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It is a great challenge to sample seawater across interfaces, for example the halocline or the redoxcline, to investigate trace metal distribution. With the use of 10l sampling bottles mounted to a wire or a CTD-Rosette it is possible to obtain a maximum vertical resolution of 5m. For the detection of small vertical structures in the vertical distribution of trace metals across the redoxcline, the CTD-Bottle-Rosette is not sufficient. Therefore, a PUMP-CTD-System was developed, which enables water sampling with high resolution (1m maximum) along a vertical profile. To investigate the suitability and possible contamination sources of this device two experiments were carried out in the Gotland Basin. The first experiment consisted of two separate profiles. The first profile was obtained with the CTD-Bottle-Rosette and the second with the PUMP-CTD-System. Both were taken from the bottom to the surface water layer. The second experiment was a combined profile obtained from the surface to the bottom with the PUMP-CTD-System attached to the CTD-Bottle-Rosette. Concentrations of dissolved Pb, Cd, Cu, Zn, Fe, Mn, Co and Ni from the "Niskin Bottles" and from the PUMP were measured and compared for each investigation. We demonstrate that it is useful to perform vertical sampling from lower to higher concentrations, e.g. surface to bottom in this environment, and that a longer flushing is required for sampling seawater in the anoxic bottom water. A comparison of the two systems for oxygen and hydrogen sulphide measurements showed an improvement of the precision and the quality of the sampling when using the PUMP. Thus, metal speciation at the oxic-anoxic gradient zone and on a high vertical resolution will be accessible. As concentrations of dissolved Pb, Cd, Cu, Zn, Co, Ni, Fe and Mn in seawater sampled with both devices were in the same range, we conclude that the PUMP-CTD-System is well suited to sample seawater for trace metal analyses. 相似文献
3.
P.M. Roth S.D. Reynolds T.W. Tesche P.D. Gutfreund C. Seigneur 《Environment international》1983,9(6):549-571
The purpose of this study is to evaluate the effect of reductions of reactive organic gases (ROG) and NOx emissions on short-term O3 and NO2 concentrations and annual average NO2 concentrations in the California South Coast Air Basin. Short-term air quality predictions were obtained by applying the Systems Applications Airshed Model to summer O3 and autumn NO2 episodes. Effects of emission controls on annual NO2 concentrations were estimated using CDM and a new parcel tracking model NOXTRAK. Results for the summer O3 episode indicate that ROG emission reduction in an effective means for reducing peak O3 concentrations. NOx emission reduction imposed in addition to ROG emission reductions are counterproductive in reducing peak O3 concentrations. The modeling results also suggest that attainment of the 1-h federal O3 standard requires ROG emission reductions on the order of 80% from 1987 levels. Results for the autumn NO2 episode indicate that NOx emission reductions approximating those recommended in a proposed Air Quality Management Plan (about 22%) will result in only small (about 5%) reductions in the peak NO2 concentrations. ROG emission reduction may be more effective than NOx emission reduction in reducing the peak NO2 concentration. For the episode studied, a reduction of 36% in ROG emissions is estimated to result in a reduction in peak NO2 concentrations commensurate with that required to attain the 1-h state NO2 standard. Model calculations also indicate that the federal NO2 standard may not be meet by 1987 at one or two stations, but may blosely approached. 相似文献
4.
M. Alisa Mast David J. Manthorne David A. Roth 《Atmospheric environment (Oxford, England : 1994)》2010,44(21-22):2577-2586
Atmospheric deposition of Hg and selected trace elements was reconstructed over the past 150 years using sediment cores collected from nine remote, high-elevation lakes in Rocky Mountain National Park in Colorado and Glacier National Park in Montana. Cores were age dated by 210Pb, and sedimentation rates were determined using the constant rate of supply model. Hg concentrations in most of the cores began to increase around 1900, reaching a peak sometime after 1980. Other trace elements, particularly Pb and Cd, showed similar post-industrial increases in lake sediments, confirming that anthropogenic contaminants are reaching remote areas of the Rocky Mountains via atmospheric transport and deposition. Preindustrial (pre-1875) Hg fluxes in the sediment ranged from 5.7 to 42 μg m?2 yr?1 and modern (post-1985) fluxes ranged from 17.7 to 141 μg m?2 yr?1. The average ratio of modern to preindustrial fluxes was 3.2, which is similar to remote lakes elsewhere in North America. Estimates of net atmospheric deposition based on the cores were 3.1 μg m?2 yr?1 for preindustrial and 11.7 μg m?2 yr?1 for modern times. Current-day measurements of wet deposition range from 5.0 to 8.6 μg m?2 yr?1, which are lower than the modern sediment-based estimate of 11.7 μg m?2 yr?1, perhaps owing to inputs of dry-deposited Hg to the lakes. 相似文献
5.
Pavel Karásek Barbora Hohnová Josef Planeta Lenka Št’avíková Michal Roth 《Chemosphere》2013,90(6):2035-2040
Increasing production and disposal of organic light-emitting diode (OLED) displays for smartphones and tablets may have impact on the environment depending on the aqueous solubility of the pertinent chemicals. Here, aqueous solubilities are presented for several compounds, mostly aromatic amines, used as hole transport materials in the OLED displays. Solute selection includes 1,4-bis(diphenylamino)benzene, tetra-N-phenylbenzidine, 4,4′-bis(N-carbazolyl)-1,1′-biphenyl, 1,3,5-tris(diphenylamino)benzene, and 9,10-bis(phenylethynyl)anthracene. The solubilities are those in pressurized hot water (PHW), i.e., measured at elevated temperature (up to 260 °C) and pressure. The semi-quantitative estimates of room-temperature solubilities of the solutes have been obtained from extrapolations of the solubilities in PHW. For the compounds studied, the estimated aqueous solubilities at room temperature do not exceed 2 × 10?11 g of the solute per 1 kg of water. Aqueous solubilities of triphenylamine have also been measured and used to upgrade a recent group-contribution model of aqueous solubilities of organic nonelectrolytes with the parameters for the nitrogen atom in aromatic amines. 相似文献
6.
Andrew S. Watt Kimberly A. Magrini Lynnae E. Carlson Edward J. Wolfrum Sheldon A. Larson Christine Roth 《Journal of the Air & Waste Management Association (1995)》2013,63(11):1368-1373
ABSTRACT Researchers from the National Renewable Energy Laboratory recently conducted a pilot-scale study at McClellan Air Force Base (AFB) in Sacramento, CA. The objective of the test was to determine the effectiveness of an ambient-temperature, solar-powered photocatalytic oxidation treatment unit for destroying emissions of chlorinated organic compounds from an air stripper. This paper reports test results and discusses applications and limitations of the technology. A 10-standard-cubic-foot-per-minute (SCFM) (28.3 L/min) slip stream of air from an air stripper at Operative Unit 29-31 at McClellan AFB was passed through a reactor that contained a lightweight, perforated, inert support coated with photoactive titanium dioxide. The reactor faced south and was tilted at a 45° angle from vertical so that the light-activated catalyst received most of the available sunlight. An online portable gas chro-matograph with two identical columns simultaneously analyzed the volatile organic compounds contained in the reactor inlet and outlet air streams. Summa canister grab samples of the inlet and outlet were also collected and sent to a certified laboratory for U.S. Environmental Protection Agency Method TO-14 analysis and verification of our field analyses. Three weeks of testing demonstrated that the treatment system's destruction and removal efficiencies (DREs) are greater than 95% at 10 SCFM with UV intensities at or greater than 1.5 milliwatts/square centimeter (mW/cm2). DREs greater than 95% at 20 SCFM were obtained under conditions where UV irradiation measured at or greater than 2 mW/cm2. In Sacramento, this provided 6 hours of operation per clear or nearly clear day in April. A solar tracking system could extend operating time. The air stream also contained trace amounts of benzene. We observed no loss of system performance during testing. 相似文献
7.
Polyacetylene is presented as the prototype of a metallic conducting polymer. The concepts of one-dimensional metal physics are illustrated and special attention is drawn to a structural defect called “soliton”. Electrical, magnetic, and optical experiments connected with solitons are discussed. The authors' opinion is expressed that present experimental results do not yet furnish strong evidence for the existence of solitons in polyacetylene, but that the soliton idea is a fruitful stimulus for further investigations and novel applications. 相似文献
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Summary The Dominican Republic and other Caribbean countries face serious challenges to their natural resource base. In recent years
the government of the Dominican Republic has taken major steps toward the development and implementation of a comprehensive
plan for national natural resources management. This plan is called Plan Sierra. An important component of this plan is the
outline of actions for carrying out an environmental education programme within the country. This demonstrates a commitment
to fulfill Recommendation No. 96 of the Stockholm Conference in a way that could become a model for other Latin American nations.
Clinton L. Shepard is Assistant Professor in the Division of Environmental Education, School of Natural Resources, The Ohio
State University. Dr Shepard holds a Bachelor of Science degree in Zoology from the University of Kentucky and graduate degrees
from The Ohio State University in Natural Resources/Environmental Education and Education-Foundations and Research. He has
worked as an interpreter and Environmental Education Coordinator for the State of Ohio Department of Natural Resources, a
research associate for ERIC—Science, Math, and Environmental Education Clearinghouse, and College instructor in interpretive
methods, environmental education methodology, resident outdoor programming, and natural resources development. He is also
involved in international research and development, especially in the Caribbean Basin.
Robert E. Roth is Chairman/Professor in the Division of Environmental Education, School of Natural Resources, The Ohio State
University. Dr Roth received a Bachelor's degree in Wildlife Management, a Bachelor's degree in Secondary Science Education,
a Master's degree in Conservation Education from The Ohio State University, and his Ph.D. in Environmental Education from
The University of Wisconsin. he came to OSU in 1969 and since that time has designed and institutionalized the only academic
unit in the US that offers both well developed undergraduate and graduate programmes in Environmental Communications, Education
and Interpretation and has published over 40 works in the field. He has been instrumental in implementing a growing international
environmental education research and development emphasis in the wider Caribbean, he continues as an Executive Editor of theJournal of Environmental Education. 相似文献
10.