Design of a Cost-Effective Weighing Facility for PM2.5 Quality Assurance

Abstract

The U.S. Environmental Protection Agency (EPA) Quality Assurance (QA) Guidance Document 2.12: Monitoring PM_2.5 in Ambient Air Using Designated Reference or Class I Equivalent Methods¹ (Document 2.12) requires conditioning of PM_2.5 filters at 20-23 °C and 30-40% relative humidity (RH) for 24 hr prior to gravimetric analysis. Variability of temperature and humidity may not exceed ±2 °C and ±5% RH during the conditioning period. The quality assurance team at EPA Region 2’s regional laboratory designed a PM_2.5 weighing facility that operates well within these strict performance requirements.

The traditional approach to meeting the performance requirements of Document 2.12 for PM_2.5 filter analysis is to build a walk-in room, with costs typically exceeding $100,000. The initial one-time capital cost for the laboratory at EPA’s Edison, NJ, facility was approximately $24,000. Annual costs [e.g., National Institute of Standards and Technology (NIST) recertifications and nitrogen replacement cylinders used for humidity control] are approximately $500. The average 24-hr variabilities in temperature and RH in the Region 2 weighing chamber are small, ±0.2 °C and ±0.8% RH, respectively. The mass detection limit for the PM_2.5 weighing system of 47-mm stretched Teflon (lab blank) filters is 6.3 μg. This facility demonstrates an effective and economical example for states and other organizations planning PM_2.5 weighing facilities.     

Task type as a moderator of positive/negative feedback effects on motivation and performance: A regulatory focus perspective

Applying Higgins' regulatory focus theory, we hypothesized that the effect of positive/negative feedback on motivation and performance is moderated by task type, which is argued to be an antecedent to situational regulatory focus (promotion or prevention). Thus, first we demonstrated that some tasks (e.g., tasks requiring creativity) are perceived as promotion tasks, whereas others (e.g., those requiring vigilance and attention to detail) are perceived as prevention tasks. Second, as expected, our tests in two studies of the moderation hypothesis showed that positive feedback increased self‐reported motivation (meta‐analysis across samples: N = 315, d = 0.43) and actual performance (N = 55, d = 0.67) among people working on promotion tasks, relative to negative feedback. Positive feedback, however, decreased motivation (N = 318, d = ?0.33) and performance (N = 55, d = ?0.37) among individuals working on prevention tasks, relative to negative feedback. These findings suggest that (a) performance of different tasks can affect regulatory focus and (b) variability in positive/negative feedback effects can be partially explained by regulatory focus and task type. Copyright © 2010 John Wiley & Sons, Ltd.     

Study of the biouptake of labeled single-walled carbon nanotubes using fluorescence-based method

Single-wall carbon nanotubes (CNT) are one of the most attractive engineered nanomaterials due to their unique electrical, mechanical and thermal properties, and potential use in a variety of commercial products. Due to their small size, CNT could become easily airborne and reach the various environmental compartments and eventually the food chain and humans. However, the environmental fate processes and health impacts of CNT are not clear. This study investigated a method for the quantitative measurement of carbon nanotube (CNT) in natural media such soil and benthic organism tissues. Fluorescence dye Nile blue was used for noncovalent labeling of CNT to enable their fluorescence detection. Labeled nanotubes were successfully detected in soil samples as well as in worm tissue. We were also able to detect the presence of labeled carbon nanotubes in worms exposed for 1 week to CNT-laden soil, which indicates CNT may transfer through environmental food web. The method allows for laboratory measurements of CNT mass transfer and partitioning into various environmental systems.     

Hele-Shaw beach creation by breaking waves: a mathematics-inspired experiment

Fundamentals of nonlinear wave-particle interactions are studied experimentally in a Hele-Shaw configuration with wave breaking and a dynamic bed. To design this configuration, we determine, mathematically, the gap width which allows inertial flows to survive the viscous damping due to the side walls. Damped wave sloshing experiments compared with simulations confirm that width-averaged potential-flow models with linear momentum damping are adequately capturing the large scale nonlinear wave motion. Subsequently, we show that the four types of wave breaking observed at real-world beaches also emerge on Hele-Shaw laboratory beaches, albeit in idealized forms. Finally, an experimental parameter study is undertaken to quantify the formation of quasi-steady beach morphologies due to nonlinear, breaking waves: berm or dune, beach and bar formation are all classified. Our research reveals that the Hele-Shaw beach configuration allows a wealth of experimental and modelling extensions, including benchmarking of forecast models used in the coastal engineering practice, especially for shingle beaches.