Metal ion uptake from aqueous solution by olive stones: a carbon-13 solid-state nuclear magnetic resonance and potentiometric study.

The use of biomasses that result from the agriculture and food industries in removing heavy metals from wastewaters is attracting increasing interest. We present a joined potentiometric and cross polarization magic angle spinning (CP-MAS) carbon-13 (13C) nuclear magnetic resonance (NMR) study on the interaction of olive stones with copper(II), nickel(II), and cadmium(II). The potentiometric measurements allow both to distinguish two kind of basic sites in the olive stones and to postulate the coordination models for the three studied metals. The NMR spectral analysis allows the attribution of the different signals to the components of the olive stone matrix. A comparison of CP-MAS 13C NMR spectra of the samples after metal treatment suggests a specific complexation between metal ions and hydroxyl groups on guaiacyl and syringyl moieties.     

Comparative analysis of macrofaunal species richness and composition in Posidonia oceanica, Cymodocea nodosa and leaf litter beds

We investigated macrofaunal species richness and composition in Posidonia oceanica, Cymodocea nodosa and Leaf litter beds within a coastal area of the Gulf of Oristano in proximity of the Cabras lagoon (western Sardinia, Italy). A total of 124 taxa were found, of which 116 were identified at the species level. They were analyzed based on both taxonomic and substrate affinity classification. Presence/absence analysis revealed that P. oceanica, C. nodosa and Leaf litter were all characterized by a conspicuous number of soft-bottom polychaetes (e.g., Prionospio multibranchiata and Ampharete acutifrons) and crustaceans (e.g., Corophium sextonae and Dynamene bidentatus), also known as detritivores. There were also major differences between the three habitats investigated. Consistent with its structural complexity, P. oceanica showed the highest species richness [E(S ₅₀)] and the most diversified macrofaunal assemblages, both in terms of taxonomic groups and taxa associated with different substrates. The two seagrasses, however, showed a similar species composition and differed from Leaf litter for the exclusive presence of hard-bottom species (e.g., the tunicate Phallusia fumigata) and seagrass-associated species (e.g., the polychaete Syllis garciai and the decapod Paguristes syrtensis). In contrast, Leaf litter showed the most differences between the habitats, and was characterized by the bivalves Abra alba and Cerastoderma glaucum, not found in seagrass beds, and by Loripes lacteus and Ruditapes decussatus. Leaf litter also had the highest content of organic matter (26.7% ± 1.4) and total organic carbon (10.3% ± 0.4). Our results confirmed the facilitative role of living seagrasses, in particular P. oceanica, as related to their structural complexity, for numerous species from different substrates (e.g., hard bottom species). This study also showed that leaf litter beds act as a particular environment where sediment instability, leaf breakdown, and organic matter enrichment and decomposition strongly influence animal distribution. Finally, our results highlighted the ecological and trophic importance of seagrass-derived detritus and the associated macroinvertebrate detritivores within seagrass-dominated systems.     

Larval development of <Emphasis Type="Italic">Lightiella magdalenina</Emphasis> (Crustacea,Cephalocarida)

The larval development of the newly discovered cephalocarid from Mediterranean sea, Lightiella magdalenina, was analysed using light and scanning electron microscopy. Twenty-nine larval specimens, divided into 15 metanaupliar and 2 juvenile stages of development, were found. The first six metanaupliar stages had an even number (6, 8, 10, 12, 14 and 16) of trunk segments including telson. The condition of 20 trunk segments, typical of the adult, was reached after another 4 stages by the addition of a single segment per stage. At this tenth stage, the larvae had an incomplete number of trunk limbs. Another five stages were needed to complete the cephalic appendage development, passing from the metanaupliar to the juvenile stage, characterized by loss of the naupliar enditic process of the second antenna. Trunk limbs development was completed during the last two juvenile stages. According to the ontogenetic data reported for Hutchinsoniella macracantha and Lightiella incisa, these seventeen stages probably do not represent the complete developmental series. Nevertheless, they allow us to clarify the main features of cephalocarid ontogeny and show specific differences in the development of both the trunk segments and appendages.     

On the uncertainty and confidence in decision support tools (DSTs) with insights from the Baltic Sea ecosystem

Ecosystems around the world are increasingly exposed to multiple, often interacting human activities, leading to pressures and possibly environmental state changes. Decision support tools (DSTs) can assist environmental managers and policy makers to evaluate the current status of ecosystems (i.e. assessment tools) and the consequences of alternative policies or management scenarios (i.e. planning tools) to make the best possible decision based on prevailing knowledge and uncertainties. However, to be confident in DST outcomes it is imperative that known sources of uncertainty such as sampling and measurement error, model structure, and parameter use are quantified, documented, and addressed throughout the DST set-up, calibration, and validation processes. Here we provide a brief overview of the main sources of uncertainty and methods currently available to quantify uncertainty in DST input and output. We then review 42 existing DSTs that were designed to manage anthropogenic pressures in the Baltic Sea to summarise how and what sources of uncertainties were addressed within planning and assessment tools. Based on our findings, we recommend future DST development to adhere to good modelling practise principles, and to better document and communicate uncertainty among stakeholders.Electronic supplementary materialThe online version of this article (doi:10.1007/s13280-020-01385-x) contains supplementary material, which is available to authorized users.     

FLOOD MANAGEMENT IN THE LOWER INCOMATI RIVER BASIN,MOZAMBIQUE: TWO ALTERNATIVES1

ABSTRACT: The aim of this paper is to compare two views of flood management and thus add to the present thinking of living with floods as opposed to the traditional approach of flood control. The traditional pathway has widely been adopted in developed countries and aims to control floodwaters by means of dams and dikes. The alternative pathway tends towards a policy whereby society lives with the floods by being prepared and having the right damage reduction measures in place. In this paper two pathways are tentatively compared for the Lower Incomati Basin, Mozambique. In the design cultural theory is considered, as is how the design of each path may look according to different management perspectives. The Lower Incomati Basin provides an interesting case study as it is in a relatively undeveloped state. Hence, it is an ideal area for conducting research into the application of alternative flood management strategies. The preliminary results suggest that both pathways are feasible. However, considering recent hydrological extremes such as the 2000 floods, the resilient pathway may ultimately be a more appealing flood management strategy.     

Combination of beehive matrices analysis and ant biodiversity to study heavy metal pollution impact in a post-mining area (Sardinia, Italy)

Mining activities represent a major source of environment contamination. The aim of this study was to evaluate the use of bees and ants as bioindicators to detect the heavy metal impact in post-mining areas. A biomonitoring programme involving a combination of honeybee hive matrices analysis and ant biodiversity survey was conducted over a 3-year period. The experimental design involved three monitoring stations where repeated sampling activities focused on chemical detection of cadmium (Cd), chrome (Cr) and lead (Pb) from different matrices, both from hosted beehives (foraging bees, honey and pollen) and from the surrounding environment (stream water and soil). At the same time, ant biodiversity (number and abundance of species) was determined through a monitoring programme based on the use of pitfall traps placed in different habitats inside each mining site. The heavy metal content detected in stream water from the control station was always below the analytical limit of quantification. In the case of soil, the content of Cd and Pb from the control was lower than that of mining sites. The mean heavy metal concentrations in beehive matrices from mining sites were mainly higher than the control, and as a result of regression and discriminant analysis, forager bee sampling was an efficient environmental pollution bioindicator. Ant collection and identification highlighted a wide species variety with differences among habitats mostly associated with vegetation features. A lower variability was observed in the polluted landfill characterised by lack of vegetation. Combined biomonitoring with forager bees and ants represents a reliable tool for heavy metal environmental impact studies.     

Universal access to water and sanitation: Why the private sector must participate

Against the background of the current state of provision of drinking water and sanitation in the world — with one billion lacking safe water, and 2.2 billion not having adequate sanitation — this article argues that private participation is necessary. The most important issues for the management of water utilities in the 21^st century are identified as mobilizing investment for the highly capital intensive operation of water supply and sanitation infrastructure, and achieving efficiency in the delivery of services. The article highlights the issues that need to be raised if private investment is to be seriously considered as an alternative. Case studies, especially from Latin America (Argentina, Chile, Peru, Bolivia), illustrate different modes of private participation, and possible reasons for successes and failures are discussed. The article stresses that regardless of the modality of private sector involvement, on‐going government regulatory responsibility in the water sector is crucial. It suggests that regulatory policy must go beyond just setting tariffs, to develop standards for drinking water quality and waste treatment, as well as other standards. In conclusion, the article recognizes that numerous and increasingly difficult challenges face utilities in fulfilling their responsibility to deliver drinking water of adequate quality, in sufficient quantity, and at affordable prices, as well as safe and sustainable disposal of wastewaters for members of urban and rural communities.