A comparison of results from two test methods for assessing the toxicity of aminotriazole to Selenastrum capricornutum

Two different test methods for assessing the toxicity of aminotriazole to Selenastrum capricornutum are compared. Growth medium composition is demonstrated to have a significant effect on the toxicity of aminotriazole.     

Octachlorodibenzo-p-dioxin in wood treatment materials and treated wood

The octachlorodibenzo-p-dioxin (OCDD) concentrations have been determined in aged samples of commercial pentachlorophenol (PCP), in wood protection formulations containing PCP and in wood treated with PCP as a preservative or as an anti-sapstain treatment. The concentrations of OCDD found in the various samples are within the range expected from the amount of commercial PCP initially present in the samples. In view of the known stability of OCDD the results are interpreted as indicating that the formulation, treatment and ageing processes have not led to any substantial conversion of PCP to OCDD; although one result indicates that outdoor exposure of treated samples increased the OCDD concentration by a factor of approximately 2 after $\text{3}\text{1}\text{2}$ years. Analysis of aged samples of treated wood indicate that OCDD is lost much less rapidly from the wood than PCP.     

Profile analysis and modeling of reduced tillage effects on soil nitrous oxide flux

The impact of no-till (NT) and other reduced tillage (RT) practices on soil to atmosphere fluxes of nitrous oxide (N(2)O) are difficult to predict, and there is limited information regarding strategies for minimizing fluxes from RT systems. We measured vertical distributions of key microbial, chemical, and physical properties in soils from a long-term tillage experiment and used these data as inputs to a process-based model that accounts for N(2)O production, consumption, and gaseous diffusion. The results demonstrate how differences among tillage systems in the stratification of microbial enzyme activity, chemical reactivity, and other properties can control N(2)O fluxes. Under nitrification-dominated conditions, simulated N(2)O emissions in the presence of nitrite (NO(2)(-)) were 2 to 10 times higher in NT soil compared to soil under conventional tillage (CT). Under denitrification-dominated conditions in the presence of nitrate (NO(3)(-)), higher bulk density and water content under NT promoted higher denitrification rates than CT. These effects were partially offset by higher soluble organic carbon and/or temperature and lower N(2)O reduction rates under CT. The NT/CT ratio of N(2)O fluxes increased as NO(2)(-) or NO(3)(-) was placed closer to the surface. The highest NT/CT ratios of N(2)O flux (>30:1) were predicted for near-surface NO(3)(-) placement, while NT/CT ratios < 1 were predicted for NO(3)(-) placement below 15 cm. These results suggest that N(2)O fluxes from RT systems can be minimized by subsurface fertilizer placement and by using a chemical form of fertilizer that does not promote substantial NO(2)(-) accumulation.     

Analysis of polychlorobiphenyls from used transformers for polychlorodibenzofurans

The results of analyses for polychlorodibenzofuran (PCDF) content in two samples of polychlorobiphenyl (PCB) from used electrical transformers are presented and discussed. In neither sample was there evidence for enhanced PCDF concentrations even though one of them had been subjected to overheating while in service.     

Polychlorodibenzo-p-dioxins and dibenzofurans in technical pentachlorophenol - results of a collaborative analytical exercise

Results of analyses of eight samples of technical pentachlorophenol conducted by three different analytical methods are presented and discussed.     

An investigation of aqueous activity coefficients at low concentrations

The activity of a chemical in solution determines its tendency to move into other media. At low concentrations (<0.01M) it is generally considered to be linearly related to concentration. A hypothetical model based on the structure of liquid water is discussed which could cause deviations from this linearity in the ppb region, a concentration much lower than that normally investigated thermodynamically, but one of great importance environmentally. Headspace experiments are reported with carbon tetrachloride and chloroform in water at concentrations down to ～10^?3 ppb but no such deviations were discerned.     

Long term changes in polychlorodibenzo-p-dioxin concentrations in wood treated with technical pentachlorophenol

Wood samples treated with technical pentachlorophenol (PCP), technical sodium pentachlorophenoxide (NaPCP) and octachlorodibenzo-p-dioxin have been exposed outdoors for periods up to $\text{2}\text{1}\text{2}$ years. Analysis of extracts from the samples show that photolytic reductive dechlorination of highly chlorinated dibenzo-p-dioxins to less chlorinated isomers occurs. However there is no discernible increase in polychlorodibenzo-p-dioxin concentrations in the technical PCP treated wood presumably because further photolytic reactions and volatilisation compete effectively with the photolytic formation. There is no evidence for formation of octachlorodibenzo-p-dioxin (OCDD) in technical PCP treated wood in this study, probably because photolytic destruction and volatilisation compete effectively with formation reactions when the initial OCDD concentration is relatively high.