity) for the lower frequency bands (0.016–0.250 kHz). A more restricted exceeded noise area concerned instead the most sensitive frequency bands" for the strigiform (1–2 kHz). 相似文献
6.
Carolina Fernández-Ramos Oscar Ballesteros Alberto Zafra-Gómez Francisco Javier Camino-Sánchez Rosario Blanc Alberto Navalón José Luís Vílchez 《Environmental science and pollution research international》2014,21(6):4286-4296
The study describes the environmental monitoring of anionic surfactants―alcohol sulfates (AS) and alcohol ethoxysulfates (AES)—in marine sediments. Concentration values were obtained after pressurised liquid extraction (PLE) and liquid chromatography–tandem mass spectrometry analysis (LC–MS/MS). Samples were collected from a range of wastewater discharge points along the coast of the provinces of Huelva, Málaga, Granada and Almería. Urban, agricultural and industrial wastewaters are discharged at the selected 38 sampling sites. Principal component analysis was carried out in order to evaluate the distribution and behaviour of these compounds in these coastal environments. Evaluation of the data revealed that the behaviour and sources of AS and AES in marine sediments are different, and that the distribution of AES depends on the length of the alkyl chain, while the number of ethoxylated units is not relevant. Additionally, the 38 sampling sites can be grouped into only two types of outfalls according to their AS distribution. The concentration of compounds in sediment samples ranged from 7.52 to 13.50 mg kg?1 for AS, from 3.04 to 10.68 mg kg?1 for AES–C12Ex and from 3.83 to 11.56 mg kg?1 for AES–C14Ex. 相似文献
7.
Juan José Cabello Dunia Garcia Alexis Sagastume Rosario Priego Luc Hens Carlo Vandecasteele 《Environment, Development and Sustainability》2012,14(4):573-591
This paper analyzes the Cuban model of sustainable development and explains the causes that made Cuba the only country that meets the conditions of sustainability according to the Worldwide Fund for Nature (WWF). The Human Development Index has three main components: quality of life (health indicator measured as life expectancy at birth), knowledge (education indicator measured as adult literacy) and the standard of life (economic indicator measured by the Gross Domestic Income). This paper analyses the aspects of the educational and health system of Cuba and also of its energy policies that explain the excellent scores of the Human Development Index. Cuba shows a Human Development Index of 0.8 with an Ecological Footprint of 1.8?gha. This is achieved with a Gross Domestic Income lower than other countries with similar Human Development Index. The Ecological Footprint of Cuba is mainly determined by the CO2 and the agricultural land footprint. The paper shows how the economic transition, after the economic crisis of the early 1990s, was realized without significantly increasing the Ecological Footprint. 相似文献
8.
Soil and groundwater contamination due to petroleum hydrocarbon spills is a frequent problem worldwide. In Mexico, even when programs oriented to the diminution of these undesirable events exist, in 2000, a total of 1,518 petroleum spills were reported. Exploration zones, refineries, and oil distribution and storage stations frequently are contaminated with total petroleum hydrocarbons (TPH); diesel fraction; gasoline fraction; benzene, toluene, ethyl benzene, and xylenes (BTEX); and polycyclic aromatic hydrocarbons (PAHs). Among the many methodologies available for the treatment of this kind of contaminated soil, bioremediation is the most favorable, because it is an efficient/low‐cost option that is environmentally friendly. This article discusses the capability of using a biopile to treat soils contaminated with about 40,000 mg/kg of TPH. Design and operation of a 27‐m3 biopile is described in this work, including microbiological and respirometric aspects. Parameters such as TPH, diesel fraction, BTEX, and PAHs considered by the U.S. Environmental Protection Agency were measured in biopile samples at 0, 2, 4, 6, 8, 10, and 22 weeks. A final average TPH concentration of 7,300 mg/kg was achieved in 22 weeks, a removal efficiency of 80 percent. © 2007 Wiley Periodicals, Inc. 相似文献
9.
Rosario Iturbe Carlos Flores Claudia Chvez Adriana Ramírez Luis G. Torres 《补救:环境净化治理成本、技术与工艺杂志》2004,14(2):141-152
This article demonstrates the applicability of in situ flushing for the remediation of soil contaminated with petroleum hydrocarbons at a Mexican refinery. The initial average total petroleum hydrocarbon (TPH) concentration for the demonstration field test was 55,156 g/kg. After six weeks of in situ flushing with alternate periods of water and water/surfactant, an average concentration of 1,407 mg/kg was reached, achieving a total removal efficiency of 98 percent. At the end of the process, no hydrocarbons such as diesel; gasoline; benzene, toluene, ethyl benzene, and xylene (BTEX); or petroleum aromatic hydrocarbons (PAHs) were found. Iron washing achieved a removal efficiency of 70 percent, and for vanadium, the removal efficiency was 94.4 percent. The volume of soil treated was 41.6 m3 (38 m2), equivalent to 69.5 tons of soil. A rough calculation of the process costs estimated a total cost of $104.20/m3 ($114.00/m2). Our research indicates that there are a few studies demonstrating in situ flushing experiences under field conditions where both organic (TPH, diesel, gasoline, PAHs, BTEX) and metal (iron and vanadium) removals are reported. © 2004 Wiley Periodicals, Inc. 相似文献
10.
Rosario Perez Espejo 《Environment, Development and Sustainability》2006,8(3):391-411
The objective of this article is to address the environmental costs of pig farms in the La Piedad region Mexico, through an
analysis of the standard on wastewater discharges to national water bodies. Field work was carried out from April to September
1999; a survey was conducted on 23 farms and samples of wastewater were taken on 11 farms. Pig production is the third most
important system in Mexican livestock production. Heterogeneity in production systems, dependence on imported inputs (genetics
and feed grains), and weak internalization of environmental costs are the main characteristics of pig production in Mexico.
With no specific environmental regulations on intensive livestock activities at the municipal or state levels, Mexican Official
Standard 001 on wastewater discharges is the only environmental obligation that pig farms must meet. Standard 001 on wastewater
contains the maximum permissible limits for 20 contaminant parameters, and is based on a cost-benefit analysis that points
to secondary treatment for the regulation’s economic viability. Investment in treatment systems and the fees that pig producers
must pay when they fail to comply with the limits stipulated in the regulation, are estimated assessed as an approach to environmental
costs. In order to remain within the limits in the standard, pig farms must invest in tertiary treatment, and that makes meeting
the standard unaffordable for this sector. 相似文献